不同时期叶面喷施钼肥对烤烟香味成分的影响

doi:10.3969/j.issn.1004-1524.20221620

浙江农业学报 ›› 2024, Vol. 36 ›› Issue (3): 481-493.DOI: 10.3969/j.issn.1004-1524.20221620

不同时期叶面喷施钼肥对烤烟香味成分的影响

刘春奎¹(), 李紫琳¹, 韦小玲², 贾琳³, 夏阳⁴^,^*(), 龙李进⁵, 贺远¹, 李波⁶, 闫洪洋⁷, 张博莹¹

1.郑州轻工业大学烟草科学与工程学院,烟草行业烟草工业生物技术重点实验室,河南郑州 450001
2.广西中烟工业有限责任公司柳州卷烟厂,广西柳州 545006
3.河南农业大学农学院,河南郑州 450046
4.平顶山市烟草公司叶县分公司,河南平顶山 467200
5.贵州黄果树金叶科技有限公司,贵州安顺 561000
6.浙江中烟工业有限责任公司,浙江杭州 310004
7.中国烟草总公司职工进修学院,河南郑州 450008

收稿日期:2022-11-15 出版日期:2024-03-25 发布日期:2024-04-09
作者简介:刘春奎(1982—),男,河南方城人,博士,副教授,主要从事烟草营养、烟草原料初加工和卷烟产品设计研究。E-mail:liuck2008@126.com
通讯作者: *夏阳,E-mail:651366995@qq.com
基金资助:
河南省科技攻关项目(212102110308);郑州轻工业大学博士基金项目(2020BSJJ014)

Effects of foliar application of molybdenum fertilizer at different growth stages on aroma components of flue-cured tobacco

LIU Chunkui¹(), LI Zilin¹, WEI Xiaoling², JIA Lin³, XIA Yang⁴^,^*(), LONG Lijin⁵, HE Yuan¹, LI Bo⁶, YAN Hongyang⁷, ZHNAG Boying¹

1. Key Laboratory of Tobacco Industrial Biotechnology, College of Tobacco Science and Engineering, Zhengzhou University of Light Industry, Zhengzhou 450001, China
2. Liuzhou Cigarette Factory, China Tobacco Guangxi Industrial Co., Ltd., Liuzhou 545006, Guangxi, China
3. College of Agronomy, Henan Agricultural University, Zhengzhou 450046, China
4. Ye County Branch, Pingdingshan Tobacco Company, Pingdingshan 467200, Henan, China
5. Guizhou Huangguoshu Golden Leaf Technology Corporation Limited, Anshun 561000, Guizhou, China
6. China Tobacco Zhejiang Industrial Co., Ltd., Hangzhou 310004, China
7. College of Further Education for Staffs, China National Tobacco Corporation, Zhengzhou 450008, China

Received:2022-11-15 Online:2024-03-25 Published:2024-04-09

摘要/Abstract

摘要：

为研究不同时期叶面喷施钼肥对烤烟叶片香味成分含量的影响,以烤烟品种中烟100为试验材料,设置4个处理:T1,对照;T2,旺长期喷施0.10%钼肥;T3,打顶期喷施0.10%钼肥;T4,旺长期和打顶期均喷施0.10%钼肥。采用同时蒸馏萃取处理烟叶样品,利用气相色谱质谱法(GC-MS)测定烟叶的香味成分种类及其含量。结果表明:从T1~T4处理烤烟B2F中分别鉴定到香味成分84、89、87、94种,香味物质总量(不含新植二烯)以T2处理最高,T4、T3处理次之,三者较对照分别显著(P<0.05)增加了27.76%、7.76%、5.88%,新植二烯含量以T2和T3处理最高,显著高于对照。从T1~T4处理烤烟C3F中分别鉴定到香味成分88、102、108、95种,烤烟香味物质总量(不含新植二烯)以T3和T4处理最高,T2处理次之,三者分别较对照显著增加了73.73%、71.64%、62.17%,新植二烯含量以T2处理最高,显著高于其他处理。从T1~T4处理烤烟X2F中分别鉴定到香味成分70、84、67、81种,各处理的烤烟香味物质总量(不含新植二烯)差异显著,从高到低依次为T2>T4>T1>T3,T2、T4处理分别较对照显著高出35.72%、30.61%,新植二烯含量以T2和T4处理最高,T3处理次之,三者均显著高于对照。结果表明,旺长期叶面喷施0.10%钼肥能显著提高烤烟的新植二烯含量和香味成分总量(不含新植二烯),在增加烤烟香味总量方面效果较好。

关键词: 香味成分, 钼肥, 叶面喷施, 烤烟

Abstract:

In order to test the effects of molybdenum fertilizer sprayed on the tobacco leaves at different growth stages on the contents of aroma components in flue-cured tobacco, the flue-cured tobacco variety Zhongyan 100 was served as the test material. Four treatments were set up in the experiment: T1, control; T2, 0.10% molybdenum fertilizer sprayed at the resettling stage; T3, 0.10% molybdenum fertilizer sprayed at the topping stage; T4, 0.10% molybdenum fertilizer sprayed both at the resettling stage and the topping stage. Samples of tobacco leaves were treated by simultaneous distillation and extraction, and the types and contents of aroma components in tobacco leaves were determined by gas chromatography-mass spectrometry (GC-MS). The results showed that there were 84, 89, 87, and 94 types of aroma components in B2F flue-cured tobacco under T1, T2, T3 and T4 treatments, respectively. The total content of aroma components (except neophytadiene) in B2F flue-cured tobacco reached the highest value under T2 treatment, which was followed by T4 and T3 treatments. The total content of aroma components (except neophytadiene) in B2F flue-cured tobacco under T2, T4 and T3 treatments was significantly (P<0.05) higher than that under the control by 27.76%, 7.76%, and 5.88%, respectively. The neophytadiene content of B2F flue-cured tobacco under T2 and T3 treatments was significantly higher than that under the control. There were 88, 102, 108, and 95 types of aroma components in C3F flue-cured tobacco under T1, T2, T3 and T4 treatments, respectively. The total content of aroma components (except neophytadiene) in C3F flue-cured tobacco reached the highest value under T3 and T4 treatments, which was followed by T2 treatment. The total content of aroma components (except neophytadiene) in C3F flue-cured tobacco under T3, T4 and T2 treatments was significantly higher than that under the control by 73.73%, 71.64%, and 62.17%, respectively. The neophytadiene content of C3F flue-cured tobacco under T2 treatment was significantly higher than the others. There were 70, 84, 67, and 81 types of aroma components in X2F flue-cured tobacco under T1, T2, T3 and T4 treatments, respectively. The total content of aroma components (except neophytadiene) in X2F flue-cured tobacco varied significantly among treatments as T2>T4>T1>T3, and the total content of aroma components (except neophytadiene) under T2 and T4 treatments were significantly higher than that under the control by 35.72% and 30.61%. The neophytadiene content of X2F flue-cured tobacco reached the highest value under T2 and T4 treatments, followed by T3 treatment, which were all significantly higher that of the control. Overall, spraying 0.10% molybdenum fertilizer at the resettling stage could significantly increase neophytadiene content and the total content of aroma components (except neophytadiene) in flue-cured tobacco.

Key words: aroma component, molybdenum fertilizer, foliage spraying, flue-cured tobacco

中图分类号:

S572

刘春奎, 李紫琳, 韦小玲, 贾琳, 夏阳, 龙李进, 贺远, 李波, 闫洪洋, 张博莹. 不同时期叶面喷施钼肥对烤烟香味成分的影响[J]. 浙江农业学报, 2024, 36(3): 481-493.

