Acta Agriculturae Zhejiangensis ›› 2024, Vol. 36 ›› Issue (7): 1548-1557.DOI: 10.3969/j.issn.1004-1524.20230791
• Horticultural Science • Previous Articles Next Articles
WEN Ting1,2(), JIN Sanpeng1, LIU Dechun1, HU Wei1, KUANG Liuqing1, SONG Jie1, ZHU Chang3, LIU Yong1, YANG Li1,*(
)
Received:
2023-06-21
Online:
2024-07-25
Published:
2024-08-05
CLC Number:
WEN Ting, JIN Sanpeng, LIU Dechun, HU Wei, KUANG Liuqing, SONG Jie, ZHU Chang, LIU Yong, YANG Li. Effects of bagging on oil cell development and volatile component in Jinsha pomelo pericarp[J]. Acta Agriculturae Zhejiangensis, 2024, 36(7): 1548-1557.
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URL: http://www.zjnyxb.cn/EN/10.3969/j.issn.1004-1524.20230791
Fig.1 Effects of different bagging treatments on the development of fruit oil cells N, No bagging; D, Single-layer white paper bag, light transmittance of 42.39%; B, Double-layer outer red inner black paper bag, light transmittance of 0.02%. 01, 30 days after bagging; 02, 70 days after bagging; 03, 140 days after bagging. The same as below.
Fig.2 Effects of different bagging treatments on the number of oil cells during fruit development Different lowercase letters indicate significant difference among treatments at 0.05 level.
Fig.3 Effect of different bagging treatments on morphology and structure of oil cell in exocarp The upper image is cross-sectioned, the lower image is vertical sectioned.
套袋后天数 Days after bagging/d | 套袋处理Bagging treatment | |||||
---|---|---|---|---|---|---|
N | D | B | ||||
横径 Transverse diameter/μm | 纵径 Longitudinal diameter/μm | 横径 Transverse diameter/μm | 纵径 Longitudinal diameter/μm | 横径 Transverse diameter/μm | 纵径 Longitudinal diameter/μm | |
30 | 248.86±12.52 a | 390.55±43.63 a | 273.22±46.81 a | 307.38±70.22 a | 287.99±15.30 a | 404.35±89.59 a |
70 | 322.48±32.14 a | 370.02±52.57 a | 352.90±43.35 a | 399.23±51.40 a | 337.73±6.36 a | 416.84±19.32 a |
140 | 340.47±37.8 a | 442.32±35.95 a | 352.20±43.36 a | 476.40±23.32 a | 351.95±37.34 a | 455.65±15.97 a |
Table 1 Changes of oil cell diameter in fruit peel after different bagging treatments
套袋后天数 Days after bagging/d | 套袋处理Bagging treatment | |||||
---|---|---|---|---|---|---|
N | D | B | ||||
横径 Transverse diameter/μm | 纵径 Longitudinal diameter/μm | 横径 Transverse diameter/μm | 纵径 Longitudinal diameter/μm | 横径 Transverse diameter/μm | 纵径 Longitudinal diameter/μm | |
30 | 248.86±12.52 a | 390.55±43.63 a | 273.22±46.81 a | 307.38±70.22 a | 287.99±15.30 a | 404.35±89.59 a |
70 | 322.48±32.14 a | 370.02±52.57 a | 352.90±43.35 a | 399.23±51.40 a | 337.73±6.36 a | 416.84±19.32 a |
140 | 340.47±37.8 a | 442.32±35.95 a | 352.20±43.36 a | 476.40±23.32 a | 351.95±37.34 a | 455.65±15.97 a |
序号 No. | 萜烯类化合物名称 Terpene compound names | CAS编号 CAS No. | N03 | D03 | B03 | ||||||
---|---|---|---|---|---|---|---|---|---|---|---|
