Effect of ammonium polyphosphate on phosphorus adsorption and desorption in laterite and calcareous soil

doi:10.3969/j.issn.1004-1524.2021.04.15

Acta Agriculturae Zhejiangensis ›› 2021, Vol. 33 ›› Issue (4): 697-703.DOI: 10.3969/j.issn.1004-1524.2021.04.15

• Environmental Science • Previous Articles Next Articles

Effect of ammonium polyphosphate on phosphorus adsorption and desorption in laterite and calcareous soil

YANG Yibin¹(), CHEN Xiaojuan¹, DENG Lansheng¹, LIN Jingjing¹, CHENG Fengxian¹, HU Kewei², ZHANG Chenglin¹^,^*(), TU Panfeng³^,^*()

1. College of Natural Resources and Environment, South China Agricultural University, Guangzhou 510642, China
2. Dongguan Yixiang Liquid Fertilizer Co., Ltd., Dongguan 523135, China
3. College of Horticulture and Landscape Architecture, Zhongkai University of Agriculture and Engineering, Guangzhou 510225, China

Received:2020-10-12 Online:2021-04-25 Published:2021-04-25
Contact: ZHANG Chenglin,TU Panfeng

Abstract

Abstract:

In the present study, the soil culture experiments were conducted to study the adsorption and desorption behaviors of ammonium polyphosphate (APP) and monoammonium phosphate (MAP) in calcareous soil and laterite, to provide theoretical reference for the evaluation of phosphorus availability. Six treatments were introduced in this work according to the materials used: APP1 (mainly high polymer), APP2 (mainly oligomeric), APP3 (mainly low, medium, and high polymer), MAP, A-M (APP3 and MAP mixed with the ratio of 1∶1 based on the content of P₂O₅), and CK (blank control). All the treatments set the same rate of nitrogen and phosphorus except CK. After 50 days of soil cultivation, the adsorption and desorption characteristics of phosphorus were measured. The results showed that the equations of Langmuir, Freundlich, and Temkin could well fit the adsorption characteristics of soil phosphorus in different soils, and the Freundlich equation had the best fitting effect with a correlation coefficient of 0.86-0.98. In calcareous soil (except CK), the soil with APP1 had the strongest adsorption capacity, while the soil with A-M had the weakest adsorption capacity, the largest phosphorus desorption, and the highest phosphorus desorption rate. In laterite (except CK), the soil with APP1 showed the strongest adsorption capacity, and the soil with APP2 showed the weakest adsorption, the largest phosphorus desorption, and the highest phosphorus desorption rate. The results indicated that the application of MAP with APP with uniform polymerization degree distribution and high aggregate content could reduce the adsorption of phosphorus in calcareous soil to improve the availability of phosphorus. While APP with low polymerization degree could lower the adsorption of phosphorus by laterite, and maintain the balance of phosphorus.

Key words: ammonium polyphosphate, monoammonium phosphate, adsorption, desorption, polymerization degree

CLC Number:

S143.2

YANG Yibin, CHEN Xiaojuan, DENG Lansheng, LIN Jingjing, CHENG Fengxian, HU Kewei, ZHANG Chenglin, TU Panfeng. Effect of ammonium polyphosphate on phosphorus adsorption and desorption in laterite and calcareous soil[J]. Acta Agriculturae Zhejiangensis, 2021, 33(4): 697-703.

Figures/Tables 5

References 22

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成分Component	APP1	APP2	APP3
正磷酸 Ortho-phosphoric acid	0.49	9.79	4.95
焦磷酸 Pyrophosphate	1.39	35.50	11.39
三聚磷酸 Tri-phosphoric acid	10.18	13.11	10.05
四聚磷酸 Tetra-phosphoric acid	22.59	3.67	19.88
五聚磷酸 Penta-phosphoric acid	6.34	0.09	7.27
多聚磷酸 Poly-phosphoric acid	2.64	0.05	16.80
总磷 Total phosphorus	43.50	43.76	60.00

成分Component	APP1	APP2	APP3
正磷酸 Ortho-phosphoric acid	0.49	9.79	4.95
焦磷酸 Pyrophosphate	1.39	35.50	11.39
三聚磷酸 Tri-phosphoric acid	10.18	13.11	10.05
四聚磷酸 Tetra-phosphoric acid	22.59	3.67	19.88
五聚磷酸 Penta-phosphoric acid	6.34	0.09	7.27
多聚磷酸 Poly-phosphoric acid	2.64	0.05	16.80
总磷 Total phosphorus	43.50	43.76	60.00

