浙江农业学报 ›› 2024, Vol. 36 ›› Issue (7): 1548-1557.DOI: 10.3969/j.issn.1004-1524.20230791
文婷1,2(), 靳三鹏1, 刘德春1, 胡威1, 匡柳青1, 宋杰1, 朱昌3, 刘勇1, 杨莉1,*(
)
收稿日期:
2023-06-21
出版日期:
2024-07-25
发布日期:
2024-08-05
作者简介:
文婷(1997—),女,湖南桃江人,硕士研究生,主要从事果树发育生理研究。E-mail: 837834505@qq.com
通讯作者:
*杨莉,E-mail: yangli526526@126.com
基金资助:
WEN Ting1,2(), JIN Sanpeng1, LIU Dechun1, HU Wei1, KUANG Liuqing1, SONG Jie1, ZHU Chang3, LIU Yong1, YANG Li1,*(
)
Received:
2023-06-21
Online:
2024-07-25
Published:
2024-08-05
摘要:
以金沙柚为试验材料,不套袋为对照,采用不同透光率纸袋在盛花后80 d 进行套袋处理。分析套袋后不同发育时间油胞发育状况及成熟果皮挥发性成分含量变化。结果表明:套袋后油胞形态结构、横纵径无显著变化,但挥发性物质的种类和相对含量发生了变化。不套袋、单层白色纸袋和双层外红内黑纸袋处理分别检测到44、45和44种挥发性物质,均以萜烯类化合物为主,相对含量为75.77%~80.58%。两种套袋处理的萜烯类种类少于不套袋处理,三者共有萜烯类物质11种,都以D-柠檬烯相对含量最高,而双层纸袋处理D-柠檬烯高于不套袋和单层纸袋处理;两种套袋处理的醇类物质种类和相对含量高于不套袋处理,三者均以橙花醇和香叶醇为主;三者都包含两种检测到的醛类物质,并以柠檬醛为主,其中单层纸袋相对含量最高;酮类物质相对含量随光照减少而减少,其中不套袋以姜黄酮为主,单层和双层纸袋以圆柚酮为主;酯类中乙酸香叶酯相对含量最高,并且在各处理间差异很小;仅在单层纸袋处理中检测到微量的异香橙烯环氧化物。
中图分类号:
文婷, 靳三鹏, 刘德春, 胡威, 匡柳青, 宋杰, 朱昌, 刘勇, 杨莉. 套袋对金沙柚果皮油胞发育及挥发性成分的影响[J]. 浙江农业学报, 2024, 36(7): 1548-1557.
WEN Ting, JIN Sanpeng, LIU Dechun, HU Wei, KUANG Liuqing, SONG Jie, ZHU Chang, LIU Yong, YANG Li. Effects of bagging on oil cell development and volatile component in Jinsha pomelo pericarp[J]. Acta Agriculturae Zhejiangensis, 2024, 36(7): 1548-1557.
图1 不同套袋处理对果实油胞发育的影响 N,不套袋;D,套单层白色纸袋,透光率42.39%;B,套双层外红内黑纸袋,透光率0.02%。01,套袋后30 d;02,套袋后70 d;03,套袋后140 d。下同。
Fig.1 Effects of different bagging treatments on the development of fruit oil cells N, No bagging; D, Single-layer white paper bag, light transmittance of 42.39%; B, Double-layer outer red inner black paper bag, light transmittance of 0.02%. 01, 30 days after bagging; 02, 70 days after bagging; 03, 140 days after bagging. The same as below.
图2 不同套袋处理对果实发育期间油胞数量的影响 不同小写字母表示处理间差异显著性(P<0.05)。
Fig.2 Effects of different bagging treatments on the number of oil cells during fruit development Different lowercase letters indicate significant difference among treatments at 0.05 level.
图3 不同套袋处理对外果皮层油胞形态结构的影响 上图为横切观察,下图为纵切观察。
Fig.3 Effect of different bagging treatments on morphology and structure of oil cell in exocarp The upper image is cross-sectioned, the lower image is vertical sectioned.