保留时间 Retention time/min | 定性 Qualita- tive | 相对含量 Relative content/% | 保留时间 Retention time/min | 定性 Qualita- tive | 相对含量 Relative content/% | 保留时间 Retention time/min | 定性 Qualita- tive | 相对含量 Relative content/% | |||
1 | α-蒎烯α-Pinene | 007785-26-4 | 5.811 | 96 | 0.33 | 5.818 | 97 | 0.45 | — | — | — |
2 | α-蒎烯α-Pinene | 007785-70-8 | 5.894 | 96 | 0.33 | 5.893 | 97 | 0.38 | 5.811 | 96 | 0.52 |
3 | β-蒎烯β-Pinene | 000127-91-3 | — | — | — | — | — | — | 6.928 | 94 | 1.40 |
4 | β-蒎烯β-Pinene | 018172-67-3 | 6.928 | 91 | 1.52 | — | — | — | — | — | — |
5 | 2-异丙烯基-2-蒎烯 | 1000151-27-0 | — | — | — | 25.386 | 46 | 0.12 | — | — | — |
2-Isopropenyl-2-pinene | |||||||||||
6 | β-月桂烯β-Myrcene | 000123-35-3 | 7.383 | 86 | 1.41 | 7.390 | 91 | 1.71 | — | — | — |
7 | D-柠檬烯D-Limonene | 005989-27-5 | 8.741 | 64 | 56.62 | — | — | — | — | — | — |
8 | δ-榄香烯δ-Elemene | 020307-84-0 | 15.981 | 97 | 0.80 | 15.981 | 97 | 0.79 | 15.981 | 98 | 0.99 |
9 | Β-榄香烯β-Elemene | 000515-13-9 | 17.188 | 99 | 0.74 | — | — | — | 17.181 | 98 | 0.56 |
10 | α-荜澄茄油烯α-Cubebene | 017699-14-8 | 16.250 | 98 | 0.20 | 16.250 | 97 | 0.18 | 16.243 | 98 | 0.16 |
11 | α-荜澄茄油烯α-Cubebene | 013744-15-5 | 17.981 | 96 | 0.49 | — | — | — | 17.974 | 96 | 0.30 |
12 | α-木罗烯α-Mulutene | 000483-75-0 | 17.774 | 95 | 1.23 | 19.139 | 90 | 8.09 | 17.767 | 93 | 0.97 |
13 | γ-榄香烯γ-Elemene | 030824-67-0 | 18.071 | 99 | 0.13 | 15.823 | 38 | 0.14 | 18.064 | 98 | 0.34 |
14 | d-大根香叶烯d-Germacrene | 023986-74-5 | 18.305 | 94 | 0.27 | 17.981 | 95 | 0.43 | 19.112 | 96 | 5.61 |
15 | 二环大根香叶烯 | 067650-90-2 | 19.408 | 91 | 1.95 | 19.408 | 91 | 1.81 | 19.394 | 91 | 1.31 |
Bicyclogermacrene | |||||||||||
16 | 佛手柑油烯Bergamotene | 017699-05-7 | 19.601 | 87 | 0.19 | — | — | — | — | — | — |
17 | Γ-杜松烯Γ-Cadinene | 030021-74-0 | 19.153 | 93 | 9.10 | — | — | — | 19.001 | 98 | 0.35 |
18 | 杜松烯Cadinene | 000483-76-1 | 19.926 | 96 | 0.66 | 19.925 | 95 | 0.61 | 19.918 | 96 | 0.47 |
19 | 杜松烯Cadinene | 016728-99-7 | 20.112 | 96 | 0.12 | 20.112 | 96 | 0.14 | 20.105 | 92 | 0.13 |
20 | 香橙烯Aromadendrene | 000489-39-4 | 22.553 | 78 | 0.28 | — | — | — | — | — | — |
21 | 桧烯Sabinene | 028634-89-1 | — | — | — | — | — | — | 7.383 | 78 | 2.49 |
22 | 桧烯Sabinene | 003387-41-5 | — | — | — | — | — | — | 7.672 | 86 | 0.20 |
23 | D-柠檬烯D-limonene | 000138-86-3 | — | — | — | 8.803 | 78 | 55.65 | 8.707 | 78 | 62.70 |
24 | 衣兰烯Ylangene | 014912-44-8 | — | — | — | — | — | — | 16.719 | 95 | 0.09 |
25 | α-丁香烯??-Caryophylene | 006753-98-6 | — | — | — | — | — | — | 18.484 | 64 | 0.26 |
26 | β-松油烯β - terpinene | 000099-84-3 | — | — | — | 6.935 | 91 | 1.06 | — | — | — |
27 | 水芹烯Phellandrene | 054324-03-7 | — | — | — | 18.698 | 94 | 0.49 | — | — | — |
28 | β-波旁烯β-bourbonene | 005208-59-3 | — | — | — | 20.953 | 47 | 0.11 | — | — | — |
29 | 古芸烯Gurjunene | 022567-17-5 | — | — | — | 22.552 | 90 | 0.25 | 22.546 | 89 | 0.15 |
30 | 鲨烯Squalene | 007683-64-9 | — | — | — | 16.567 | 59 | 0.84 | — | — | — |
31 | 1-羟基-1,7-二甲基-4-异丙基-2, | 072120-50-4 | 20.960 | 96 | 0.12 | — | — | — | 20.953 | 64 | 0.10 |
