啶虫脒在芹菜设施栽培体系下的沉积与残留

doi:10.3969/j.issn.1004-1524.2020.12.12

浙江农业学报 ›› 2020, Vol. 32 ›› Issue (12): 2211-2217.DOI: 10.3969/j.issn.1004-1524.2020.12.12

啶虫脒在芹菜设施栽培体系下的沉积与残留

喻歆茹(), 何红梅, 王祥云, 李艳杰, 徐玲英, 赵学平, 张昌朋^*()

省部共建农产品质量安全危害因子与风险防控国家重点实验室(筹),农业农村部农药残留检测重点实验室,浙江省农业科学院农产品质量标准研究所,浙江杭州 310021

收稿日期:2020-05-14 出版日期:2020-12-25 发布日期:2020-12-25
通讯作者: 张昌朋
作者简介:*张昌朋,E-mail: cpzhang1215@126.com
喻歆茹(1993—),女,云南弥勒人,硕士,实习研究员,主要从事农药残留与农产品安全研究。E-mail: yxr520511@163.com
基金资助:
国家重点研发计划(2016YFD0200204,2017YFD0201600)

Deposition and residue of acetamiprid under protected celery cultivation

YU Xinru(), HE Hongmei, WANG Xiangyun, LI Yanjie, XU Lingying, ZHAO Xueping, ZHANG Changpeng^*()

State Key Laboratory for Managing Biotic and Chemical Threats to the Quality and Safety of Agro-Products (in Prepared), Key Laboratory for Pesticide Residue Detection, Ministry of Agriculture and Rural Affairs, Institute of Quality and Standard for Agro-Products, Zhejiang Academy of Agricultural Sciences, Hangzhou 310021, China

Received:2020-05-14 Online:2020-12-25 Published:2020-12-25
Contact: ZHANG Changpeng

摘要/Abstract

摘要：

通过田间试验,研究了芹菜设施栽培条件下啶虫脒的沉积与残留规律,并建立了芹菜叶、茎、根,以及土壤中的啶虫咪经乙腈提取、QuEChERs萃取净化和液相色谱串联质谱检测的方法。结果表明:啶虫脒在芹菜叶、茎、根和土壤中的平均回收率分别为100.2%~102.5%、83.9%~93.5%、97.0%~100.1%和90.8%~94.4%,在芹菜设施栽培体系中啶虫脒的沉积量由大到小依次为芹菜叶>土壤>芹菜茎>芹菜根。啶虫脒在芹菜叶的残留消解动态符合一级动力学方程,消解半衰期为4.2~19.4 d。按有效成分18 g·hm^-2和27 g·hm^-2施药后7 d,设施栽培条件下芹菜叶和茎的啶虫咪残留量分别为0.330 0~2.570 0、0.004 7~0.030 0 mg·kg^-1,均低于GB 2763—2019规定的最大残留限量(3 mg·kg^-1)。研究结果可为啶虫脒在芹菜设施栽培体系下的合理使用提供科学参考。

关键词: 啶虫脒, 设施栽培, 残留, 沉积, 芹菜

Abstract:

Based on the field experiments and laboratory tests, the deposition and residue characteristics of acetamiprid in celery under protected cultivation were studied, and a detection method was also established. The acetamiprid in soil and plant samples was extracted by using acetonitrile, purified by QuEChERs and detected by liquid chromagraphy-mass spectrometry. The average recoveries of acetamiprid in celery leaf, stem, root and soil were 100.2%-102.5%, 83.9%-93.5%, 97.0%-100.1% and 90.8%-94.4%, respectively. The amount of acetamiprid deposition decreased as celery leaf>soil>celery stem>celery root. The degradation curve of acetamiprid in celery leaf was in accordance with the first-order kinetic equation, and the degradation half-life of acetamiprid was 4.2-19.4 d. Seven days after application of acetamiprid with dosage of 18, 27 g·hm^-2, the residues of acetamiprid in celery leaf and stem were 0.330 0-2.570 0, 0.004 7-0.030 0 mg·kg^-1, respectively, which were below the maximum residue limit (3 mg·kg^-1) of the Chinese national standard GB 2763—2019. The results could provide scientific reference for the rational use of acetamiprid on celery under protected cultivation.

Key words: acetamiprid, protected cultivation, residue, deposition, celery

中图分类号:

S481⁺.8

喻歆茹, 何红梅, 王祥云, 李艳杰, 徐玲英, 赵学平, 张昌朋. 啶虫脒在芹菜设施栽培体系下的沉积与残留[J]. 浙江农业学报, 2020, 32(12): 2211-2217.

YU Xinru, HE Hongmei, WANG Xiangyun, LI Yanjie, XU Lingying, ZHAO Xueping, ZHANG Changpeng. Deposition and residue of acetamiprid under protected celery cultivation[J]. Acta Agriculturae Zhejiangensis, 2020, 32(12): 2211-2217.