套袋后天数 Days after bagging/d | 套袋处理Bagging treatment | |||||
---|---|---|---|---|---|---|
N | D | B | ||||
横径 Transverse diameter/μm | 纵径 Longitudinal diameter/μm | 横径 Transverse diameter/μm | 纵径 Longitudinal diameter/μm | 横径 Transverse diameter/μm | 纵径 Longitudinal diameter/μm | |
30 | 248.86±12.52 a | 390.55±43.63 a | 273.22±46.81 a | 307.38±70.22 a | 287.99±15.30 a | 404.35±89.59 a |
70 | 322.48±32.14 a | 370.02±52.57 a | 352.90±43.35 a | 399.23±51.40 a | 337.73±6.36 a | 416.84±19.32 a |
140 | 340.47±37.8 a | 442.32±35.95 a | 352.20±43.36 a | 476.40±23.32 a | 351.95±37.34 a | 455.65±15.97 a |
表1 不同套袋处理后果皮油胞大小变化
Table 1 Changes of oil cell diameter in fruit peel after different bagging treatments
套袋后天数 Days after bagging/d | 套袋处理Bagging treatment | |||||
---|---|---|---|---|---|---|
N | D | B | ||||
横径 Transverse diameter/μm | 纵径 Longitudinal diameter/μm | 横径 Transverse diameter/μm | 纵径 Longitudinal diameter/μm | 横径 Transverse diameter/μm | 纵径 Longitudinal diameter/μm | |
30 | 248.86±12.52 a | 390.55±43.63 a | 273.22±46.81 a | 307.38±70.22 a | 287.99±15.30 a | 404.35±89.59 a |
70 | 322.48±32.14 a | 370.02±52.57 a | 352.90±43.35 a | 399.23±51.40 a | 337.73±6.36 a | 416.84±19.32 a |
140 | 340.47±37.8 a | 442.32±35.95 a | 352.20±43.36 a | 476.40±23.32 a | 351.95±37.34 a | 455.65±15.97 a |
序号 No. | 萜烯类化合物名称 Terpene compound names | CAS编号 CAS No. | N03 | D03 | B03 | ||||||
---|---|---|---|---|---|---|---|---|---|---|---|
保留时间 Retention time/min | 定性 Qualita- tive | 相对含量 Relative content/% | 保留时间 Retention time/min | 定性 Qualita- tive | 相对含量 Relative content/% | 保留时间 Retention time/min | 定性 Qualita- tive | 相对含量 Relative content/% | |||
1 | α-蒎烯α-Pinene | 007785-26-4 | 5.811 | 96 | 0.33 | 5.818 | 97 | 0.45 | — | — | — |
2 | α-蒎烯α-Pinene | 007785-70-8 | 5.894 | 96 | 0.33 | 5.893 | 97 | 0.38 | 5.811 | 96 | 0.52 |
3 | β-蒎烯β-Pinene | 000127-91-3 | — | — | — | — | — | — | 6.928 | 94 | 1.40 |
4 | β-蒎烯β-Pinene | 018172-67-3 | 6.928 | 91 | 1.52 | — | — | — | — | — | — |
5 | 2-异丙烯基-2-蒎烯 | 1000151-27-0 | — | — | — | 25.386 | 46 | 0.12 | — | — | — |
2-Isopropenyl-2-pinene | |||||||||||
6 | β-月桂烯β-Myrcene | 000123-35-3 | 7.383 | 86 | 1.41 | 7.390 | 91 | 1.71 | — | — | — |
7 | D-柠檬烯D-Limonene | 005989-27-5 | 8.741 | 64 | 56.62 | — | — | — | — | — | — |
8 | δ-榄香烯δ-Elemene | 020307-84-0 | 15.981 | 97 | 0.80 | 15.981 | 97 | 0.79 | 15.981 | 98 | 0.99 |
9 | Β-榄香烯β-Elemene | 000515-13-9 | 17.188 | 99 | 0.74 | — | — | — | 17.181 | 98 | 0.56 |
10 | α-荜澄茄油烯α-Cubebene | 017699-14-8 | 16.250 | 98 | 0.20 | 16.250 | 97 | 0.18 | 16.243 | 98 | 0.16 |
11 | α-荜澄茄油烯α-Cubebene | 013744-15-5 | 17.981 | 96 | 0.49 | — | — | — | 17.974 | 96 | 0.30 |
12 | α-木罗烯α-Mulutene | 000483-75-0 | 17.774 | 95 | 1.23 | 19.139 | 90 | 8.09 | 17.767 | 93 | 0.97 |
13 | γ-榄香烯γ-Elemene | 030824-67-0 | 18.071 | 99 | 0.13 | 15.823 | 38 | 0.14 | 18.064 | 98 | 0.34 |
14 | d-大根香叶烯d-Germacrene | 023986-74-5 | 18.305 | 94 | 0.27 | 17.981 | 95 | 0.43 | 19.112 | 96 | 5.61 |
15 | 二环大根香叶烯 | 067650-90-2 | 19.408 | 91 | 1.95 | 19.408 | 91 | 1.81 | 19.394 | 91 | 1.31 |
Bicyclogermacrene | |||||||||||
16 | 佛手柑油烯Bergamotene | 017699-05-7 | 19.601 | 87 | 0.19 | — | — | — | — | — | — |