7-环癸二烯 | |||||||||||
1-hydroxy-1,7-dimethyl-4-isopropyl-2,7-cyclodecadiene | |||||||||||
32 | (Z)-1-甲氧基-3,7-二甲基,2-6 | 072152-72-8 | 16.568 | 72 | 0.69 | — | — | — | — | — | — |
辛二烯(Z) | |||||||||||
1-Methoxy-3,7-Dimethyl, 2-6-Octadiene | |||||||||||
33 | 7-乙烯基双环7-vinylbicyclo | 1000142-18-2 | 17.588 | 60 | 0.43 | — | — | — | — | — | — |
34 | 二环[4.4.0]癸-1-烯,2-异丙基- | 150320-52-8 | 18.698 | 91 | 0.59 | 17.774 | 90 | 1.20 | 18.691 | 91 | 0.43 |
5-甲基-9-亚甲基 | |||||||||||
Bicyclo[4.4.0] decane-1-ene, 2-isopropyl-5-methyl-9-methylene | |||||||||||
35 | (Z)-3,7-二甲基-1,3,6-十八烷 | 003338-55-4 | 8.983 | 97 | 0.96 | 9.010 | 97 | 1.32 | 8.962 | 97 | 1.05 |
三烯(Z) | |||||||||||
3,7-Dimethyl-1,3,6-octadecanetriene |
Table 2 The types and relative contents of terpenes in pericarp with different bagging treatments
序号 No. | 萜烯类化合物名称 Terpene compound names | CAS编号 CAS No. | N03 | D03 | B03 | ||||||
---|---|---|---|---|---|---|---|---|---|---|---|
保留时间 Retention time/min | 定性 Qualita- tive | 相对含量 Relative content/% | 保留时间 Retention time/min | 定性 Qualita- tive | 相对含量 Relative content/% | 保留时间 Retention time/min | 定性 Qualita- tive | 相对含量 Relative content/% | |||
1 | α-蒎烯α-Pinene | 007785-26-4 | 5.811 | 96 | 0.33 | 5.818 | 97 | 0.45 | — | — | — |
2 | α-蒎烯α-Pinene | 007785-70-8 | 5.894 | 96 | 0.33 | 5.893 | 97 | 0.38 | 5.811 | 96 | 0.52 |
3 | β-蒎烯β-Pinene | 000127-91-3 | — | — | — | — | — | — | 6.928 | 94 | 1.40 |
4 | β-蒎烯β-Pinene | 018172-67-3 | 6.928 | 91 | 1.52 | — | — | — | — | — | — |
5 | 2-异丙烯基-2-蒎烯 | 1000151-27-0 | — | — | — | 25.386 | 46 | 0.12 | — | — | — |
2-Isopropenyl-2-pinene | |||||||||||
6 | β-月桂烯β-Myrcene | 000123-35-3 | 7.383 | 86 | 1.41 | 7.390 | 91 | 1.71 | — | — | — |
7 | D-柠檬烯D-Limonene | 005989-27-5 | 8.741 | 64 | 56.62 | — | — | — | — | — | — |
8 | δ-榄香烯δ-Elemene | 020307-84-0 | 15.981 | 97 | 0.80 | 15.981 | 97 | 0.79 | 15.981 | 98 | 0.99 |
9 | Β-榄香烯β-Elemene | 000515-13-9 | 17.188 | 99 | 0.74 | — | — | — | 17.181 | 98 | 0.56 |
10 | α-荜澄茄油烯α-Cubebene | 017699-14-8 | 16.250 | 98 | 0.20 | 16.250 | 97 | 0.18 | 16.243 | 98 | 0.16 |
11 | α-荜澄茄油烯α-Cubebene | 013744-15-5 | 17.981 | 96 | 0.49 | — | — | — | 17.974 | 96 | 0.30 |
12 | α-木罗烯α-Mulutene | 000483-75-0 | 17.774 | 95 | 1.23 | 19.139 | 90 | 8.09 | 17.767 | 93 | 0.97 |
13 | γ-榄香烯γ-Elemene | 030824-67-0 | 18.071 | 99 | 0.13 | 15.823 | 38 | 0.14 | 18.064 | 98 | 0.34 |
14 | d-大根香叶烯d-Germacrene | 023986-74-5 | 18.305 | 94 | 0.27 | 17.981 | 95 | 0.43 | 19.112 | 96 | 5.61 |
15 | 二环大根香叶烯 | 067650-90-2 | 19.408 | 91 | 1.95 | 19.408 | 91 | 1.81 | 19.394 | 91 | 1.31 |
Bicyclogermacrene | |||||||||||
16 | 佛手柑油烯Bergamotene | 017699-05-7 | 19.601 | 87 | 0.19 | — | — | — | — | — | — |
17 | Γ-杜松烯Γ-Cadinene | 030021-74-0 | 19.153 | 93 | 9.10 | — | — | — | 19.001 | 98 | 0.35 |
18 | 杜松烯Cadinene | 000483-76-1 | 19.926 | 96 | 0.66 | 19.925 | 95 | 0.61 | 19.918 | 96 | 0.47 |
19 | 杜松烯Cadinene | 016728-99-7 | 20.112 | 96 | 0.12 | 20.112 | 96 | 0.14 | 20.105 | 92 | 0.13 |