图/表 5

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样品 Sample	添加水平 Spike level/(mg·kg^-1)	回收率Recovery/%						平均回收率 Average recovery/%	相对标准偏差 RSD/%
样品 Sample	添加水平 Spike level/(mg·kg^-1)	1	2	3	4	5	6	平均回收率 Average recovery/%	相对标准偏差 RSD/%
芹菜叶	0.05	107.2	104.2	99.2	95.2	98.0	104.7	101.4	4.6
Celery leaf	0.10	101.4	100.4	107.5	105.2	93.8	93.1	100.2	5.8
	1.00	103.5	112.0	97.1	98.8	93.3	110.4	102.5	7.3
芹菜茎	0.05	81.1	81.2	83.8	87.3	81.9	88.3	83.9	3.7
Celery stem	0.10	82.2	89.6	95.7	87.9	105.0	100.7	93.5	9.1
	1.00	87.2	96.2	92.8	92.5	90.2	99.2	93.0	4.6
芹菜根	0.05	106.5	98.2	93.6	94.5	93.5	98.3	97.4	5.0
Celery root	0.10	101.5	100.5	96.3	100.5	100.6	101.3	100.1	1.9
	1.00	99.7	96.9	98.8	90.4	94.8	101.4	97.0	4.1
土壤Soil	0.02	85.4	89.6	92.9	103.8	89.4	90.7	92.0	6.8
	0.20	81.2	80.6	94.9	97.2	96.3	94.7	90.8	8.5
	1.00	86.0	96.3	96.8	95.4	102.5	89.2	94.4	6.2

样品 Sample	添加水平 Spike level/(mg·kg^-1)	回收率Recovery/%						平均回收率 Average recovery/%	相对标准偏差 RSD/%
样品 Sample	添加水平 Spike level/(mg·kg^-1)	1	2	3	4	5	6	平均回收率 Average recovery/%	相对标准偏差 RSD/%
芹菜叶	0.05	107.2	104.2	99.2	95.2	98.0	104.7	101.4	4.6
Celery leaf	0.10	101.4	100.4	107.5	105.2	93.8	93.1	100.2	5.8
	1.00	103.5	112.0	97.1	98.8	93.3	110.4	102.5	7.3
芹菜茎	0.05	81.1	81.2	83.8	87.3	81.9	88.3	83.9	3.7
Celery stem	0.10	82.2	89.6	95.7	87.9	105.0	100.7	93.5	9.1
	1.00	87.2	96.2	92.8	92.5	90.2	99.2	93.0	4.6
芹菜根	0.05	106.5	98.2	93.6	94.5	93.5	98.3	97.4	5.0
Celery root	0.10	101.5	100.5	96.3	100.5	100.6	101.3	100.1	1.9
	1.00	99.7	96.9	98.8	90.4	94.8	101.4	97.0	4.1
土壤Soil	0.02	85.4	89.6	92.9	103.8	89.4	90.7	92.0	6.8
	0.20	81.2	80.6	94.9	97.2	96.3	94.7	90.8	8.5
	1.00	86.0	96.3	96.8	95.4	102.5	89.2	94.4	6.2

试验点 Location	剂量 Dose/(g·hm^-2)	t	芹菜叶 Celery leaf	芹菜茎 Celery stem	芹菜根 Celery root	土壤 Soil
Zhejiang	27	2 h	2.840 0±0.250 0	0.120 0±0.016 0	0.028 0±0.013 0	0.003 5±0.000 2
		1 d	4.080 0±0.610 0	0.100 0±0.002 9	0.200 0±0.032 0	0.001 8±0.000 5
		3 d	4.110 0±0.420 0	0.110 0±0.016 0	0.160 0±0.031 0	—
		5 d	2.910 0±0.240 0	0.047 0±0.002 2	0.084 0±0.010 0	—
		7 d	2.570 0±0.420 0	0.030 0±0.002 1	0.031 0±0.006 4	—
		14 d	2.670 0±0.320 0	0.011 0±0.001 1	0.014 0±0.001 6	—
		21 d	1.890 0±0.230 0	0.006 8±0.001 7	0.009 4±0.001 4	—
	18	2 h	1.160 0±0.100 0	0.059 0±0.004 8	0.039 0±0.001 3	0.006 0±0.000 6
		1 d	1.890 0±0.310 0	0.072 0±0.012 0	0.067 0±0.005 9	0.000 6±0.000 1
		3 d	2.400 0±0.480 0	0.042 0±0.004 0	0.048 0±0.006 9	0.000 3±0.000 4
		5 d	1.580 0±0.210 0	0.017 0±0.001 4	0.017 0±0.000 2	—
		7 d	1.860 0±0.190 0	0.014 0±0.002 4	0.012 0±0.002 2	—
		14 d	1.110 0±0.210 0	0.002 0±0.000 1	0.004 5±0.000 1	—
		21 d	0.870 0±0.093 0	0.001 8±0.000 5	0.003 7±0.000 5	—
Shandong	27	2 h	1.790 0±0.200 0	0.046 0±0.009 0	0.061 0±0.003 1	0.000 5±0.000 1
		1 d	0.950 0±0.055 0	0.022 0±0.004 3	0.022 0±0.003 5	0.000 4±0.000 2
		3 d	0.680 0±0.078 0	0.016 0±0.005 7	0.009 2±0.000 6	—
		5 d	0.630 0±0.008 0	0.007 8±0.002 9	0.008 0±0.000 2	—
		7 d	0.420 0±0.068 0	0.004 7±0.000 3	0.005 3±0.000 2	—
		14 d	0.150 0±0.021 0	0.001 2±0.000 1	0.003 5±0.000 2	—
		21 d	0.039 0±0.018 0	0.000 6±0.000 1	0.001 7±0.000 2	—
	18	2 h	1.000 0±0.020 0	0.017 0±0.003 9	0.002 8±0.000 3	0.001 1±0.001 6
		1 d	0.520 0±0.057 0	0.013 0±0.003 4	0.007 5±0.000 9	—
		3 d	0.400 0±0.045 0	0.004 7±0.001 4	0.005 9±0.001 3	—
		5 d	0.590 0±0.073 0	0.005 3±0.000 7	0.003 6±0.000 5	—
		7 d	0.330 0±0.091 0	0.004 7±0.000 8	0.003 5±0.000 9	—
		14 d	0.100 0±0.008 0	0.001 3±0.000 4	0.002 8±0.000 6	—
		21 d	0.210 0±0.081 0	0.000 9±0.000 1	0.001 7±0.000 3	—