LIU Chunkui, LI Zilin, WEI Xiaoling, JIA Lin, XIA Yang, LONG Lijin, HE Yuan, LI Bo, YAN Hongyang, ZHNAG Boying. Effects of foliar application of molybdenum fertilizer at different growth stages on aroma components of flue-cured tobacco[J]. Acta Agriculturae Zhejiangensis, 2024, 36(3): 481-493.

图/表 6

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香味成分 Aroma component	不同处理的含量Content under treatments
香味成分 Aroma component	T1	T2	T3	T4
环戊酮Cyclopentanone	0.256 9 c	0.236 9 c	0.345 3 b	0.427 9 a
2, 4-壬二烯醛2,4-Nonadienal	0.247 8 b	0.266 9 b	—	0.321 1 a
吡啶Pyridine	—	0.044 9 b	0.025 1 c	0.136 6 a
2-甲基四氢呋喃-3-酮2-Methyltetrahydrfuran-3-one	0.416 8 a	0.445 5 a	0.449 0 a	0.485 1 a
3-戊炔-1-醇3-Pentyne-1-ol	0.182 9 a	0.206 6 a	0.196 4 a	0.233 0 a
糠醛Furfural	7.103 3 a	6.759 3 a	7.487 9 a	7.212 9 a
2-甲基丁酸2-Methylbutyric acid	0.550 0 a	0.410 1 c	0.458 8 b	0.579 7 a
糠醇Furfuryl alcohol	2.103 5 ab	1.884 7 b	1.610 2 c	2.322 6 a
正戊酸N-Valeric acid	0.437 8 a	0.405 6 a	0.451 6 a	—
丁酸Butanoic acid	—	0.512 3 a	—	0.445 7 b
4-环戊烯-1,3-二酮4-Cyclopentene-1,3-dione	1.229 2 a	1.103 0 a	1.109 9 a	1.190 1 a
2-乙酰基呋喃2-Acetyl furan	0.264 1 a	0.292 9 a	0.285 0 a	0.302 7 a
4-羟基丁酸内酯4-Hydroxybutyrolactone	0.353 7 b	0.520 9 a	0.385 2 b	0.291 9 c
5-甲基-2-呋喃甲醇5-Methyl-2-furyl methanol	0.599 0 b	0.702 5 a	0.470 2 c	0.690 5 a
苯甲醛Benzaldehyde	1.099 4 a	1.032 9 a	0.678 8 b	1.101 7 a
苯酚Phenol	0.517 2 b	0.565 9 ab	0.533 9 b	0.597 0 a
甲基庚烯酮Methyl heptenone	0.375 0 b	0.390 1 b	0.521 0 a	0.381 6 b
2-正戊基呋喃2-Pentylfuran	0.151 0 a	0.161 1 a	0.160 4 a	—
反式-2,4-庚二烯醛Trans-2,4-Heptadienal	0.124 5 c	0.190 9 b	0.367 2 a	0.115 4 c
3-吡啶甲醛3-Pyridinecarboxaldehyde	0.231 2 a	—	0.242 3 a	—
乙炔基环己醇1-Ethynyl-1-cyclohexanol	0.306 3 a	0.335 1 a	—	0.310 8 a
苯甲醇Benzyl alcohol	3.743 4 c	5.527 4 a	1.857 5 d	4.627 4 b
二甲基顺丁烯二酸酐Dimethylmaleic anhydride	0.247 3 b	0.295 5 a	0.334 3 a	0.194 2 c
苯乙醛Phenylacetaldehyde	3.744 1 b	3.917 2 b	3.845 7 b	4.298 9 a
2-乙酰基吡咯2-Acetylpyrrole	2.028 4 a	2.222 2 a	1.272 4 b	2.034 1 a
3-羟基苯甲醇3-Hydroxybenzyl alcohol	1.127 7 a	—	1.160 4 a	0.993 3 a
愈创木酚Guaiacol	0.291 5 a	0.251 6 a	0.244 9 a	0.268 6 a
芳樟醇Linalool	0.470 3 b	0.577 4 a	0.526 0 a	0.452 2 b
壬醛Nonanal	0.228 6 a	0.205 4 a	0.216 9 a	0.199 1 a
苯乙醇Benzyl carbinol	4.409 5 a	4.488 2 a	2.139 5 b	4.528 5 a
2,6,6-三甲基-2-环己烯-1,4-二酮2,6,6-Trimethyl-2-cyclohexene-1,4-dione	0.282 7 a	0.289 7 a	0.182 7 b	0.277 1 a
辛酸Caprylic acid	0.256 8 b	0.455 5 a	0.421 8 a	0.268 9 b
2-甲基-5-(1-甲基乙烯基)环己酮2-Methyl-5- (1-methylethenyl)-cyclohexanone	—	0.324 9 a	0.268 8 a	0.300 7 a
L-α-松油醇L-α-Terpineol	0.207 6 b	0.254 3 a	0.247 8 a	0.206 3 b
2,3-二氢-2,2,6-三甲基苯甲醛2,3-Dihydro-2,2,6-trimethylbenzaldehyde	0.234 1 a	0.253 6 a	0.219 8 a	0.234 9 a
2,3-二氢苯并呋喃2,3-Dihydrobenzofuran	0.535 3 a	0.456 2 b	0.565 6 a	0.413 5 b
1,4-二甲基-3-环己烯-1-乙醛1,4-Dimethyl-3-cyclohexene-1-acetaldehyde	0.307 5 b	0.357 2 a	0.221 9 c	0.281 8 b
4-羟基-2,4,5-三甲基-2,5-环己二烯-1-酮	0.275 7 a	—	—	0.286 2 a
4-Hydroxy-2,4,5-trimethyl-2,5-cyclohexadiene-1-one
2,6,6-三甲基-1-环己烯-1-羧醛2,6,6-Trimethyl-1-cyclohexene-1-carboxyaldehyde	—	0.289 2 a	0.173 1 b	0.300 7 a
3-乙基-4-甲基-1H-吡咯-2,5-二酮3-Ethyl-4-methyl-1H-pyrrole-2,5-dione	0.772 5 b	0.849 6 a	0.526 2 c	0.563 6 c
香叶醇Geraniol	0.177 6 a	0.217 8 a	0.181 8 a	0.161 7 a
苯并吡咯Benzopyrrole	0.740 4 a	0.703 4 a	0.599 0 b	0.702 7 a
对乙烯基愈创木酚P-Vinylguaiacol	5.063 0 a	5.282 8 a	4.572 2 b	4.067 0 c
2-(1-甲基-2-吡咯烷基)-吡啶2-(1-Methyl-2-pyrrolidinyl)-pyridine	—	1.445 1 a	—	0.810 0 b
萜品烯Terpinene	—	12.323 2 b	13.604 3 a	—
对-薄荷-1(7)-烯-9-醇P-Mint-1(7)-ene-9-ol	—	1.691 9 a	1.577 3 a	1.805 3 a
突厥酮Damascone	11.930 9 a	11.759 5 a	10.311 5 a	11.902 3 a
5-氨基-1-苯基吡唑5-Amino-1-phenylpyrazole	2.059 5 a	1.996 8 a	—	—
(E)-1-(2,3,6-三甲基苯基)丁-1,3-二烯(TPB,1)	—	3.858 4 a	3.770 1 a	4.113 3 a
(E) -1-(2,3,6-Trimethylphenyl) butyl-1,3-diene (TPB, 1)
3-(2,6,6-三甲基-1-环己烯基)-2-丙烯醛	—	—	0.789 2 a	0.889 9 a
3-(2,6,6-Trimethyl-1-cyclohexenyl)-2-acrolein
紫罗兰酮Ionone	0.292 3 c	0.369 8 b	0.428 1 a	0.344 1 b
2-乙基-5,7-二甲基-苯并[b]噻吩2-Ethyl-5,7-dimethyl-benzo [b] thiophene	—	—	0.717 1 b	0.866 7 a