17 | Γ-杜松烯Γ-Cadinene | 030021-74-0 | 19.153 | 93 | 9.10 | — | — | — | 19.001 | 98 | 0.35 |
18 | 杜松烯Cadinene | 000483-76-1 | 19.926 | 96 | 0.66 | 19.925 | 95 | 0.61 | 19.918 | 96 | 0.47 |
19 | 杜松烯Cadinene | 016728-99-7 | 20.112 | 96 | 0.12 | 20.112 | 96 | 0.14 | 20.105 | 92 | 0.13 |
20 | 香橙烯Aromadendrene | 000489-39-4 | 22.553 | 78 | 0.28 | — | — | — | — | — | — |
21 | 桧烯Sabinene | 028634-89-1 | — | — | — | — | — | — | 7.383 | 78 | 2.49 |
22 | 桧烯Sabinene | 003387-41-5 | — | — | — | — | — | — | 7.672 | 86 | 0.20 |
23 | D-柠檬烯D-limonene | 000138-86-3 | — | — | — | 8.803 | 78 | 55.65 | 8.707 | 78 | 62.70 |
24 | 衣兰烯Ylangene | 014912-44-8 | — | — | — | — | — | — | 16.719 | 95 | 0.09 |
25 | α-丁香烯??-Caryophylene | 006753-98-6 | — | — | — | — | — | — | 18.484 | 64 | 0.26 |
26 | β-松油烯β - terpinene | 000099-84-3 | — | — | — | 6.935 | 91 | 1.06 | — | — | — |
27 | 水芹烯Phellandrene | 054324-03-7 | — | — | — | 18.698 | 94 | 0.49 | — | — | — |
28 | β-波旁烯β-bourbonene | 005208-59-3 | — | — | — | 20.953 | 47 | 0.11 | — | — | — |
29 | 古芸烯Gurjunene | 022567-17-5 | — | — | — | 22.552 | 90 | 0.25 | 22.546 | 89 | 0.15 |
30 | 鲨烯Squalene | 007683-64-9 | — | — | — | 16.567 | 59 | 0.84 | — | — | — |
31 | 1-羟基-1,7-二甲基-4-异丙基-2, | 072120-50-4 | 20.960 | 96 | 0.12 | — | — | — | 20.953 | 64 | 0.10 |
7-环癸二烯 | |||||||||||
1-hydroxy-1,7-dimethyl-4-isopropyl-2,7-cyclodecadiene | |||||||||||
32 | (Z)-1-甲氧基-3,7-二甲基,2-6 | 072152-72-8 | 16.568 | 72 | 0.69 | — | — | — | — | — | — |
辛二烯(Z) | |||||||||||
1-Methoxy-3,7-Dimethyl, 2-6-Octadiene | |||||||||||
33 | 7-乙烯基双环7-vinylbicyclo | 1000142-18-2 | 17.588 | 60 | 0.43 | — | — | — | — | — | — |
34 | 二环[4.4.0]癸-1-烯,2-异丙基- | 150320-52-8 | 18.698 | 91 | 0.59 | 17.774 | 90 | 1.20 | 18.691 | 91 | 0.43 |
5-甲基-9-亚甲基 | |||||||||||
Bicyclo[4.4.0] decane-1-ene, 2-isopropyl-5-methyl-9-methylene | |||||||||||
35 | (Z)-3,7-二甲基-1,3,6-十八烷 | 003338-55-4 | 8.983 | 97 | 0.96 | 9.010 | 97 | 1.32 | 8.962 | 97 | 1.05 |
三烯(Z) | |||||||||||
3,7-Dimethyl-1,3,6-octadecanetriene |
表2 不同套袋处理果皮萜烯类物质种类及相对含量
Table 2 The types and relative contents of terpenes in pericarp with different bagging treatments
序号 No. | 萜烯类化合物名称 Terpene compound names | CAS编号 CAS No. | N03 | D03 | B03 | ||||||
---|---|---|---|---|---|---|---|---|---|---|---|
保留时间 Retention time/min | 定性 Qualita- tive | 相对含量 Relative content/% | 保留时间 Retention time/min | 定性 Qualita- tive | 相对含量 Relative content/% | 保留时间 Retention time/min | 定性 Qualita- tive | 相对含量 Relative content/% | |||
1 | α-蒎烯α-Pinene | 007785-26-4 | 5.811 | 96 | 0.33 | 5.818 | 97 | 0.45 | — | — | — |
2 | α-蒎烯α-Pinene | 007785-70-8 | 5.894 | 96 | 0.33 | 5.893 | 97 | 0.38 | 5.811 | 96 | 0.52 |
3 | β-蒎烯β-Pinene | 000127-91-3 | — | — | — | — | — | — | 6.928 | 94 | 1.40 |
4 | β-蒎烯β-Pinene | 018172-67-3 | 6.928 | 91 | 1.52 | — | — | — | — | — | — |
5 | 2-异丙烯基-2-蒎烯 | 1000151-27-0 | — | — | — | 25.386 | 46 | 0.12 | — | — | — |
2-Isopropenyl-2-pinene | |||||||||||
6 | β-月桂烯β-Myrcene | 000123-35-3 | 7.383 | 86 | 1.41 | 7.390 | 91 | 1.71 | — | — | — |
7 | D-柠檬烯D-Limonene | 005989-27-5 | 8.741 | 64 | 56.62 | — | — | — | — | — | — |
8 | δ-榄香烯δ-Elemene | 020307-84-0 | 15.981 | 97 | 0.80 | 15.981 | 97 | 0.79 | 15.981 | 98 | 0.99 |