试验点 Location	剂量 Dose/(g·hm^-2)	t	芹菜叶 Celery leaf	芹菜茎 Celery stem	芹菜根 Celery root	土壤 Soil
Zhejiang	27	2 h	2.840 0±0.250 0	0.120 0±0.016 0	0.028 0±0.013 0	0.003 5±0.000 2
		1 d	4.080 0±0.610 0	0.100 0±0.002 9	0.200 0±0.032 0	0.001 8±0.000 5
		3 d	4.110 0±0.420 0	0.110 0±0.016 0	0.160 0±0.031 0	—
		5 d	2.910 0±0.240 0	0.047 0±0.002 2	0.084 0±0.010 0	—
		7 d	2.570 0±0.420 0	0.030 0±0.002 1	0.031 0±0.006 4	—
		14 d	2.670 0±0.320 0	0.011 0±0.001 1	0.014 0±0.001 6	—
		21 d	1.890 0±0.230 0	0.006 8±0.001 7	0.009 4±0.001 4	—
	18	2 h	1.160 0±0.100 0	0.059 0±0.004 8	0.039 0±0.001 3	0.006 0±0.000 6
		1 d	1.890 0±0.310 0	0.072 0±0.012 0	0.067 0±0.005 9	0.000 6±0.000 1
		3 d	2.400 0±0.480 0	0.042 0±0.004 0	0.048 0±0.006 9	0.000 3±0.000 4
		5 d	1.580 0±0.210 0	0.017 0±0.001 4	0.017 0±0.000 2	—
		7 d	1.860 0±0.190 0	0.014 0±0.002 4	0.012 0±0.002 2	—
		14 d	1.110 0±0.210 0	0.002 0±0.000 1	0.004 5±0.000 1	—
		21 d	0.870 0±0.093 0	0.001 8±0.000 5	0.003 7±0.000 5	—
Shandong	27	2 h	1.790 0±0.200 0	0.046 0±0.009 0	0.061 0±0.003 1	0.000 5±0.000 1
		1 d	0.950 0±0.055 0	0.022 0±0.004 3	0.022 0±0.003 5	0.000 4±0.000 2
		3 d	0.680 0±0.078 0	0.016 0±0.005 7	0.009 2±0.000 6	—
		5 d	0.630 0±0.008 0	0.007 8±0.002 9	0.008 0±0.000 2	—
		7 d	0.420 0±0.068 0	0.004 7±0.000 3	0.005 3±0.000 2	—
		14 d	0.150 0±0.021 0	0.001 2±0.000 1	0.003 5±0.000 2	—
		21 d	0.039 0±0.018 0	0.000 6±0.000 1	0.001 7±0.000 2	—
	18	2 h	1.000 0±0.020 0	0.017 0±0.003 9	0.002 8±0.000 3	0.001 1±0.001 6
		1 d	0.520 0±0.057 0	0.013 0±0.003 4	0.007 5±0.000 9	—
		3 d	0.400 0±0.045 0	0.004 7±0.001 4	0.005 9±0.001 3	—
		5 d	0.590 0±0.073 0	0.005 3±0.000 7	0.003 6±0.000 5	—
		7 d	0.330 0±0.091 0	0.004 7±0.000 8	0.003 5±0.000 9	—
		14 d	0.100 0±0.008 0	0.001 3±0.000 4	0.002 8±0.000 6	—
		21 d	0.210 0±0.081 0	0.000 9±0.000 1	0.001 7±0.000 3	—

啶虫脒在芹菜设施栽培体系下的沉积与残留

Deposition and residue of acetamiprid under protected celery cultivation

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