4-异丙基肉桂酸4-Isopropyl cinnamic acid	0.872 7 a	—	—	0.875 1 a
2,4-二异丙基-5-甲基苯酚2,4-Diisopropyl-5-methylphenol	1.331 7 a	0.802 2 b	1.237 6 a	0.744 0 b
香叶基丙酮Geranyl acetone	2.984 7 a	2.797 1 a	2.723 9 a	3.052 7 a
(5-乙基环戊-1-烯基)甲醇(5-Ethylhexyl-1-alkenyl) methanol	—	2.685 6 a	2.001 5 b	—
4-(1-乙烯基-1H-咪唑-2-基)丁酸甲酯	—	—	1.732 6 b	2.580 0 a
4-(1-vinyl-1H-imidazole-2-yl) methyl butanoate
4,4,5,8-四甲基-2-醇4,4,5,8-Tetramethyl-2-ol	—	0.295 0 a	0.385 8 a	0.359 0 a
6,7-二甲氧基香豆素6,7-Dimethoxycoumarin	0.315 4 b	0.388 2 a	—	—
2,4-二叔丁基苯酚2,4-Di-tert-butylphenol	0.152 5 c	0.149 9 c	0.252 7 a	0.202 6 b
对异丙基苯甲醇P-Isopropylbenzyl alcohol	—	0.701 5 a	0.346 8 c	0.517 4 b
5,6-二甲基-2-苯并咪唑啉酮5,6-Dimethyl-2-benzimidazolone	3.422 1 a	—	3.233 1 a	3.292 1 a
2,3'-联吡啶2,3'-Bipyridine	0.463 9 b	0.487 8 b	0.644 7 a	0.341 6 c
二氢猕猴桃内酯Dihydroactinidiolide	3.645 8 a	3.778 3 a	3.494 0 a	3.650 9 a
2,5-双异丁基噻吩2,5-Diisobutylthiophene	0.329 9 a	0.296 0 a	—	0.287 5 a
橙花叔醇Nerolidol	0.289 7 a	—	—	0.337 6 a
4-甲基-2,5-二甲氧基苯甲醛4-Methyl-2,5-dimethoxybenzaldehyde	1.899 9 a	—	—	1.503 9 b
巨豆三烯酮Megastigmatrienone	27.355 8 b	28.596 3 ab	23.171 6 c	30.295 8 a
3-羟基-β-大马酮3-Hydroxy-β-damascenone	4.800 5 b	5.496 6 a	4.013 7 c	3.311 1 d
3-(1-甲基-2-丙烯基)-2,4-戊二酮3-(1-Methyl-2-propenyl)-2,4-pentanedione	—	—	0.219 3 a	0.231 9 a
4-(3-羟基-1-丁烯基)-3,5,5-三甲基-2-环己烯-1-酮	2.749 1 a	3.017 3 a	2.272 2 b	2.114 3 b
4-(3-Hydroxy-1-butenyl)-3,5,5-trimethyl-2-cyclohexen-1-one
3-丁基-1-甲基-1H-茚3-Butyl-1-methyl-1H-indene	—	0.594 8 b	—	0.887 3 a
6-氨基-2,4-二甲基-5-甲氧基喹啉6-Amino-2,4-dimethyl-5-methoxyquinoline	—	0.547 8 a	—	0.397 3 b
5-苯并吡咯5-Benzopyrrole	0.752 9 b	0.772 8 b	0.938 9 a	0.972 9 a
肉豆蔻酸甲酯Methyl myristate	0.223 3 b	0.211 8 b	0.251 8 b	0.419 0 a
(E)甲醚法尼醇(E) Methyl ether farnesol	0.339 8 a	0.342 3 a	—	0.317 9 a
4-(2,2-二甲基-6-亚甲基环己基)-2-丁酮	0.323 1 a	0.322 5 a	—	—
4-(2,2-dimethyl-6-methylene cyclohexyl)-2-butanone
喇叭茶醇Palustrol	0.373 9 b	0.334 3 b	0.097 9 c	1.225 0 a
肉豆蔻酸Myristic acid	0.803 3 b	0.695 0 c	0.761 0 bc	0.906 5 a
2,6,6-三甲基-1-(3-甲基-1,3-丁二烯基)-1,3-环己二烯	—	0.380 5 a	0.343 9 a	—
2,6,6-Trimethyl-1-(3-methyl-1,3-butadiene)-1,3-cyclohexadiene
2,3,6-三甲基-1,4-萘二酮2,3,6-Trimethyl-1,4-naphthalenedione	—	0.736 1 b	0.726 0 b	1.160 6 a
绿油脑Anthracene	0.697 1 a	0.626 3 b	0.725 6 a	0.574 7 b
螺岩兰草酮Solavetivone	0.463 9 c	1.575 9 b	1.387 0 b	2.634 9 a
6,10,14-三甲基-2-十五烷酮6,10,14-Trimethyl-2-pentadecanone	0.770 0 b	1.742 2 a	—	2.082 9 a
7,10,13-十六碳三烯酸甲酯Methyl 7,10,13-hexadecatrienoate	0.254 6 b	—	0.357 6 a	0.375 7 a
棕榈酸甲酯Methyl palmitate	12.214 0 ab	12.715 0 a	10.281 8 c	11.934 5 b
正癸烯N-decene	0.570 5 b	—	0.894 0 a	—
1,2,3,4-四氢-1,4-甲醇萘-6-醇1,2,3,4-Tetrahydro-1,4-methylnaphthalene-6-ol	0.722 7 a	—	—	0.468 1 b
异植物醇Isophytol	0.286 5 a	0.282 4 a	0.308 5 a	0.230 9 b
十七烷酸Heptadecanoic acid	—	0.798 9 a	0.461 0 b	—
棕榈酸Palmitic acid	40.862 4 b	53.500 3 a	36.110 2 c	38.352 5 c
十三酸Tridecanoic acid	2.497 9 a	—	—	0.824 4 b
(1S,2E,4R,7E,11E)-2,7,11-西柏三烯-4-醇	4.154 8 c	8.050 5 a	6.873 0 b	3.217 1 d
(1S,2E,4R,7E,11E)-2,7,11-Cedriene-4-ol
亚麻酸甲酯Methyl linolenate	7.001 4 b	8.034 6 a	5.908 9 c	6.311 5 bc
叶绿醇Phytol	8.311 4 b	9.403 2 a	8.445 6 b	6.265 6 c
1-烯丙基环丙烷甲酸1-Allylcyclopropanecarboxylic acid	—	12.135 0 a	11.518 1 a	8.266 9 b
香茅醇Citronellol	1.279 7 a	1.561 9 a	1.439 9 a	1.175 9 a
2-亚甲基-5α-胆甾-3β-醇2-Methylene-5α-cholesterol-3β-alcohol	0.817 7 c	1.213 9 b	1.803 4 a	—
氧化石竹烯Caryophyllene oxide	1.176 3 c	3.174 6 a	1.418 0 b	1.326 0 bc
香叶基香叶醇Geranylgeraniol	0.654 1 b	0.813 0 a	—	—
法尼醇Farnesol	0.561 6 c	0.654 1 b	0.957 2 a	0.330 1 d
顺式-Z-α-双酚环氧化物Cis-Z-α-Bisphenol epoxide	0.942 4 a	0.858 3 b	—	0.349 9 c
金合欢基丙酮Farnesyl acetone	—	—	0.345 4 a	0.382 1 a
反式-法尼基丙酮Trans-farnesyl acetone	0.637 8 c	—	0.778 5 b	0.920 2 a
己二酸二辛酯Dioctyl adipate	—	—	0.311 3 a	0.215 3 b
N-糠基-环己烷甲酰胺N-Furfuryl-cyclohexane formamide	0.642 3 a	0.339 7 c	0.455 6 b	0.291 4 c
新植二烯Neophytadiene	511.324 9 b	535.784 2 a	529.243 8 a	515.034 7 b
合计(除新植二烯)Total (except neophytadiene)	194.925 4 c	249.041 4 a	206.383 7 b	210.053 9 b
合计Total	706.250 3 c	784.825 6 a	735.627 5 b	725.088 6 b