9 | Β-榄香烯β-Elemene | 000515-13-9 | 17.188 | 99 | 0.74 | — | — | — | 17.181 | 98 | 0.56 |
10 | α-荜澄茄油烯α-Cubebene | 017699-14-8 | 16.250 | 98 | 0.20 | 16.250 | 97 | 0.18 | 16.243 | 98 | 0.16 |
11 | α-荜澄茄油烯α-Cubebene | 013744-15-5 | 17.981 | 96 | 0.49 | — | — | — | 17.974 | 96 | 0.30 |
12 | α-木罗烯α-Mulutene | 000483-75-0 | 17.774 | 95 | 1.23 | 19.139 | 90 | 8.09 | 17.767 | 93 | 0.97 |
13 | γ-榄香烯γ-Elemene | 030824-67-0 | 18.071 | 99 | 0.13 | 15.823 | 38 | 0.14 | 18.064 | 98 | 0.34 |
14 | d-大根香叶烯d-Germacrene | 023986-74-5 | 18.305 | 94 | 0.27 | 17.981 | 95 | 0.43 | 19.112 | 96 | 5.61 |
15 | 二环大根香叶烯 | 067650-90-2 | 19.408 | 91 | 1.95 | 19.408 | 91 | 1.81 | 19.394 | 91 | 1.31 |
Bicyclogermacrene | |||||||||||
16 | 佛手柑油烯Bergamotene | 017699-05-7 | 19.601 | 87 | 0.19 | — | — | — | — | — | — |
17 | Γ-杜松烯Γ-Cadinene | 030021-74-0 | 19.153 | 93 | 9.10 | — | — | — | 19.001 | 98 | 0.35 |
18 | 杜松烯Cadinene | 000483-76-1 | 19.926 | 96 | 0.66 | 19.925 | 95 | 0.61 | 19.918 | 96 | 0.47 |
19 | 杜松烯Cadinene | 016728-99-7 | 20.112 | 96 | 0.12 | 20.112 | 96 | 0.14 | 20.105 | 92 | 0.13 |
20 | 香橙烯Aromadendrene | 000489-39-4 | 22.553 | 78 | 0.28 | — | — | — | — | — | — |
21 | 桧烯Sabinene | 028634-89-1 | — | — | — | — | — | — | 7.383 | 78 | 2.49 |
22 | 桧烯Sabinene | 003387-41-5 | — | — | — | — | — | — | 7.672 | 86 | 0.20 |
23 | D-柠檬烯D-limonene | 000138-86-3 | — | — | — | 8.803 | 78 | 55.65 | 8.707 | 78 | 62.70 |
24 | 衣兰烯Ylangene | 014912-44-8 | — | — | — | — | — | — | 16.719 | 95 | 0.09 |
25 | α-丁香烯??-Caryophylene | 006753-98-6 | — | — | — | — | — | — | 18.484 | 64 | 0.26 |
26 | β-松油烯β - terpinene | 000099-84-3 | — | — | — | 6.935 | 91 | 1.06 | — | — | — |
27 | 水芹烯Phellandrene | 054324-03-7 | — | — | — | 18.698 | 94 | 0.49 | — | — | — |
28 | β-波旁烯β-bourbonene | 005208-59-3 | — | — | — | 20.953 | 47 | 0.11 | — | — | — |
29 | 古芸烯Gurjunene | 022567-17-5 | — | — | — | 22.552 | 90 | 0.25 | 22.546 | 89 | 0.15 |
30 | 鲨烯Squalene | 007683-64-9 | — | — | — | 16.567 | 59 | 0.84 | — | — | — |
31 | 1-羟基-1,7-二甲基-4-异丙基-2, | 072120-50-4 | 20.960 | 96 | 0.12 | — | — | — | 20.953 | 64 | 0.10 |
7-环癸二烯 | |||||||||||
1-hydroxy-1,7-dimethyl-4-isopropyl-2,7-cyclodecadiene | |||||||||||
32 | (Z)-1-甲氧基-3,7-二甲基,2-6 | 072152-72-8 | 16.568 | 72 | 0.69 | — | — | — | — | — | — |
辛二烯(Z) | |||||||||||
1-Methoxy-3,7-Dimethyl, 2-6-Octadiene | |||||||||||
33 | 7-乙烯基双环7-vinylbicyclo | 1000142-18-2 | 17.588 | 60 | 0.43 | — | — | — | — | — | — |
34 | 二环[4.4.0]癸-1-烯,2-异丙基- | 150320-52-8 | 18.698 | 91 | 0.59 | 17.774 | 90 | 1.20 | 18.691 | 91 | 0.43 |
5-甲基-9-亚甲基 | |||||||||||
Bicyclo[4.4.0] decane-1-ene, 2-isopropyl-5-methyl-9-methylene | |||||||||||
35 | (Z)-3,7-二甲基-1,3,6-十八烷 | 003338-55-4 | 8.983 | 97 | 0.96 | 9.010 | 97 | 1.32 | 8.962 | 97 | 1.05 |
三烯(Z) | |||||||||||
3,7-Dimethyl-1,3,6-octadecanetriene |
序号 No. | 醇类化合物名称 Alcohol compound name | CAS编号 CAS No. | N03 | D03 | B03 | ||||||
---|---|---|---|---|---|---|---|---|---|---|---|
保留时间 Retention time/min | 定性 Qualita- tive | 相对含量 Relative content/% | 保留时间 Retention time/min | 定性 Qualita- tive | 相对含量 Relative content/% | 保留时间 Retention time/min | 定性 Qualita- tive | 相对含量 Relative content/% | |||