土壤 Soil	处理 Treatment	Langmuir方程 Langmuir equation	Freundlich方程 Freundlich equation	Langmuir方程 Langmuir equation
石灰性土壤 Calcareous soil	APP1	C/q=0.000 1C+0.264 5, r=0.519 4	ln q=1.745 0+0.898 3ln C, r=0.978 7	q=4.063 9+0.001 3ln C, r=0.912 4
	APP2	C/q=0.000 1C+0.312 8, r=0.359 6	ln q=1.427 6+0.929 9ln C, r=0.965 2	q=4.176 9+0.001 4ln C, r=0.958 4
	APP3	C/q=0.000 1C+0.312 3, r=0.429 4	ln q=1.392 7+0.937 9ln C, r=0.978 2	q=4.193 3+0.001 3ln C, r=0.944 9
	A-M	C/q=0.000 1C+0.313 8, r=0.313 9	ln q=1.375 8+0.941 2ln C, r=0.968 3	q=4.189 8+0.001 3ln C, r=0.950 7
	MAP	C/q=0.000 1C+0.286 0, r=0.324 1	ln q=1.552 5+0.926 7ln C, r=0.975 7	q=4.135 5+0.001 3ln C, r=0.917 1
	CK	C/q=0.000 5C+0.212 9, r=0.525 8	ln q=2.420 1+0.798 3ln C, r=0.985 3	q=3.844 0+0.001 4ln C, r=0.822 0
砖红壤 Laterite	APP1	C/q=0.000 5C+0.099 8, r=0.548 8	ln q=3.358 5+0.714 3ln C, r=0.925 7	q=3.130 5+0.001 4ln C, r=0.828 5
	APP2	C/q=0.000 5C+0.141 8, r=0.408 6	ln q=2.664 0+0.816 8ln C, r=0.941 6	q=3.497 1+0.001 3ln C, r=0.870 9
	APP3	C/q=0.000 5C+0.131 5, r=0.455 3	ln q=2.918 4+0.771 6ln C, r=0.934 4	q=3.403 8+0.001 3ln C, r=0.854 0
	A-M	C/q=0.000 5C+0.132 0, r=0.434 1	ln q=2.875 6+0.780 8ln C, r=0.939 6	q=3.419 6+0.001 3ln C, r=0.852 3
	MAP	C/q=0.000 5C+0.127 1, r=0.368 4	ln q=3.190 1+0.724 0ln C, r=0.862 3	q=3.321 1+0.001 3ln C, r=0.832 2
	CK	C/q=0.000 3C+0.035 0, r=0.951 8	ln q=4.387 6+0.599 3ln C, r=0.949 4	q=1.967 6+0.001 7ln C, r=0.920 7

土壤 Soil	处理 Treatment	Langmuir方程 Langmuir equation	Freundlich方程 Freundlich equation	Langmuir方程 Langmuir equation
石灰性土壤 Calcareous soil	APP1	C/q=0.000 1C+0.264 5, r=0.519 4	ln q=1.745 0+0.898 3ln C, r=0.978 7	q=4.063 9+0.001 3ln C, r=0.912 4
	APP2	C/q=0.000 1C+0.312 8, r=0.359 6	ln q=1.427 6+0.929 9ln C, r=0.965 2	q=4.176 9+0.001 4ln C, r=0.958 4
	APP3	C/q=0.000 1C+0.312 3, r=0.429 4	ln q=1.392 7+0.937 9ln C, r=0.978 2	q=4.193 3+0.001 3ln C, r=0.944 9
	A-M	C/q=0.000 1C+0.313 8, r=0.313 9	ln q=1.375 8+0.941 2ln C, r=0.968 3	q=4.189 8+0.001 3ln C, r=0.950 7
	MAP	C/q=0.000 1C+0.286 0, r=0.324 1	ln q=1.552 5+0.926 7ln C, r=0.975 7	q=4.135 5+0.001 3ln C, r=0.917 1
	CK	C/q=0.000 5C+0.212 9, r=0.525 8	ln q=2.420 1+0.798 3ln C, r=0.985 3	q=3.844 0+0.001 4ln C, r=0.822 0
砖红壤 Laterite	APP1	C/q=0.000 5C+0.099 8, r=0.548 8	ln q=3.358 5+0.714 3ln C, r=0.925 7	q=3.130 5+0.001 4ln C, r=0.828 5
	APP2	C/q=0.000 5C+0.141 8, r=0.408 6	ln q=2.664 0+0.816 8ln C, r=0.941 6	q=3.497 1+0.001 3ln C, r=0.870 9
	APP3	C/q=0.000 5C+0.131 5, r=0.455 3	ln q=2.918 4+0.771 6ln C, r=0.934 4	q=3.403 8+0.001 3ln C, r=0.854 0
	A-M	C/q=0.000 5C+0.132 0, r=0.434 1	ln q=2.875 6+0.780 8ln C, r=0.939 6	q=3.419 6+0.001 3ln C, r=0.852 3
	MAP	C/q=0.000 5C+0.127 1, r=0.368 4	ln q=3.190 1+0.724 0ln C, r=0.862 3	q=3.321 1+0.001 3ln C, r=0.832 2
	CK	C/q=0.000 3C+0.035 0, r=0.951 8	ln q=4.387 6+0.599 3ln C, r=0.949 4	q=1.967 6+0.001 7ln C, r=0.920 7

处理 Treatment	石灰性土壤 Calcareous soil	砖红壤 Laterite
APP1	5.73±0.03 b	28.75±0.03 b
APP2	4.17±0.02 d	14.35±0.02 f
APP3	4.03±0.02 de	18.51±0.02 d
A-M	3.96±0.03 e	17.74±0.02 e
MAP	4.72±0.06 c	24.29±0.06 c
CK	11.25±0.07 a	80.45±0.06 a

Effect of ammonium polyphosphate on phosphorus adsorption and desorption in laterite and calcareous soil

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