香味成分 Aroma component	不同处理的含量Content under treatments
香味成分 Aroma component	T1	T2	T3	T4
环戊酮Cyclopentanone	0.256 9 c	0.236 9 c	0.345 3 b	0.427 9 a
2, 4-壬二烯醛2,4-Nonadienal	0.247 8 b	0.266 9 b	—	0.321 1 a
吡啶Pyridine	—	0.044 9 b	0.025 1 c	0.136 6 a
2-甲基四氢呋喃-3-酮2-Methyltetrahydrfuran-3-one	0.416 8 a	0.445 5 a	0.449 0 a	0.485 1 a
3-戊炔-1-醇3-Pentyne-1-ol	0.182 9 a	0.206 6 a	0.196 4 a	0.233 0 a
糠醛Furfural	7.103 3 a	6.759 3 a	7.487 9 a	7.212 9 a
2-甲基丁酸2-Methylbutyric acid	0.550 0 a	0.410 1 c	0.458 8 b	0.579 7 a
糠醇Furfuryl alcohol	2.103 5 ab	1.884 7 b	1.610 2 c	2.322 6 a
正戊酸N-Valeric acid	0.437 8 a	0.405 6 a	0.451 6 a	—
丁酸Butanoic acid	—	0.512 3 a	—	0.445 7 b
4-环戊烯-1,3-二酮4-Cyclopentene-1,3-dione	1.229 2 a	1.103 0 a	1.109 9 a	1.190 1 a
2-乙酰基呋喃2-Acetyl furan	0.264 1 a	0.292 9 a	0.285 0 a	0.302 7 a
4-羟基丁酸内酯4-Hydroxybutyrolactone	0.353 7 b	0.520 9 a	0.385 2 b	0.291 9 c
5-甲基-2-呋喃甲醇5-Methyl-2-furyl methanol	0.599 0 b	0.702 5 a	0.470 2 c	0.690 5 a
苯甲醛Benzaldehyde	1.099 4 a	1.032 9 a	0.678 8 b	1.101 7 a
苯酚Phenol	0.517 2 b	0.565 9 ab	0.533 9 b	0.597 0 a
甲基庚烯酮Methyl heptenone	0.375 0 b	0.390 1 b	0.521 0 a	0.381 6 b
2-正戊基呋喃2-Pentylfuran	0.151 0 a	0.161 1 a	0.160 4 a	—
反式-2,4-庚二烯醛Trans-2,4-Heptadienal	0.124 5 c	0.190 9 b	0.367 2 a	0.115 4 c
3-吡啶甲醛3-Pyridinecarboxaldehyde	0.231 2 a	—	0.242 3 a	—
乙炔基环己醇1-Ethynyl-1-cyclohexanol	0.306 3 a	0.335 1 a	—	0.310 8 a
苯甲醇Benzyl alcohol	3.743 4 c	5.527 4 a	1.857 5 d	4.627 4 b
二甲基顺丁烯二酸酐Dimethylmaleic anhydride	0.247 3 b	0.295 5 a	0.334 3 a	0.194 2 c
苯乙醛Phenylacetaldehyde	3.744 1 b	3.917 2 b	3.845 7 b	4.298 9 a
2-乙酰基吡咯2-Acetylpyrrole	2.028 4 a	2.222 2 a	1.272 4 b	2.034 1 a
3-羟基苯甲醇3-Hydroxybenzyl alcohol	1.127 7 a	—	1.160 4 a	0.993 3 a
愈创木酚Guaiacol	0.291 5 a	0.251 6 a	0.244 9 a	0.268 6 a
芳樟醇Linalool	0.470 3 b	0.577 4 a	0.526 0 a	0.452 2 b
壬醛Nonanal	0.228 6 a	0.205 4 a	0.216 9 a	0.199 1 a
苯乙醇Benzyl carbinol	4.409 5 a	4.488 2 a	2.139 5 b	4.528 5 a
2,6,6-三甲基-2-环己烯-1,4-二酮2,6,6-Trimethyl-2-cyclohexene-1,4-dione	0.282 7 a	0.289 7 a	0.182 7 b	0.277 1 a
辛酸Caprylic acid	0.256 8 b	0.455 5 a	0.421 8 a	0.268 9 b
2-甲基-5-(1-甲基乙烯基)环己酮2-Methyl-5- (1-methylethenyl)-cyclohexanone	—	0.324 9 a	0.268 8 a	0.300 7 a
L-α-松油醇L-α-Terpineol	0.207 6 b	0.254 3 a	0.247 8 a	0.206 3 b
2,3-二氢-2,2,6-三甲基苯甲醛2,3-Dihydro-2,2,6-trimethylbenzaldehyde	0.234 1 a	0.253 6 a	0.219 8 a	0.234 9 a
2,3-二氢苯并呋喃2,3-Dihydrobenzofuran	0.535 3 a	0.456 2 b	0.565 6 a	0.413 5 b
1,4-二甲基-3-环己烯-1-乙醛1,4-Dimethyl-3-cyclohexene-1-acetaldehyde	0.307 5 b	0.357 2 a	0.221 9 c	0.281 8 b
4-羟基-2,4,5-三甲基-2,5-环己二烯-1-酮	0.275 7 a	—	—	0.286 2 a
4-Hydroxy-2,4,5-trimethyl-2,5-cyclohexadiene-1-one
2,6,6-三甲基-1-环己烯-1-羧醛2,6,6-Trimethyl-1-cyclohexene-1-carboxyaldehyde	—	0.289 2 a	0.173 1 b	0.300 7 a
3-乙基-4-甲基-1H-吡咯-2,5-二酮3-Ethyl-4-methyl-1H-pyrrole-2,5-dione	0.772 5 b	0.849 6 a	0.526 2 c	0.563 6 c
香叶醇Geraniol	0.177 6 a	0.217 8 a	0.181 8 a	0.161 7 a
苯并吡咯Benzopyrrole	0.740 4 a	0.703 4 a	0.599 0 b	0.702 7 a
对乙烯基愈创木酚P-Vinylguaiacol	5.063 0 a	5.282 8 a	4.572 2 b	4.067 0 c
2-(1-甲基-2-吡咯烷基)-吡啶2-(1-Methyl-2-pyrrolidinyl)-pyridine	—	1.445 1 a	—	0.810 0 b
萜品烯Terpinene	—	12.323 2 b	13.604 3 a	—
对-薄荷-1(7)-烯-9-醇P-Mint-1(7)-ene-9-ol	—	1.691 9 a	1.577 3 a	1.805 3 a
突厥酮Damascone	11.930 9 a	11.759 5 a	10.311 5 a	11.902 3 a
5-氨基-1-苯基吡唑5-Amino-1-phenylpyrazole	2.059 5 a	1.996 8 a	—	—
(E)-1-(2,3,6-三甲基苯基)丁-1,3-二烯(TPB,1)	—	3.858 4 a	3.770 1 a	4.113 3 a
(E) -1-(2,3,6-Trimethylphenyl) butyl-1,3-diene (TPB, 1)
3-(2,6,6-三甲基-1-环己烯基)-2-丙烯醛	—	—	0.789 2 a	0.889 9 a
3-(2,6,6-Trimethyl-1-cyclohexenyl)-2-acrolein
紫罗兰酮Ionone	0.292 3 c	0.369 8 b	0.428 1 a	0.344 1 b
2-乙基-5,7-二甲基-苯并[b]噻吩2-Ethyl-5,7-dimethyl-benzo [b] thiophene	—	—	0.717 1 b	0.866 7 a
4-异丙基肉桂酸4-Isopropyl cinnamic acid	0.872 7 a	—	—	0.875 1 a
2,4-二异丙基-5-甲基苯酚2,4-Diisopropyl-5-methylphenol	1.331 7 a	0.802 2 b	1.237 6 a	0.744 0 b
香叶基丙酮Geranyl acetone	2.984 7 a	2.797 1 a	2.723 9 a	3.052 7 a