20 | 香橙烯Aromadendrene | 000489-39-4 | 22.553 | 78 | 0.28 | — | — | — | — | — | — |
21 | 桧烯Sabinene | 028634-89-1 | — | — | — | — | — | — | 7.383 | 78 | 2.49 |
22 | 桧烯Sabinene | 003387-41-5 | — | — | — | — | — | — | 7.672 | 86 | 0.20 |
23 | D-柠檬烯D-limonene | 000138-86-3 | — | — | — | 8.803 | 78 | 55.65 | 8.707 | 78 | 62.70 |
24 | 衣兰烯Ylangene | 014912-44-8 | — | — | — | — | — | — | 16.719 | 95 | 0.09 |
25 | α-丁香烯??-Caryophylene | 006753-98-6 | — | — | — | — | — | — | 18.484 | 64 | 0.26 |
26 | β-松油烯β - terpinene | 000099-84-3 | — | — | — | 6.935 | 91 | 1.06 | — | — | — |
27 | 水芹烯Phellandrene | 054324-03-7 | — | — | — | 18.698 | 94 | 0.49 | — | — | — |
28 | β-波旁烯β-bourbonene | 005208-59-3 | — | — | — | 20.953 | 47 | 0.11 | — | — | — |
29 | 古芸烯Gurjunene | 022567-17-5 | — | — | — | 22.552 | 90 | 0.25 | 22.546 | 89 | 0.15 |
30 | 鲨烯Squalene | 007683-64-9 | — | — | — | 16.567 | 59 | 0.84 | — | — | — |
31 | 1-羟基-1,7-二甲基-4-异丙基-2, | 072120-50-4 | 20.960 | 96 | 0.12 | — | — | — | 20.953 | 64 | 0.10 |
7-环癸二烯 | |||||||||||
1-hydroxy-1,7-dimethyl-4-isopropyl-2,7-cyclodecadiene | |||||||||||
32 | (Z)-1-甲氧基-3,7-二甲基,2-6 | 072152-72-8 | 16.568 | 72 | 0.69 | — | — | — | — | — | — |
辛二烯(Z) | |||||||||||
1-Methoxy-3,7-Dimethyl, 2-6-Octadiene | |||||||||||
33 | 7-乙烯基双环7-vinylbicyclo | 1000142-18-2 | 17.588 | 60 | 0.43 | — | — | — | — | — | — |
34 | 二环[4.4.0]癸-1-烯,2-异丙基- | 150320-52-8 | 18.698 | 91 | 0.59 | 17.774 | 90 | 1.20 | 18.691 | 91 | 0.43 |
5-甲基-9-亚甲基 | |||||||||||
Bicyclo[4.4.0] decane-1-ene, 2-isopropyl-5-methyl-9-methylene | |||||||||||
35 | (Z)-3,7-二甲基-1,3,6-十八烷 | 003338-55-4 | 8.983 | 97 | 0.96 | 9.010 | 97 | 1.32 | 8.962 | 97 | 1.05 |
三烯(Z) | |||||||||||
3,7-Dimethyl-1,3,6-octadecanetriene |
序号 No. | 醇类化合物名称 Alcohol compound name | CAS编号 CAS No. | N03 | D03 | B03 | ||||||
---|---|---|---|---|---|---|---|---|---|---|---|
保留时间 Retention time/min | 定性 Qualita- tive | 相对含量 Relative content/% | 保留时间 Retention time/min | 定性 Qualita- tive | 相对含量 Relative content/% | 保留时间 Retention time/min | 定性 Qualita- tive | 相对含量 Relative content/% | |||
1 | 芳樟醇Linalool | 1000121-97-4 | — | — | — | 9.562 | 86 | 0.11 | — | — | — |
2 | 芳樟醇Linalool | 000078-70-6 | 10.265 | 70 | 0.84 | 10.279 | 94 | 1.21 | 10.265 | 93 | 1.20 |
3 | 松油醇Terpineol | 1000157-89-9 | 12.527 | 90 | 0.95 | 12.541 | 90 | 1.42 | 12.520 | 90 | 1.03 |
4 | 橙花醇Nerol | 000106-25-2 | 13.472 | 95 | 1.82 | 13.492 | 90 | 2.83 | 13.478 | 95 | 2.31 |
5 | 橙花叔醇Nerolidol | 007212-44-4 | 20.705 | 90 | 0.27 | 20.698 | 93 | 0.26 | 20.691 | 92 | 0.14 |
6 | 香叶醇Geraniol | 000624-15-7 | — | — | — | 14.140 | 91 | 2.87 | — | — | — |
7 | 香叶醇Geraniol | 000106-24-1 | 14.113 | 83 | 1.88 | — | — | — | 14.119 | 83 | 2.68 |
8 | 金合欢醇Farnesol | 004602-84-0 | — | — | — | 15.981 | 97 | 0.29 | 23.663 | 96 | 0.10 |
9 | 金合欢醇Farnesol | 004380-32-9 | 23.566 | 50 | 0.34 | — | — | — | — | — | — |
10 | 金合欢醇Farnesol | 003790-71-4 | 23.683 | 94 | 0.50 | — | — | — | — | — | — |