1 | 芳樟醇Linalool | 1000121-97-4 | — | — | — | 9.562 | 86 | 0.11 | — | — | — |
2 | 芳樟醇Linalool | 000078-70-6 | 10.265 | 70 | 0.84 | 10.279 | 94 | 1.21 | 10.265 | 93 | 1.20 |
3 | 松油醇Terpineol | 1000157-89-9 | 12.527 | 90 | 0.95 | 12.541 | 90 | 1.42 | 12.520 | 90 | 1.03 |
4 | 橙花醇Nerol | 000106-25-2 | 13.472 | 95 | 1.82 | 13.492 | 90 | 2.83 | 13.478 | 95 | 2.31 |
5 | 橙花叔醇Nerolidol | 007212-44-4 | 20.705 | 90 | 0.27 | 20.698 | 93 | 0.26 | 20.691 | 92 | 0.14 |
6 | 香叶醇Geraniol | 000624-15-7 | — | — | — | 14.140 | 91 | 2.87 | — | — | — |
7 | 香叶醇Geraniol | 000106-24-1 | 14.113 | 83 | 1.88 | — | — | — | 14.119 | 83 | 2.68 |
8 | 金合欢醇Farnesol | 004602-84-0 | — | — | — | 15.981 | 97 | 0.29 | 23.663 | 96 | 0.10 |
9 | 金合欢醇Farnesol | 004380-32-9 | 23.566 | 50 | 0.34 | — | — | — | — | — | — |
10 | 金合欢醇Farnesol | 003790-71-4 | 23.683 | 94 | 0.50 | — | — | — | — | — | — |
11 | 金合欢醇Farnesol | 000502-67-0 | 24.056 | 98 | 0.54 | 24.042 | 98 | 0.22 | — | — | — |
12 | 1-辛醇1-Octanol | 000111-87-5 | — | — | — | — | — | — | 9.513 | 90 | 0.10 |
13 | 香芹醇Carveol | 000099-48-9 | — | — | — | 17.588 | 55 | 0.49 | 17.581 | 60 | 0.24 |
14 | 紫苏醇Perilla alcohol | 000536-59-4 | — | — | — | — | — | — | 15.092 | 49 | 0.13 |
15 | α-杜松醇α-cadinol | 000481-34-5 | — | — | — | 22.463 | 93 | 0.14 | 22.456 | 96 | 0.08 |
16 | 松油烯-4-醇Terpinen-4-ol | 000562-74-3 | — | — | — | 12.182 | 96 | 0.13 | 12.175 | 96 | 0.13 |
表3 不同套袋处理果皮醇类物质种类及相对含量
Table 3 The types and relative contents of alcohols in pericarp with different bagging treatments
序号 No. | 醇类化合物名称 Alcohol compound name | CAS编号 CAS No. | N03 | D03 | B03 | ||||||
---|---|---|---|---|---|---|---|---|---|---|---|
保留时间 Retention time/min | 定性 Qualita- tive | 相对含量 Relative content/% | 保留时间 Retention time/min | 定性 Qualita- tive | 相对含量 Relative content/% | 保留时间 Retention time/min | 定性 Qualita- tive | 相对含量 Relative content/% | |||
1 | 芳樟醇Linalool | 1000121-97-4 | — | — | — | 9.562 | 86 | 0.11 | — | — | — |
2 | 芳樟醇Linalool | 000078-70-6 | 10.265 | 70 | 0.84 | 10.279 | 94 | 1.21 | 10.265 | 93 | 1.20 |
3 | 松油醇Terpineol | 1000157-89-9 | 12.527 | 90 | 0.95 | 12.541 | 90 | 1.42 | 12.520 | 90 | 1.03 |
4 | 橙花醇Nerol | 000106-25-2 | 13.472 | 95 | 1.82 | 13.492 | 90 | 2.83 | 13.478 | 95 | 2.31 |
5 | 橙花叔醇Nerolidol | 007212-44-4 | 20.705 | 90 | 0.27 | 20.698 | 93 | 0.26 | 20.691 | 92 | 0.14 |
6 | 香叶醇Geraniol | 000624-15-7 | — | — | — | 14.140 | 91 | 2.87 | — | — | — |
7 | 香叶醇Geraniol | 000106-24-1 | 14.113 | 83 | 1.88 | — | — | — | 14.119 | 83 | 2.68 |
8 | 金合欢醇Farnesol | 004602-84-0 | — | — | — | 15.981 | 97 | 0.29 | 23.663 | 96 | 0.10 |
9 | 金合欢醇Farnesol | 004380-32-9 | 23.566 | 50 | 0.34 | — | — | — | — | — | — |
10 | 金合欢醇Farnesol | 003790-71-4 | 23.683 | 94 | 0.50 | — | — | — | — | — | — |
11 | 金合欢醇Farnesol | 000502-67-0 | 24.056 | 98 | 0.54 | 24.042 | 98 | 0.22 | — | — | — |
12 | 1-辛醇1-Octanol | 000111-87-5 | — | — | — | — | — | — | 9.513 | 90 | 0.10 |
13 | 香芹醇Carveol | 000099-48-9 | — | — | — | 17.588 | 55 | 0.49 | 17.581 | 60 | 0.24 |
14 | 紫苏醇Perilla alcohol | 000536-59-4 | — | — | — | — | — | — | 15.092 | 49 | 0.13 |
15 | α-杜松醇α-cadinol | 000481-34-5 | — | — | — | 22.463 | 93 | 0.14 | 22.456 | 96 | 0.08 |
16 | 松油烯-4-醇Terpinen-4-ol | 000562-74-3 | — | — | — | 12.182 | 96 | 0.13 | 12.175 | 96 | 0.13 |