(5-乙基环戊-1-烯基)甲醇(5-Ethylhexyl-1-alkenyl) methanol	—	2.685 6 a	2.001 5 b	—
4-(1-乙烯基-1H-咪唑-2-基)丁酸甲酯	—	—	1.732 6 b	2.580 0 a
4-(1-vinyl-1H-imidazole-2-yl) methyl butanoate
4,4,5,8-四甲基-2-醇4,4,5,8-Tetramethyl-2-ol	—	0.295 0 a	0.385 8 a	0.359 0 a
6,7-二甲氧基香豆素6,7-Dimethoxycoumarin	0.315 4 b	0.388 2 a	—	—
2,4-二叔丁基苯酚2,4-Di-tert-butylphenol	0.152 5 c	0.149 9 c	0.252 7 a	0.202 6 b
对异丙基苯甲醇P-Isopropylbenzyl alcohol	—	0.701 5 a	0.346 8 c	0.517 4 b
5,6-二甲基-2-苯并咪唑啉酮5,6-Dimethyl-2-benzimidazolone	3.422 1 a	—	3.233 1 a	3.292 1 a
2,3'-联吡啶2,3'-Bipyridine	0.463 9 b	0.487 8 b	0.644 7 a	0.341 6 c
二氢猕猴桃内酯Dihydroactinidiolide	3.645 8 a	3.778 3 a	3.494 0 a	3.650 9 a
2,5-双异丁基噻吩2,5-Diisobutylthiophene	0.329 9 a	0.296 0 a	—	0.287 5 a
橙花叔醇Nerolidol	0.289 7 a	—	—	0.337 6 a
4-甲基-2,5-二甲氧基苯甲醛4-Methyl-2,5-dimethoxybenzaldehyde	1.899 9 a	—	—	1.503 9 b
巨豆三烯酮Megastigmatrienone	27.355 8 b	28.596 3 ab	23.171 6 c	30.295 8 a
3-羟基-β-大马酮3-Hydroxy-β-damascenone	4.800 5 b	5.496 6 a	4.013 7 c	3.311 1 d
3-(1-甲基-2-丙烯基)-2,4-戊二酮3-(1-Methyl-2-propenyl)-2,4-pentanedione	—	—	0.219 3 a	0.231 9 a
4-(3-羟基-1-丁烯基)-3,5,5-三甲基-2-环己烯-1-酮	2.749 1 a	3.017 3 a	2.272 2 b	2.114 3 b
4-(3-Hydroxy-1-butenyl)-3,5,5-trimethyl-2-cyclohexen-1-one
3-丁基-1-甲基-1H-茚3-Butyl-1-methyl-1H-indene	—	0.594 8 b	—	0.887 3 a
6-氨基-2,4-二甲基-5-甲氧基喹啉6-Amino-2,4-dimethyl-5-methoxyquinoline	—	0.547 8 a	—	0.397 3 b
5-苯并吡咯5-Benzopyrrole	0.752 9 b	0.772 8 b	0.938 9 a	0.972 9 a
肉豆蔻酸甲酯Methyl myristate	0.223 3 b	0.211 8 b	0.251 8 b	0.419 0 a
(E)甲醚法尼醇(E) Methyl ether farnesol	0.339 8 a	0.342 3 a	—	0.317 9 a
4-(2,2-二甲基-6-亚甲基环己基)-2-丁酮	0.323 1 a	0.322 5 a	—	—
4-(2,2-dimethyl-6-methylene cyclohexyl)-2-butanone
喇叭茶醇Palustrol	0.373 9 b	0.334 3 b	0.097 9 c	1.225 0 a
肉豆蔻酸Myristic acid	0.803 3 b	0.695 0 c	0.761 0 bc	0.906 5 a
2,6,6-三甲基-1-(3-甲基-1,3-丁二烯基)-1,3-环己二烯	—	0.380 5 a	0.343 9 a	—
2,6,6-Trimethyl-1-(3-methyl-1,3-butadiene)-1,3-cyclohexadiene
2,3,6-三甲基-1,4-萘二酮2,3,6-Trimethyl-1,4-naphthalenedione	—	0.736 1 b	0.726 0 b	1.160 6 a
绿油脑Anthracene	0.697 1 a	0.626 3 b	0.725 6 a	0.574 7 b
螺岩兰草酮Solavetivone	0.463 9 c	1.575 9 b	1.387 0 b	2.634 9 a
6,10,14-三甲基-2-十五烷酮6,10,14-Trimethyl-2-pentadecanone	0.770 0 b	1.742 2 a	—	2.082 9 a
7,10,13-十六碳三烯酸甲酯Methyl 7,10,13-hexadecatrienoate	0.254 6 b	—	0.357 6 a	0.375 7 a
棕榈酸甲酯Methyl palmitate	12.214 0 ab	12.715 0 a	10.281 8 c	11.934 5 b
正癸烯N-decene	0.570 5 b	—	0.894 0 a	—
1,2,3,4-四氢-1,4-甲醇萘-6-醇1,2,3,4-Tetrahydro-1,4-methylnaphthalene-6-ol	0.722 7 a	—	—	0.468 1 b
异植物醇Isophytol	0.286 5 a	0.282 4 a	0.308 5 a	0.230 9 b
十七烷酸Heptadecanoic acid	—	0.798 9 a	0.461 0 b	—
棕榈酸Palmitic acid	40.862 4 b	53.500 3 a	36.110 2 c	38.352 5 c
十三酸Tridecanoic acid	2.497 9 a	—	—	0.824 4 b
(1S,2E,4R,7E,11E)-2,7,11-西柏三烯-4-醇	4.154 8 c	8.050 5 a	6.873 0 b	3.217 1 d
(1S,2E,4R,7E,11E)-2,7,11-Cedriene-4-ol
亚麻酸甲酯Methyl linolenate	7.001 4 b	8.034 6 a	5.908 9 c	6.311 5 bc
叶绿醇Phytol	8.311 4 b	9.403 2 a	8.445 6 b	6.265 6 c
1-烯丙基环丙烷甲酸1-Allylcyclopropanecarboxylic acid	—	12.135 0 a	11.518 1 a	8.266 9 b
香茅醇Citronellol	1.279 7 a	1.561 9 a	1.439 9 a	1.175 9 a
2-亚甲基-5α-胆甾-3β-醇2-Methylene-5α-cholesterol-3β-alcohol	0.817 7 c	1.213 9 b	1.803 4 a	—
氧化石竹烯Caryophyllene oxide	1.176 3 c	3.174 6 a	1.418 0 b	1.326 0 bc
香叶基香叶醇Geranylgeraniol	0.654 1 b	0.813 0 a	—	—
法尼醇Farnesol	0.561 6 c	0.654 1 b	0.957 2 a	0.330 1 d
顺式-Z-α-双酚环氧化物Cis-Z-α-Bisphenol epoxide	0.942 4 a	0.858 3 b	—	0.349 9 c
金合欢基丙酮Farnesyl acetone	—	—	0.345 4 a	0.382 1 a
反式-法尼基丙酮Trans-farnesyl acetone	0.637 8 c	—	0.778 5 b	0.920 2 a
己二酸二辛酯Dioctyl adipate	—	—	0.311 3 a	0.215 3 b
N-糠基-环己烷甲酰胺N-Furfuryl-cyclohexane formamide	0.642 3 a	0.339 7 c	0.455 6 b	0.291 4 c
新植二烯Neophytadiene	511.324 9 b	535.784 2 a	529.243 8 a	515.034 7 b
合计(除新植二烯)Total (except neophytadiene)	194.925 4 c	249.041 4 a	206.383 7 b	210.053 9 b
合计Total	706.250 3 c	784.825 6 a	735.627 5 b	725.088 6 b