11 | 金合欢醇Farnesol | 000502-67-0 | 24.056 | 98 | 0.54 | 24.042 | 98 | 0.22 | — | — | — |
12 | 1-辛醇1-Octanol | 000111-87-5 | — | — | — | — | — | — | 9.513 | 90 | 0.10 |
13 | 香芹醇Carveol | 000099-48-9 | — | — | — | 17.588 | 55 | 0.49 | 17.581 | 60 | 0.24 |
14 | 紫苏醇Perilla alcohol | 000536-59-4 | — | — | — | — | — | — | 15.092 | 49 | 0.13 |
15 | α-杜松醇α-cadinol | 000481-34-5 | — | — | — | 22.463 | 93 | 0.14 | 22.456 | 96 | 0.08 |
16 | 松油烯-4-醇Terpinen-4-ol | 000562-74-3 | — | — | — | 12.182 | 96 | 0.13 | 12.175 | 96 | 0.13 |
Table 3 The types and relative contents of alcohols in pericarp with different bagging treatments
序号 No. | 醇类化合物名称 Alcohol compound name | CAS编号 CAS No. | N03 | D03 | B03 | ||||||
---|---|---|---|---|---|---|---|---|---|---|---|
保留时间 Retention time/min | 定性 Qualita- tive | 相对含量 Relative content/% | 保留时间 Retention time/min | 定性 Qualita- tive | 相对含量 Relative content/% | 保留时间 Retention time/min | 定性 Qualita- tive | 相对含量 Relative content/% | |||
1 | 芳樟醇Linalool | 1000121-97-4 | — | — | — | 9.562 | 86 | 0.11 | — | — | — |
2 | 芳樟醇Linalool | 000078-70-6 | 10.265 | 70 | 0.84 | 10.279 | 94 | 1.21 | 10.265 | 93 | 1.20 |
3 | 松油醇Terpineol | 1000157-89-9 | 12.527 | 90 | 0.95 | 12.541 | 90 | 1.42 | 12.520 | 90 | 1.03 |
4 | 橙花醇Nerol | 000106-25-2 | 13.472 | 95 | 1.82 | 13.492 | 90 | 2.83 | 13.478 | 95 | 2.31 |
5 | 橙花叔醇Nerolidol | 007212-44-4 | 20.705 | 90 | 0.27 | 20.698 | 93 | 0.26 | 20.691 | 92 | 0.14 |
6 | 香叶醇Geraniol | 000624-15-7 | — | — | — | 14.140 | 91 | 2.87 | — | — | — |
7 | 香叶醇Geraniol | 000106-24-1 | 14.113 | 83 | 1.88 | — | — | — | 14.119 | 83 | 2.68 |
8 | 金合欢醇Farnesol | 004602-84-0 | — | — | — | 15.981 | 97 | 0.29 | 23.663 | 96 | 0.10 |
9 | 金合欢醇Farnesol | 004380-32-9 | 23.566 | 50 | 0.34 | — | — | — | — | — | — |
10 | 金合欢醇Farnesol | 003790-71-4 | 23.683 | 94 | 0.50 | — | — | — | — | — | — |
11 | 金合欢醇Farnesol | 000502-67-0 | 24.056 | 98 | 0.54 | 24.042 | 98 | 0.22 | — | — | — |
12 | 1-辛醇1-Octanol | 000111-87-5 | — | — | — | — | — | — | 9.513 | 90 | 0.10 |
13 | 香芹醇Carveol | 000099-48-9 | — | — | — | 17.588 | 55 | 0.49 | 17.581 | 60 | 0.24 |
14 | 紫苏醇Perilla alcohol | 000536-59-4 | — | — | — | — | — | — | 15.092 | 49 | 0.13 |
15 | α-杜松醇α-cadinol | 000481-34-5 | — | — | — | 22.463 | 93 | 0.14 | 22.456 | 96 | 0.08 |
16 | 松油烯-4-醇Terpinen-4-ol | 000562-74-3 | — | — | — | 12.182 | 96 | 0.13 | 12.175 | 96 | 0.13 |
序号 No. | 醛类化合物名称 Aldehyde compound name | CAS编号 CAS No. | N03 | D03 | B03 | ||||||
---|---|---|---|---|---|---|---|---|---|---|---|
保留时间 Retention time/min | 定性 Qualita- tive | 相对含量 Relative content/% | 保留时间 Retention time/min | 定性 Qualita- tive | 相对含量 Relative content/% | 保留时间 Retention time/min | 定性 Qualita- tive | 相对含量 Relative content/% | |||
1 | 柠檬醛Citral | 005392-40-5 | 14.506 | 96 | 2.94 | 14.526 | 96 | 3.81 | 14.485 | 96 | 2.46 |
2 | (Z)-3,7-二甲基-2,6-辛二烯醛(Z) | 000106-26-3 | 13.775 | 95 | 1.67 | 13.795 | 96 | 2.21 | 13.768 | 95 | 1.44 |
