›› 2013, Vol. 25 ›› Issue (1): 0-118.

• 论文 •    

Study on adsorption\|desorption characteristics of butylene fipronil in soils

CAO Weiqiang;LYU Yixiu;YYU Yyujuan;YE Qing;SHE Yongxin;WANG Jing;*   

  1. 1 Huizhou Exit\|Entry Inspection and Quarantine Bureau, Huizhou 516006, China; 2 School of Chemical Engineering and Light Industry,Guangdong University of Technology, Guangzhou 510006, China;3Institute of Quality Standard & Testing Technology for Agro\|Product,Chinese Academy of Agricultural Sciences, Beijing 100081, China
  • Received:1900-01-01 Revised:1900-01-01 Online:2013-01-25 Published:2013-01-25

Abstract: The adsorption-desorption experiments of butylene fipronil in soils were conducted by the batch equilibration and GC-MS techniques, furthermore, data were analyzed with mathematic models to describe the characteristics and mechanism of adsorption-desorption and the shift of butylene fipronil in soils. The results showed that the adsorption-desorption isotherms of butylene fipronil was fitted for Freundlich model well, and the physical reaction played the main role in adsorption-desorption process. The adsorption values (1/nads) of butylene fipronil in 5 types of soils ranged from 0.4539-0.4868 and the desorption values (1/ndes) ranged from 0.4220-0.4623. The results of desorption indicated that there was no obvious hysteresis phenomena appeared during the desorption process, and the hysteresis index (HI) of the butylene fipronil in 5 soils studied varied from 0.8958-0.9497. Furthermore, there was not a positive correlation between the adsorption values (1/nads) and the desorption values (1/ndes) of butylene fipronil and organic materials in soils, average hysteresis index (HI) decreased with increasing organic materials content slightly. The mobility of butylene fipronil in 5 types of tested soils was very low, and there was no risk to surface water and underground water during routine use.

Key words: butylene fipronil, adsorption\|desorption, Freundlich model, hysteresis phenomena