序号 No. | 醛类化合物名称 Aldehyde compound name | CAS编号 CAS No. | N03 | D03 | B03 | ||||||
---|---|---|---|---|---|---|---|---|---|---|---|
保留时间 Retention time/min | 定性 Qualita- tive | 相对含量 Relative content/% | 保留时间 Retention time/min | 定性 Qualita- tive | 相对含量 Relative content/% | 保留时间 Retention time/min | 定性 Qualita- tive | 相对含量 Relative content/% | |||
1 | 柠檬醛Citral | 005392-40-5 | 14.506 | 96 | 2.94 | 14.526 | 96 | 3.81 | 14.485 | 96 | 2.46 |
2 | (Z)-3,7-二甲基-2,6-辛二烯醛(Z) | 000106-26-3 | 13.775 | 95 | 1.67 | 13.795 | 96 | 2.21 | 13.768 | 95 | 1.44 |
3,7-dimethyl-2,6-octadienal |
表4 不同套袋处理果皮醛类物质种类及相对含量
Table 4 The types and relative contents of aldehydes in pericarp with different bagging treatments
序号 No. | 醛类化合物名称 Aldehyde compound name | CAS编号 CAS No. | N03 | D03 | B03 | ||||||
---|---|---|---|---|---|---|---|---|---|---|---|
保留时间 Retention time/min | 定性 Qualita- tive | 相对含量 Relative content/% | 保留时间 Retention time/min | 定性 Qualita- tive | 相对含量 Relative content/% | 保留时间 Retention time/min | 定性 Qualita- tive | 相对含量 Relative content/% | |||
1 | 柠檬醛Citral | 005392-40-5 | 14.506 | 96 | 2.94 | 14.526 | 96 | 3.81 | 14.485 | 96 | 2.46 |
2 | (Z)-3,7-二甲基-2,6-辛二烯醛(Z) | 000106-26-3 | 13.775 | 95 | 1.67 | 13.795 | 96 | 2.21 | 13.768 | 95 | 1.44 |
3,7-dimethyl-2,6-octadienal |
序号 No. | 酮类化合物名称 Ketone compound name | CAS编号 CAS No. | N03 | D03 | B03 | ||||||
---|---|---|---|---|---|---|---|---|---|---|---|
保留时间 Retention time/min | 定性 Qualita- tive | 相对含量 Relative content/% | 保留时间 Retention time/min | 定性 Qualita- tive | 相对含量 Relative content/% | 保留时间 Retention time/min | 定性 Qualita- tive | 相对含量 Relative content/% | |||
1 | 芳姜黄酮Arturrncrone | 1000292-71-0 | 22.663 | 98 | 0.39 | 22.649 | 95 | 0.15 | 22.642 | 95 | 0.09 |
2 | 姜黄酮Turmerone | 180315-67-7 | 22.739 | 97 | 0.46 | 22.725 | 97 | 0.24 | 22.718 | 97 | 0.10 |
3 | 姜黄酮Turmerone | 087440-60-6 | 23.332 | 95 | 0.23 | — | — | — | — | — | — |
4 | 圆柚酮Nootkatone | 004674-50-4 | 25.256 | 99 | 0.04 | 25.242 | 99 | 3.17 | 25.214 | 99 | 2.14 |
5 | 5,6-二甲氧基-1,2-茚二酮 | 040243-67-2 | 25.400 | 46 | 0.14 | — | — | — | — | — | — |
5,6-Dimethoxy-1,2-indindanone | |||||||||||
6 | (E,E)-3-[3,5-癸二烯基]-环戊酮 | 1000131-99-7 | — | — | — | 23.552 | 86 | 0.15 | — | — | — |
(E, E) -3-[3,5-decadienyl]-cyclopentanone |
表5 不同套袋处理果皮酮类物质种类及相对含量
Table 5 The types and relative contents of ketones in pericarp with different bagging treatments
序号 No. | 酮类化合物名称 Ketone compound name | CAS编号 CAS No. | N03 | D03 | B03 | ||||||
---|---|---|---|---|---|---|---|---|---|---|---|
保留时间 Retention time/min | 定性 Qualita- tive | 相对含量 Relative content/% | 保留时间 Retention time/min | 定性 Qualita- tive | 相对含量 Relative content/% | 保留时间 Retention time/min | 定性 Qualita- tive | 相对含量 Relative content/% | |||
1 | 芳姜黄酮Arturrncrone | 1000292-71-0 | 22.663 | 98 | 0.39 | 22.649 | 95 | 0.15 | 22.642 | 95 | 0.09 |
2 | 姜黄酮Turmerone | 180315-67-7 | 22.739 | 97 | 0.46 | 22.725 | 97 | 0.24 | 22.718 | 97 | 0.10 |
3 | 姜黄酮Turmerone | 087440-60-6 | 23.332 | 95 | 0.23 | — | — | — | — | — | — |
4 | 圆柚酮Nootkatone | 004674-50-4 | 25.256 | 99 | 0.04 | 25.242 | 99 | 3.17 | 25.214 | 99 | 2.14 |