3,7-dimethyl-2,6-octadienal |
Table 4 The types and relative contents of aldehydes in pericarp with different bagging treatments
序号 No. | 醛类化合物名称 Aldehyde compound name | CAS编号 CAS No. | N03 | D03 | B03 | ||||||
---|---|---|---|---|---|---|---|---|---|---|---|
保留时间 Retention time/min | 定性 Qualita- tive | 相对含量 Relative content/% | 保留时间 Retention time/min | 定性 Qualita- tive | 相对含量 Relative content/% | 保留时间 Retention time/min | 定性 Qualita- tive | 相对含量 Relative content/% | |||
1 | 柠檬醛Citral | 005392-40-5 | 14.506 | 96 | 2.94 | 14.526 | 96 | 3.81 | 14.485 | 96 | 2.46 |
2 | (Z)-3,7-二甲基-2,6-辛二烯醛(Z) | 000106-26-3 | 13.775 | 95 | 1.67 | 13.795 | 96 | 2.21 | 13.768 | 95 | 1.44 |
3,7-dimethyl-2,6-octadienal |
序号 No. | 酮类化合物名称 Ketone compound name | CAS编号 CAS No. | N03 | D03 | B03 | ||||||
---|---|---|---|---|---|---|---|---|---|---|---|
保留时间 Retention time/min | 定性 Qualita- tive | 相对含量 Relative content/% | 保留时间 Retention time/min | 定性 Qualita- tive | 相对含量 Relative content/% | 保留时间 Retention time/min | 定性 Qualita- tive | 相对含量 Relative content/% | |||
1 | 芳姜黄酮Arturrncrone | 1000292-71-0 | 22.663 | 98 | 0.39 | 22.649 | 95 | 0.15 | 22.642 | 95 | 0.09 |
2 | 姜黄酮Turmerone | 180315-67-7 | 22.739 | 97 | 0.46 | 22.725 | 97 | 0.24 | 22.718 | 97 | 0.10 |
3 | 姜黄酮Turmerone | 087440-60-6 | 23.332 | 95 | 0.23 | — | — | — | — | — | — |
4 | 圆柚酮Nootkatone | 004674-50-4 | 25.256 | 99 | 0.04 | 25.242 | 99 | 3.17 | 25.214 | 99 | 2.14 |
5 | 5,6-二甲氧基-1,2-茚二酮 | 040243-67-2 | 25.400 | 46 | 0.14 | — | — | — | — | — | — |
5,6-Dimethoxy-1,2-indindanone | |||||||||||
6 | (E,E)-3-[3,5-癸二烯基]-环戊酮 | 1000131-99-7 | — | — | — | 23.552 | 86 | 0.15 | — | — | — |
(E, E) -3-[3,5-decadienyl]-cyclopentanone |
Table 5 The types and relative contents of ketones in pericarp with different bagging treatments
序号 No. | 酮类化合物名称 Ketone compound name | CAS编号 CAS No. | N03 | D03 | B03 | ||||||
---|---|---|---|---|---|---|---|---|---|---|---|
保留时间 Retention time/min | 定性 Qualita- tive | 相对含量 Relative content/% | 保留时间 Retention time/min | 定性 Qualita- tive | 相对含量 Relative content/% | 保留时间 Retention time/min | 定性 Qualita- tive | 相对含量 Relative content/% | |||
1 | 芳姜黄酮Arturrncrone | 1000292-71-0 | 22.663 | 98 | 0.39 | 22.649 | 95 | 0.15 | 22.642 | 95 | 0.09 |
2 | 姜黄酮Turmerone | 180315-67-7 | 22.739 | 97 | 0.46 | 22.725 | 97 | 0.24 | 22.718 | 97 | 0.10 |
3 | 姜黄酮Turmerone | 087440-60-6 | 23.332 | 95 | 0.23 | — | — | — | — | — | — |
4 | 圆柚酮Nootkatone | 004674-50-4 | 25.256 | 99 | 0.04 | 25.242 | 99 | 3.17 | 25.214 | 99 | 2.14 |
5 | 5,6-二甲氧基-1,2-茚二酮 | 040243-67-2 | 25.400 | 46 | 0.14 | — | — | — | — | — | — |
5,6-Dimethoxy-1,2-indindanone | |||||||||||
6 | (E,E)-3-[3,5-癸二烯基]-环戊酮 | 1000131-99-7 | — | — | — | 23.552 | 86 | 0.15 | — | — | — |
(E, E) -3-[3,5-decadienyl]-cyclopentanone |
序号 No. | 酯类化合物名称 Ester compound name | CAS编号 CAS No. | N03 | D03 | B03 | ||||||
---|---|---|---|---|---|---|---|---|---|---|---|