香味成分种类 Classification of aroma components	不同处理的含量Content under treatments
香味成分种类 Classification of aroma components	T1	T2	T3	T4
烯类Alkenes	513.071 7 b	555.520 9 a	549.274 1 a	520.47 4 b
酮类Ketones	59.339 0 b	60.053 0 b	53.013 2 c	65.637 3 a
酸类Acids	46.280 9 c	68.912 7 a	51.915 1 b	53.099 7 b
醇类Alcohols	31.119 7 bc	42.223 6 a	32.626 7 b	30.776 2 c
酯类Esters	23.692 8 b	25.260 6 a	20.990 6 c	23.198 8 b
醛类Aldehydes	15.220 4 b	13.272 6 d	14.242 8 c	16.460 3 a
酚类Phenols	7.355 9 a	7.052 4 ab	6.841 3 b	5.879 2 c
吡咯类Pyrrolidines	3.521 7 a	3.698 4 a	2.810 3 b	3.709 7 a
呋喃类Furans	0.950 4 b	0.910 2 c	1.01 1 a	0.716 2 d
吡啶类Pyridines	0.463 9 d	1.977 8 a	0.669 8 c	1.288 2 b
其他Others	5.233 9 b	5.943 4 a	2.232 6 d	3.849 0 c

香味成分种类 Classification of aroma components	不同处理的含量Content under treatments
香味成分种类 Classification of aroma components	T1	T2	T3	T4
烯类Alkenes	513.071 7 b	555.520 9 a	549.274 1 a	520.47 4 b
酮类Ketones	59.339 0 b	60.053 0 b	53.013 2 c	65.637 3 a
酸类Acids	46.280 9 c	68.912 7 a	51.915 1 b	53.099 7 b
醇类Alcohols	31.119 7 bc	42.223 6 a	32.626 7 b	30.776 2 c
酯类Esters	23.692 8 b	25.260 6 a	20.990 6 c	23.198 8 b
醛类Aldehydes	15.220 4 b	13.272 6 d	14.242 8 c	16.460 3 a
酚类Phenols	7.355 9 a	7.052 4 ab	6.841 3 b	5.879 2 c
吡咯类Pyrrolidines	3.521 7 a	3.698 4 a	2.810 3 b	3.709 7 a
呋喃类Furans	0.950 4 b	0.910 2 c	1.01 1 a	0.716 2 d
吡啶类Pyridines	0.463 9 d	1.977 8 a	0.669 8 c	1.288 2 b
其他Others	5.233 9 b	5.943 4 a	2.232 6 d	3.849 0 c

