Comparison of key properties of short-chain polyphosphate fertilizers in market

doi:10.3969/j.issn.1004-1524.20230476

Acta Agriculturae Zhejiangensis ›› 2024, Vol. 36 ›› Issue (5): 1134-1143.DOI: 10.3969/j.issn.1004-1524.20230476

• Environmental Science • Previous Articles Next Articles

Comparison of key properties of short-chain polyphosphate fertilizers in market

KANG Longfei¹^,²(), XU Linfeng¹, WANG Shirong¹, JIANG Chengtao¹, CHU Guixin¹^,^*()

1. College of Life and Environmental Sciences, Shaoxing University, Shaoxing 312000, Zhejiang, China
2. Key Laboratory of Oasis Eco-Agriculture of Xinjiang Construction Corps, Agricultural College, Shihezi University, Shihezi 832000, Xinjiang, China

Received:2023-04-10 Online:2024-05-25 Published:2024-05-29

Abstract

Abstract:

Currently, the quality of short-chain polyphosphate fertilizers varied greatly. In the present study, 10 typical short-chain polyphosphate fertilizer samples were collected from the fertilizer market in China. Main features of these samples, including the contents of total N and total P (based on P₂O₅), polymerization degree, polymerization rate, solubility, etc, were determined, and the cluster analysis and Mantel test method were employed to compare the differences of these samples. It was shown that the average degree of polymerization was 4.00, and the average deviation between the measured values and the labeled values was 6.38%. The average polymerization rate was 83.8%, and the average deviation between the measured values and the labeled values was 2.59%. The total N content of these samples ranged from 8.6% to 28.7%, and the average deviation between the measured values and the labeled values was 2.59%. The total P content of these samples was 18.0%-64.2%. Mantel test results demonstrated that the total N content, the total P content, the pH value and salinity index were significantly (P<0.05) correlated with polymerization rate, while the total P content, solubility, salt index and the content of biuret were significantly correlated with the degree of polymerization. In conclusion, the quality of short-chain polyphosphate fertilizers in market varied greatly, and the labeled values differed from the determined values of main features in short-chain polyphosphate fertilizers. Thus, it was urgent and necessary to establish a unified measurement system to provide more accurate and comprehensive information for consumers.

Key words: polyphosphate fertilizer, solubility, polymerization degree, polymerization rate, phosphorus fertilizer

CLC Number:

S143.2

KANG Longfei, XU Linfeng, WANG Shirong, JIANG Chengtao, CHU Guixin. Comparison of key properties of short-chain polyphosphate fertilizers in market[J]. Acta Agriculturae Zhejiangensis, 2024, 36(5): 1134-1143.

Figures/Tables 6

References 50

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样品编号 Sample No.	产地 Producing area	养分(N-P₂O₅-K₂O)含量 Nutrinents (N-P₂O₅-K₂O) content/%	聚合度 Polymerization degree	聚合率 Polymerization rate/%	备注信息 Notes
S1	新疆Xinjiang	16-63-0	7.48	98.2	溶解度Solubility:340 g·L^-1
S2	内蒙古Inner Mongolia	25-46-0	4.93	94.2	溶解度Solubility:430 g·L^-1
S3	山西Shanxi	26-47-0	5.01	88.1	溶解度Solubility:470 g·L^-1
S4	河南Henan	14-55-0	4.40	88.1	pH=5.61
S5	湖南Hunan	29-47-0	3.82	94.1	pH=8.36
S6	广西Guangxi	9-18-17	3.61	53.3	复合肥 Compound fertilizer
S7	广东Guangdong	18-64-0	3.62	96.8	TE
S8	四川Sichuan	21-54-0	3.40	73.9	溶解度Solubility:990 g·L^-1
S9	云南Yunnan	25-52-17	3.37	97.7	复合肥Compound fertilizer
S10	浙江Zhejiang	19-54-0	3.19	76.2	溶解度Solubility:900 g·L^-1

样品编号 Sample No.	产地 Producing area	养分(N-P₂O₅-K₂O)含量 Nutrinents (N-P₂O₅-K₂O) content/%	聚合度 Polymerization degree	聚合率 Polymerization rate/%	备注信息 Notes
S1	新疆Xinjiang	16-63-0	7.48	98.2	溶解度Solubility:340 g·L^-1
S2	内蒙古Inner Mongolia	25-46-0	4.93	94.2	溶解度Solubility:430 g·L^-1
S3	山西Shanxi	26-47-0	5.01	88.1	溶解度Solubility:470 g·L^-1
S4	河南Henan	14-55-0	4.40	88.1	pH=5.61
S5	湖南Hunan	29-47-0	3.82	94.1	pH=8.36
S6	广西Guangxi	9-18-17	3.61	53.3	复合肥 Compound fertilizer
S7	广东Guangdong	18-64-0	3.62	96.8	TE
S8	四川Sichuan	21-54-0	3.40	73.9	溶解度Solubility:990 g·L^-1
S9	云南Yunnan	25-52-17	3.37	97.7	复合肥Compound fertilizer
S10	浙江Zhejiang	19-54-0	3.19	76.2	溶解度Solubility:900 g·L^-1

Comparison of key properties of short-chain polyphosphate fertilizers in market

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[1]	YANG Yibin, CHEN Xiaojuan, DENG Lansheng, LIN Jingjing, CHENG Fengxian, HU Kewei, ZHANG Chenglin, TU Panfeng. Effect of ammonium polyphosphate on phosphorus adsorption and desorption in laterite and calcareous soil [J]. Acta Agriculturae Zhejiangensis, 2021, 33(4): 697-703.
[2]	CHEN Xiaojuan, CHEN Yulin, LIN Jingjing, YANG Yibin, HU Kewei, ZHANG Chenglin. Conversion dynamics and effectiveness of ammonium polyphosphate with different polymerization degrees to soil phosphorus [J]. , 2019, 31(10): 1681-1688.