保留时间 Retention time/min | 定性 Qualita- tive | 相对含量 Relative content/% | 保留时间 Retention time/min | 定性 Qualita- tive | 相对含量 Relative content/% | 保留时间 Retention time/min | 定性 Qualita- tive | 相对含量 Relative content/% | |||
1 | 甲酸芳樟酯Linalyl formate | 000115-99-1 | — | — | — | — | — | — | 16.340 | 64 | 0.13 |
2 | 乙酸香芹酯Carvyl acetate | 001197-06-4 | 13.216 | 55 | 0.20 | 13.216 | 95 | 0.25 | 13.209 | 95 | 0.22 |
3 | 乙酸香叶酯Acetate geranyl ester | 000105-87-3 | 17.002 | 91 | 0.80 | 17.002 | 91 | 0.85 | 16.995 | 91 | 0.79 |
4 | 丙酸橙花酯Neryl propionate | 000105-91-9 | — | — | — | 16.340 | 64 | 0.14 | — | — | — |
5 | 棕榈酸甲酯Methyl palmitate | 000112-39-0 | 27.173 | 99 | 0.13 | — | — | — | — | — | — |
Table 6 The types and relative contents of esters in pericarp with different bagging treatments
序号 No. | 酯类化合物名称 Ester compound name | CAS编号 CAS No. | N03 | D03 | B03 | ||||||
---|---|---|---|---|---|---|---|---|---|---|---|
保留时间 Retention time/min | 定性 Qualita- tive | 相对含量 Relative content/% | 保留时间 Retention time/min | 定性 Qualita- tive | 相对含量 Relative content/% | 保留时间 Retention time/min | 定性 Qualita- tive | 相对含量 Relative content/% | |||
1 | 甲酸芳樟酯Linalyl formate | 000115-99-1 | — | — | — | — | — | — | 16.340 | 64 | 0.13 |
2 | 乙酸香芹酯Carvyl acetate | 001197-06-4 | 13.216 | 55 | 0.20 | 13.216 | 95 | 0.25 | 13.209 | 95 | 0.22 |
3 | 乙酸香叶酯Acetate geranyl ester | 000105-87-3 | 17.002 | 91 | 0.80 | 17.002 | 91 | 0.85 | 16.995 | 91 | 0.79 |
4 | 丙酸橙花酯Neryl propionate | 000105-91-9 | — | — | — | 16.340 | 64 | 0.14 | — | — | — |
5 | 棕榈酸甲酯Methyl palmitate | 000112-39-0 | 27.173 | 99 | 0.13 | — | — | — | — | — | — |
序号 No. | 酸类化合物名称 Acidic compound name | CAS编号 CAS No. | N03 | D03 | B03 | ||||||
---|---|---|---|---|---|---|---|---|---|---|---|
保留时间 Retention time/min | 定性 Qualita- tive | 相对含量 Relative content/% | 保留时间 Retention time/min | 定性 Qualita- tive | 相对含量 Relative content/% | 保留时间 Retention time/min | 定性 Qualita- tive | 相对含量 Relative content/% | |||
1 | 棕榈酸Palmitic acid | 000057-10-3 | 27.738 | 98 | 0.15 | — | — | — | — | — | — |
2 | 棕榈酸Palmitic acid | 000628-97-7 | 28.276 | 98 | 0.13 | — | — | — | — | — | — |
3 | 香叶酸Vanillic acid | 000459-80-3 | — | — | — | — | — | — | 16.560 | 68 | 0.64 |
Table 7 The types and relative contents of acids in pericarp with different bagging treatments
序号 No. | 酸类化合物名称 Acidic compound name | CAS编号 CAS No. | N03 | D03 | B03 | ||||||
---|---|---|---|---|---|---|---|---|---|---|---|
保留时间 Retention time/min | 定性 Qualita- tive | 相对含量 Relative content/% | 保留时间 Retention time/min | 定性 Qualita- tive | 相对含量 Relative content/% | 保留时间 Retention time/min | 定性 Qualita- tive | 相对含量 Relative content/% | |||
1 | 棕榈酸Palmitic acid | 000057-10-3 | 27.738 | 98 | 0.15 | — | — | — | — | — | — |
2 | 棕榈酸Palmitic acid | 000628-97-7 | 28.276 | 98 | 0.13 | — | — | — | — | — | — |
3 | 香叶酸Vanillic acid | 000459-80-3 | — | — | — | — | — | — | 16.560 | 68 | 0.64 |
序号 No. | 氧化物名称 Oxide name | CAS编号 CAS No. | N03 | D03 | B03 | ||||||