香味成分 Aroma component	不同处理的含量Content under treatments
香味成分 Aroma component	T1	T2	T3	T4
环戊酮Cyclopentanone	0.255 7 b	0.396 5 a	0.385 4 a	0.381 0 a
吡啶Pyridine	0.247 5 b	0.332 2 a	0.350 0 a	0.318 7 a
2-甲基四氢呋喃-3-酮2-Methyltetrahydrofuran-3-one	0.295 6 c	0.471 2 a	0.391 4 b	0.299 9 c
糠醛Furfural	5.069 7 c	6.944 7 b	8.966 1 a	8.512 4 a
2-甲基丁酸2-Methylbutyric acid	0.254 5 d	0.352 6 c	0.658 0 a	0.467 9 b
糠醇Furfuryl alcohol	0.450 7 d	1.281 7 c	2.042 4 a	1.579 8 b
4-环戊烯-1,3-二酮4-Cyclopentene-1,3-dione	0.457 8 c	0.964 1 b	1.728 9 a	1.741 3 a
2-乙酰基呋喃2-Acetylfuran	0.192 0 c	0.268 7 ab	0.309 8 a	0.255 8 b
4-羟基丁酸内酯4-Hydroxybutyrolactone	0.387 2 b	0.533 8 a	0.230 7 c	0.421 2 b
苯甲醛Benzaldehyde	0.590 8 c	1.094 4 a	0.805 2 b	1.135 1 a
苯酚Phenol	0.343 2 d	0.895 3 b	0.721 7 c	0.968 1 a
甲基庚烯酮Methyl heptenone	0.524 3 c	0.610 9 b	0.722 3 a	0.626 2 b
2-正戊基呋喃2-Pentylfuran	0.180 0 c	0.318 5 ab	0.336 8 a	0.273 2 b
反式-2,4-庚二烯醛Trans-2,4-Heptadienal	0.347 8 b	0.293 6 c	0.340 4 b	0.481 4 a
苯甲醇Benzyl alcohol	1.467 9 c	2.770 7 a	2.665 0 a	1.790 1 b
苯乙醛Phenylacetaldehyde	2.940 6 c	4.363 0 a	3.904 6 b	4.076 6 ab
2-乙酰基吡咯2-Acetyl pyrrole	0.377 9 d	0.604 2 c	1.260 4 a	1.079 4 b
愈创木酚Guaiacol	0.232 4 ab	0.261 9 a	0.267 9 a	0.190 5 b
芳樟醇Linalool	0.732 2 a	0.689 0 a	0.709 8 a	0.460 4 b
壬醛Nonanal	0.247 0 a	0.195 0 a	0.228 1 a	0.183 1 a
苯乙醇Benzyl carbinol	2.216 3 c	3.008 8 b	3.724 7 a	3.759 7 a
2,6,6-三甲基-2-环己烯-1,4-二酮	0.229 8 c	0.246 0 c	0.301 1 b	0.396 5 a
2,6,6-Trimethyl-2-cyclohexene-1,4-dione
2-甲基-5-(1-甲基乙烯基)-环己酮	0.138 6 c	0.409 9 a	0.296 2 b	0.399 4 a
2-Methyl-5-(1-methylethenyl)-cyclohexanone
L-α-松油醇L-α-Terpineol	0.302 2 a	0.307 3 a	0.319 1 a	0.224 4 b
2,3-二氢-2,2,6-三甲基苯甲醛	0.248 9 a	0.259 9 a	0.292 1 a	0.219 6 a
2,3-Dihydro-2,2,6-trimethylbenzaldehyde
2,3-二氢苯并呋喃2,3-Dihydrobenzofuran	0.259 2 c	0.238 8 c	0.615 6 a	0.452 0 b
香叶醇Geraniol	0.166 6 b	0.201 7 b	0.281 1 a	0.192 0 b
苯并吡咯Benzopyrrole	0.421 9 c	0.559 7 b	0.768 0 a	0.612 8 b
对乙烯基愈创木酚P-Vinylguaiacol	2.106 3 c	3.212 7 b	4.572 3 a	3.080 0 b
对-薄荷-1(7)-烯-9-醇P-Mint-1(7)-ene-9-ol	1.847 7 c	2.328 6 b	2.725 9 a	2.601 3 a
突厥酮Damascone	8.760 1 c	12.039 7 a	10.685 1 b	10.412 9 b
(E)-1-(2,3,6-三甲基苯基)丁-1,3-二烯(TPB,1)	2.734 5 c	4.153 9 b	5.056 8 a	4.176 3 b
(E)-1-(2,3,6-Trimethylphenyl) butyl-1,3-diene (TPB, 1)
紫罗兰酮Ionone	0.279 9 b	0.409 1 a	0.420 4 a	0.397 9 a
4-异丙基肉桂酸4-Isopropyl cinnamic acid	0.781 2 b	0.911 8 a	0.906 0 a	0.741 8 b
2,4-二异丙基-5-甲基苯酚2,4-Diisopropyl-5-methylphenol	0.564 7 d	0.805 7 c	2.048 9 a	1.245 1 b
香叶基丙酮Geranyl acetone	3.395 1 c	3.066 1 c	6.416 7 b	8.427 7 a
2,4-二叔丁基苯酚2,4-Di-tert-butylphenol	0.181 8 b	0.193 2 b	0.299 8 a	0.328 7 a
5,6-二甲基-2-苯并咪唑啉酮5,6-Dimethyl-2-benzimidazolone	1.698 6 c	1.460 3 c	3.239 4 a	2.461 8 b
2,3'-联吡啶2,3'-Bipyridine	0.464 4 c	0.829 1 a	0.560 4 b	0.785 7 a
二氢猕猴桃内酯Dihydroactinidiolide	1.322 4 c	1.262 6 c	2.948 1 a	2.567 6 b
橙花叔醇Nerolidol	0.286 6 c	0.265 1 c	0.639 3 b	0.705 4 a
巨豆三烯酮Megastigmatrienone	21.698 0 c	30.560 4 a	27.621 8 b	18.639 8 d
3-羟基-β-大马酮3-Hydroxy-β-damascenone	0.956 2 b	0.879 7 b	2.459 5 a	2.450 7 a
4-(3-羟基-1-丁烯基)-3,5,5-三甲基-2-环己烯-1-酮	0.475 1 b	0.294 8 b	1.051 6 a	1.227 4 a
4-(3-hydroxy-1-butenyl)-3,5,5-trimethyl-2-cyclohexen-1-one
5-苯并吡咯5-Benzopyrrole	0.513 3 c	0.511 8 c	0.928 0 a	0.591 6 b
肉豆蔻酸甲酯Methyl myristate	0.186 7 c	0.269 7 ab	0.230 0 b	0.276 5 a
肉豆蔻酸Myristic acid	0.491 7 d	0.635 3 c	0.803 0 b	0.866 1 a
2,3,6-三甲基-1,4-萘二酮2,3,6-Trimethyl-1,4-naphthalenedione	0.442 7 c	1.211 9 b	1.229 7 b	1.767 1 a
绿油脑Anthracene	0.359 2 ab	0.305 2 b	0.389 1 a	0.316 1 b
螺岩兰草酮Solavetivone	0.333 7 d	1.111 2 a	0.487 1 c	0.605 4 b
6,10,14-三甲基-2-十五烷酮6,10,14-Trimethyl-2-pentadecanone	0.727 3 d	1.646 4 b	1.257 5 c	4.324 8 a
异植物醇Isophytol	0.084 8 d	0.168 0 c	0.290 4 a	0.239 4 b
棕榈酸Palmitic acid	1.963 4 d	3.576 4 c	6.9038 b	12.518 4 a
邻苯二甲酸二丁酯Dibutyl phthalate	25.063 8 c	35.779 0 b	25.036 1 c	39.984 8 a
合金欢醇Farnesol	0.532 2 c	1.186 8 a	0.914 2 b	0.921 1 b
(1S, 2E, 4R, 7E, 11E)-2,7,11-西柏三烯-4-醇	2.830 2 d	13.965 8 a	10.473 3 b	8.631 9 c
(1S, 2E, 4R, 7E, 11E)-2,7,11-Cedriene-4-ol
亚麻酸甲酯Methyl linolenate	2.010 8 d	3.487 5 b	4.665 5 a	3.180 1 c
叶绿醇Phytol	13.557 1 b	15.957 2 a	10.903 9 c	14.223 1 b
1-烯丙基环丙烷羧酸1-Allylcyclopropanecarboxylic acid	4.190 1 c	5.240 4 c	11.737 7 b	14.062 5 a
己二酸二辛酯Dioctyl adipate	0.327 8 ab	0.286 9 bc	0.353 6 a	0.272 3 c
新植二烯Neophytadiene	276.949 6 c	377.011 9 a	351.241 0 b	276.147 0 c
合计(除新植二烯)Total (except neophytadiene)	139.480 9 c	226.191 0 b	242.324 8 a	239.405 1 a
总量Total	416.430 5 c	603.202 9 a	593.565 8 a	515.552 1 b

不同时期叶面喷施钼肥对烤烟香味成分的影响

Effects of foliar application of molybdenum fertilizer at different growth stages on aroma components of flue-cured tobacco

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香味成分种类 Classification of aroma components	不同处理的含量Content under treatments
香味成分种类 Classification of aroma components	T1	T2	T3	T4
烯类Alkenes	279.830 1 c	384.444 2 a	358.434 2 b	283.731 7 c
酮类Ketones	43.447 9 c	66.121 3 a	67.396 1 a	60.682 7 b
酸类Acids	8.179 9 d	12.433 9 c	23.452 3 b	30.954 3 a
醇类Alcohols	28.543 8 d	47.529 0 c	52.628 2 a	50.584 2 b
酯类Esters	35.995 1 d	61.111 9 a	55.510 9 b	53.806 0 c
醛类Aldehydes	11.463 4 b	16.626 1 a	17.003 0 a	17.348 2 a
酚类Phenols	3.754 9 c	6.064 0 b	8.014 6 a	6.539 3 b
吡咯类Pyrrolidines	1.313 1 d	1.675 7 c	2.956 4 a	2.283 8 b
呋喃类Furans	0.631 2 d	0.826 0 c	1.262 2 a	0.981 0 b
吡啶类Pyridines	0.711 9 c	2.549 4 a	2.353 8 a	2.101 9 b
其他Others	2.559 2 d	3.821 4 c	4.554 1 b	6.539 0 a