5 | 5,6-二甲氧基-1,2-茚二酮 | 040243-67-2 | 25.400 | 46 | 0.14 | — | — | — | — | — | — |
5,6-Dimethoxy-1,2-indindanone | |||||||||||
6 | (E,E)-3-[3,5-癸二烯基]-环戊酮 | 1000131-99-7 | — | — | — | 23.552 | 86 | 0.15 | — | — | — |
(E, E) -3-[3,5-decadienyl]-cyclopentanone |
序号 No. | 酯类化合物名称 Ester compound name | CAS编号 CAS No. | N03 | D03 | B03 | ||||||
---|---|---|---|---|---|---|---|---|---|---|---|
保留时间 Retention time/min | 定性 Qualita- tive | 相对含量 Relative content/% | 保留时间 Retention time/min | 定性 Qualita- tive | 相对含量 Relative content/% | 保留时间 Retention time/min | 定性 Qualita- tive | 相对含量 Relative content/% | |||
1 | 甲酸芳樟酯Linalyl formate | 000115-99-1 | — | — | — | — | — | — | 16.340 | 64 | 0.13 |
2 | 乙酸香芹酯Carvyl acetate | 001197-06-4 | 13.216 | 55 | 0.20 | 13.216 | 95 | 0.25 | 13.209 | 95 | 0.22 |
3 | 乙酸香叶酯Acetate geranyl ester | 000105-87-3 | 17.002 | 91 | 0.80 | 17.002 | 91 | 0.85 | 16.995 | 91 | 0.79 |
4 | 丙酸橙花酯Neryl propionate | 000105-91-9 | — | — | — | 16.340 | 64 | 0.14 | — | — | — |
5 | 棕榈酸甲酯Methyl palmitate | 000112-39-0 | 27.173 | 99 | 0.13 | — | — | — | — | — | — |
表6 不同套袋处理果皮酯类物质种类及相对含量
Table 6 The types and relative contents of esters in pericarp with different bagging treatments
序号 No. | 酯类化合物名称 Ester compound name | CAS编号 CAS No. | N03 | D03 | B03 | ||||||
---|---|---|---|---|---|---|---|---|---|---|---|
保留时间 Retention time/min | 定性 Qualita- tive | 相对含量 Relative content/% | 保留时间 Retention time/min | 定性 Qualita- tive | 相对含量 Relative content/% | 保留时间 Retention time/min | 定性 Qualita- tive | 相对含量 Relative content/% | |||
1 | 甲酸芳樟酯Linalyl formate | 000115-99-1 | — | — | — | — | — | — | 16.340 | 64 | 0.13 |
2 | 乙酸香芹酯Carvyl acetate | 001197-06-4 | 13.216 | 55 | 0.20 | 13.216 | 95 | 0.25 | 13.209 | 95 | 0.22 |
3 | 乙酸香叶酯Acetate geranyl ester | 000105-87-3 | 17.002 | 91 | 0.80 | 17.002 | 91 | 0.85 | 16.995 | 91 | 0.79 |
4 | 丙酸橙花酯Neryl propionate | 000105-91-9 | — | — | — | 16.340 | 64 | 0.14 | — | — | — |
5 | 棕榈酸甲酯Methyl palmitate | 000112-39-0 | 27.173 | 99 | 0.13 | — | — | — | — | — | — |
序号 No. | 酸类化合物名称 Acidic compound name | CAS编号 CAS No. | N03 | D03 | B03 | ||||||
---|---|---|---|---|---|---|---|---|---|---|---|
保留时间 Retention time/min | 定性 Qualita- tive | 相对含量 Relative content/% | 保留时间 Retention time/min | 定性 Qualita- tive | 相对含量 Relative content/% | 保留时间 Retention time/min | 定性 Qualita- tive | 相对含量 Relative content/% | |||
1 | 棕榈酸Palmitic acid | 000057-10-3 | 27.738 | 98 | 0.15 | — | — | — | — | — | — |
2 | 棕榈酸Palmitic acid | 000628-97-7 | 28.276 | 98 | 0.13 | — | — | — | — | — | — |
3 | 香叶酸Vanillic acid | 000459-80-3 | — | — | — | — | — | — | 16.560 | 68 | 0.64 |
表7 不同套袋处理果皮酸类物质种类及相对含量
Table 7 The types and relative contents of acids in pericarp with different bagging treatments
序号 No. | 酸类化合物名称 Acidic compound name | CAS编号 CAS No. | N03 | D03 | B03 | ||||||
---|---|---|---|---|---|---|---|---|---|---|---|
保留时间 Retention time/min | 定性 Qualita- tive | 相对含量 Relative content/% | 保留时间 Retention time/min | 定性 Qualita- tive | 相对含量 Relative content/% | 保留时间 Retention time/min | 定性 Qualita- tive | 相对含量 Relative content/% | |||
1 | 棕榈酸Palmitic acid | 000057-10-3 | 27.738 | 98 | 0.15 | — | — | — | — | — | — |
2 | 棕榈酸Palmitic acid | 000628-97-7 | 28.276 | 98 | 0.13 | — | — | — | — | — | — |