---|---|---|---|---|---|---|---|---|---|---|---|
保留时间 Retention time/min | 定性 Qualita- tive | 相对含量 Relative content/% | 保留时间 Retention time/min | 定性 Qualita- tive | 相对含量 Relative content/% | 保留时间 Retention time/min | 定性 Qualita- tive | 相对含量 Relative content/% | |||
1 | 异香橙烯环氧化物 | 1000159-36-6 | — | — | — | 23.056 | 35 | 0.12 | — | — | — |
Isobromene epoxide |
Table 8 The types and relative content of oxides in pericarp with different bagging treatments
序号 No. | 氧化物名称 Oxide name | CAS编号 CAS No. | N03 | D03 | B03 | ||||||
---|---|---|---|---|---|---|---|---|---|---|---|
保留时间 Retention time/min | 定性 Qualita- tive | 相对含量 Relative content/% | 保留时间 Retention time/min | 定性 Qualita- tive | 相对含量 Relative content/% | 保留时间 Retention time/min | 定性 Qualita- tive | 相对含量 Relative content/% | |||
1 | 异香橙烯环氧化物 | 1000159-36-6 | — | — | — | 23.056 | 35 | 0.12 | — | — | — |
Isobromene epoxide |
序号 No. | 其他化合物名称 Other compound name | CAS编号 CAS No. | N03 | D03 | B03 | ||||||
---|---|---|---|---|---|---|---|---|---|---|---|
保留时间 Retention time/min | 定性 Qualita- tive | 相对含量 Relative content/% | 保留时间 Retention time/min | 定性 Qualita- tive | 相对含量 Relative content/% | 保留时间 Retention time/min | 定性 Qualita- tive | 相对含量 Relative content/% | |||
1 | 1-乙烯基-1-甲基-2,4-二(丙-1-烯- | 110823-68-2 | — | — | — | 17.181 | 97 | 0.66 | — | — | — |
2-基)环己烷 | |||||||||||
1-Vinyl-1-methyl-2,4-di (propane-1-en-2-yl) cyclohexane | |||||||||||
2 | 吲哚Indole | 000120-72-9 | 15.002 | 95 | 2.63 | 14.995 | 94 | 2.22 | 15.002 | 94 | 3.15 |
3 | 1,2,4a,5,6,8a-六氢-1-异丙基-4, | 024406-05-1 | — | — | — | 20.201 | 97 | 14.00 | 20.201 | 97 | 0.12 |
7-二甲基萘 | |||||||||||
1,2,4a, 5,6,8a hexahydro-1-isopropyl-4,7-dimethylnaphthalene | |||||||||||
4 | 2-氯-3-甲氧基丙脒盐酸盐 | 1000234-64-1 | — | — | — | 15.823 | 38 | 0.14 | — | — | — |
2-Chloro-3-methoxypropamidine hydrochloride |
Table 9 The types and relative contents of other compounds in pericarp with different bagging treatments
序号 No. | 其他化合物名称 Other compound name | CAS编号 CAS No. | N03 | D03 | B03 | ||||||
---|---|---|---|---|---|---|---|---|---|---|---|
保留时间 Retention time/min | 定性 Qualita- tive | 相对含量 Relative content/% | 保留时间 Retention time/min | 定性 Qualita- tive | 相对含量 Relative content/% | 保留时间 Retention time/min | 定性 Qualita- tive | 相对含量 Relative content/% | |||
1 | 1-乙烯基-1-甲基-2,4-二(丙-1-烯- | 110823-68-2 | — | — | — | 17.181 | 97 | 0.66 | — | — | — |
2-基)环己烷 | |||||||||||
1-Vinyl-1-methyl-2,4-di (propane-1-en-2-yl) cyclohexane | |||||||||||
2 | 吲哚Indole | 000120-72-9 | 15.002 | 95 | 2.63 | 14.995 | 94 | 2.22 | 15.002 | 94 | 3.15 |
3 | 1,2,4a,5,6,8a-六氢-1-异丙基-4, | 024406-05-1 | — | — | — | 20.201 | 97 | 14.00 | 20.201 | 97 | 0.12 |
7-二甲基萘 | |||||||||||
1,2,4a, 5,6,8a hexahydro-1-isopropyl-4,7-dimethylnaphthalene | |||||||||||
4 | 2-氯-3-甲氧基丙脒盐酸盐 | 1000234-64-1 | — | — | — | 15.823 | 38 | 0.14 | — | — | — |
2-Chloro-3-methoxypropamidine hydrochloride |
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