香味成分 Aroma component	不同处理的含量Content under treatments
香味成分 Aroma component	T1	T2	T3	T4
环戊酮Cyclopentanone	0.322 8 b	0.345 8 b	0.333 3 b	0.494 6 a
糠醛Furfural	5.870 3 ab	5.693 1 b	4.168 8 c	6.356 2 a
糠醇Furfuryl alcohol	0.982 8 b	1.213 3 a	1.264 4 a	1.320 1 a
4-环戊烯-1,3-二酮4-Cyclopentene-1,3-dione	0.616 7 c	0.830 4 a	0.756 2 b	0.885 5 a
2-乙酰基呋喃2-Acetyl furan	0.203 9 b	0.170 5 b	0.272 1 a	0.182 4 b
5-甲基-2-呋喃甲醇5-Methyl-2-furanmethanol	0.397 4 ab	0.353 3 b	0.229 2 c	0.418 6 a
苯甲醛Benzaldehyde	0.332 2 c	0.489 2 b	0.270 2 c	0.692 6 a
甲基庚烯酮Methyl heptenone	0.593 5 a	0.488 4 b	0.475 9 b	0.349 9 c
反式-2,4-庚二烯醛Trans-2,4-Heptadienal	0.634 2 a	0.645 0 a	0.425 7 c	0.544 0 b
苯甲醇Benzyl alcohol	1.619 2 b	3.645 0 a	0.938 3 c	3.795 4 a
苯乙醛Phenylacetaldehyde	3.3306 c	3.8306 b	2.7512 d	4.5017 a
2-乙酰基吡咯2-Acetyl pyrrole	0.4823 b	1.0299 a	0.4434 b	0.9517 a
芳樟醇Linalool	0.280 2 a	0.325 7 a	0.328 0 a	0.289 1 a
壬醛Nonanal	0.253 3 a	0.285 8 a	0.225 1 a	0.248 1 a
苯乙醇Benzyl carbinol	1.708 6 c	2.787 0 b	1.112 7 d	3.257 7 a
2,6,6-三甲基-2-环己烯-1,4-二酮2,6,6-Trimethyl-2-cyclohexene-1,4-dione	0.146 0 c	0.207 6 b	0.134 2 c	0.277 6 a
L-α-松油醇L-α-Terpineol	0.214 5 ab	0.189 1 bc	0.253 0 a	0.156 8 c
2,3-二氢-2,2,6-三甲基苯甲醛2,3-Dihydro-2,2,6-trimethylbenzaldehyde	0.192 9 a	0.215 9 a	0.218 9 a	0.245 4 a
2,3-二氢苯并呋喃2,3-Dihydrobenzofuran	0.239 7 c	0.366 5 b	0.177 5 d	0.425 7 a
2,6,6-三甲基-1-环己烯-1-羧醛	0.189 7 a	0.192 7 a	0.160 6 a	0.196 3 a
2,6,6-Trimethyl-1-cyclohexene-1-carboxyaldehyde
苯并吡咯Benzopyrrole	0.517 7 b	0.672 6 a	0.516 0 b	0.711 6 a
对乙烯基愈创木酚P-Vinylguaiacol	3.051 7 b	3.812 6 a	1.876 8 c	3.327 4 b
对-薄荷-1(7)-烯-9-醇P-Mint-1(7)-ene-9-ol	1.241 2 c	1.445 4 b	1.659 9 a	1.463 7 b
突厥酮Damascone	13.809 2 ab	14.326 0 a	9.485 8 c	13.162 9 b
(E)-1-(2,3,6-三甲基苯基)丁-1,3-二烯(TPB,1)	3.623 9 a	3.324 2 a	2.802 5 b	3.310 4 a
(E) -1-(2,3,6-Trimethylphenyl) butyl-1,3-diene (TPB, 1)
2,4-二异丙基-5-甲基苯酚2,4-Diisopropyl-5-methylphenol	0.574 1 d	1.049 7 c	1.459 1 b	1.652 2 a
香叶基丙酮Geranyl acetone	3.850 4 a	3.854 9 a	2.984 7 b	3.862 4 a
2,4-二叔丁基苯酚2,4-Di-tert-butylphenol	0.204 7 a	0.232 9 a	0.191 4 a	0.168 1 a
2,3'-联吡啶2,3'-Bipyridine	0.240 3 b	0.305 6 a	0.342 1 a	0.241 3 b
二氢猕猴桃内酯Dihydroactinidiolide	1.606 7 b	3.000 3 a	1.404 2 b	2.737 5 a
巨豆三烯酮Megastigmatrienone	20.283 4 c	24.777 1 b	18.605 5 c	27.248 3 a
3-羟基-β-大马酮3-Hydroxy-β-damascenone	1.458 0 c	3.437 3 a	0.604 1 d	2.546 1 b
4-(3-羟基-1-丁烯基)-3,5,5-三甲基-2-环己烯-1-酮	0.665 2 c	1.386 4 a	0.498 8 d	1.106 3 b
4-(3-Hydroxy-1-butenyl)-3,5,5-trimethyl-2-cyclohexen-1-one
2,3,6-三甲基-1,4-萘二酮2,3,6-Trimethyl-1,4-naphthalenedione	0.451 8 c	0.778 7 a	0.346 5 d	0.624 3 b
棕榈酸甲酯Methyl palmitate	8.562 5 c	12.719 6 a	10.325 1 b	10.220 2 b
异植物醇Isophytol	0.290 1 bc	0.321 1 b	0.251 9 c	0.385 9 a
棕榈酸Palmitic acid	2.234 1 b	3.514 2 a	0.593 3 c	3.543 2 a
邻苯二甲酸二丁酯Dibutyl phthalate	8.139 6 b	6.023 1 d	7.062 2 c	9.737 4 a
(1S, 2E, 4R, 7E, 11E)-2,7,11-西柏三烯-4-醇	1.473 9 b	2.170 7 a	1.068 5 c	1.287 5 bc
(1S, 2E, 4R, 7E, 11E)-2,7,11-Cedriene-4-ol
亚麻酸甲酯Methyl linolenate	1.650 3 c	3.962 9 b	1.012 9 d	5.240 9 a
叶绿醇Phytol	3.547 6 b	5.635 0 a	2.364 7 c	6.194 0 a
1-烯丙基环丙烷羧酸1-Allylcyclopropanecarboxylic acid	2.335 1 c	6.136 2 a	2.653 8 c	4.006 4 b
氧化石竹烯Caryophyllene oxide	0.405 8 a	0.399 6 a	0.235 6 c	0.315 5 b
乙酰柠檬酸三丁酯Tributyl acetylcitrate	0.743 7 b	1.165 5 a	0.873 0 b	0.916 0 b
己二酸二辛酯Dioctyl adipate	0.387 2 a	0.326 4 b	0.304 8 b	0.405 3 a
新植二烯Neophytadiene	270.417 2 c	356.959 3 a	341.057 5 b	355.984 8 a
合计(除新植二烯)Total (except neophytadiene)	114.098 2 c	154.850 8 a	102.637 9 d	149.020 2 b
合计Total	384.515 4 c	511.810 1 a	443.695 4 b	505.005 0 a

香味成分种类 Classification of aroma components	不同处理的含量Content under treatments
香味成分种类 Classification of aroma components	T1	T2	T3	T4
烯类Alkenes	274.406 6 c	361.308 8 a	344.075 1 b	359.894 8 a
酮类Ketones	46.246 9 c	65.428 1 a	45.455 9 c	56.616 8 b
酸类Acids	5.737 6 c	10.296 1 a	3.247 1 d	9.347 4 b
醇类Alcohols	14.205 1 b	22.485 2 a	12.085 8 c	21.693 4 a
酯类Esters	23.267 1 b	30.681 3 a	21.967 8 b	29.800 0 a
醛类Aldehydes	12.634 8 a	12.549 6 a	8.902 9 b	13.503 8 a
酚类Phenols	3.830 5 d	5.718 2 b	4.617 1 c	6.580 0 a
吡咯类Pyrrolidines	1.000 0 b	1.702 5 a	0.959 4 b	1.663 3 a
呋喃类Furans	0.443 6 b	0.537 0 a	0.449 6 b	0.608 1 a
其他Others	2.743 2 d	3.612 6 c	6.819 2 a	5.045 9 b

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