3 | 香叶酸Vanillic acid | 000459-80-3 | — | — | — | — | — | — | 16.560 | 68 | 0.64 |
序号 No. | 氧化物名称 Oxide name | CAS编号 CAS No. | N03 | D03 | B03 | ||||||
---|---|---|---|---|---|---|---|---|---|---|---|
保留时间 Retention time/min | 定性 Qualita- tive | 相对含量 Relative content/% | 保留时间 Retention time/min | 定性 Qualita- tive | 相对含量 Relative content/% | 保留时间 Retention time/min | 定性 Qualita- tive | 相对含量 Relative content/% | |||
1 | 异香橙烯环氧化物 | 1000159-36-6 | — | — | — | 23.056 | 35 | 0.12 | — | — | — |
Isobromene epoxide |
表8 不同套袋处理果皮氧化物种类及相对含量
Table 8 The types and relative content of oxides in pericarp with different bagging treatments
序号 No. | 氧化物名称 Oxide name | CAS编号 CAS No. | N03 | D03 | B03 | ||||||
---|---|---|---|---|---|---|---|---|---|---|---|
保留时间 Retention time/min | 定性 Qualita- tive | 相对含量 Relative content/% | 保留时间 Retention time/min | 定性 Qualita- tive | 相对含量 Relative content/% | 保留时间 Retention time/min | 定性 Qualita- tive | 相对含量 Relative content/% | |||
1 | 异香橙烯环氧化物 | 1000159-36-6 | — | — | — | 23.056 | 35 | 0.12 | — | — | — |
Isobromene epoxide |
序号 No. | 其他化合物名称 Other compound name | CAS编号 CAS No. | N03 | D03 | B03 | ||||||
---|---|---|---|---|---|---|---|---|---|---|---|
保留时间 Retention time/min | 定性 Qualita- tive | 相对含量 Relative content/% | 保留时间 Retention time/min | 定性 Qualita- tive | 相对含量 Relative content/% | 保留时间 Retention time/min | 定性 Qualita- tive | 相对含量 Relative content/% | |||
1 | 1-乙烯基-1-甲基-2,4-二(丙-1-烯- | 110823-68-2 | — | — | — | 17.181 | 97 | 0.66 | — | — | — |
2-基)环己烷 | |||||||||||
1-Vinyl-1-methyl-2,4-di (propane-1-en-2-yl) cyclohexane | |||||||||||
2 | 吲哚Indole | 000120-72-9 | 15.002 | 95 | 2.63 | 14.995 | 94 | 2.22 | 15.002 | 94 | 3.15 |
3 | 1,2,4a,5,6,8a-六氢-1-异丙基-4, | 024406-05-1 | — | — | — | 20.201 | 97 | 14.00 | 20.201 | 97 | 0.12 |
7-二甲基萘 | |||||||||||
1,2,4a, 5,6,8a hexahydro-1-isopropyl-4,7-dimethylnaphthalene | |||||||||||
4 | 2-氯-3-甲氧基丙脒盐酸盐 | 1000234-64-1 | — | — | — | 15.823 | 38 | 0.14 | — | — | — |
2-Chloro-3-methoxypropamidine hydrochloride |
表9 不同套袋处理果皮其他化合物种类及相对含量
Table 9 The types and relative contents of other compounds in pericarp with different bagging treatments
序号 No. | 其他化合物名称 Other compound name | CAS编号 CAS No. | N03 | D03 | B03 | ||||||
---|---|---|---|---|---|---|---|---|---|---|---|
保留时间 Retention time/min | 定性 Qualita- tive | 相对含量 Relative content/% | 保留时间 Retention time/min | 定性 Qualita- tive | 相对含量 Relative content/% | 保留时间 Retention time/min | 定性 Qualita- tive | 相对含量 Relative content/% | |||
1 | 1-乙烯基-1-甲基-2,4-二(丙-1-烯- | 110823-68-2 | — | — | — | 17.181 | 97 | 0.66 | — | — | — |
2-基)环己烷 | |||||||||||
1-Vinyl-1-methyl-2,4-di (propane-1-en-2-yl) cyclohexane | |||||||||||
2 | 吲哚Indole | 000120-72-9 | 15.002 | 95 | 2.63 | 14.995 | 94 | 2.22 | 15.002 | 94 | 3.15 |
3 | 1,2,4a,5,6,8a-六氢-1-异丙基-4, | 024406-05-1 | — | — | — | 20.201 | 97 | 14.00 | 20.201 | 97 | 0.12 |
7-二甲基萘 | |||||||||||
1,2,4a, 5,6,8a hexahydro-1-isopropyl-4,7-dimethylnaphthalene | |||||||||||
4 | 2-氯-3-甲氧基丙脒盐酸盐 | 1000234-64-1 | — | — | — | 15.823 | 38 | 0.14 | — | — | — |
2-Chloro-3-methoxypropamidine hydrochloride |
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