›› 2011, Vol. 23 ›› Issue (2): 0-357.

• 植物保护 •    

毒死蜱与有机硅混用对四季豆的残留降解与安全间隔期的影响

朱金星1,2,郑永利 3,吴长兴4,陈丽萍4,吴声敢4,赵学平4,*
  

  1. 1浙江大学 农业与生物技术学院,浙江 杭州 310029;2浙江省遂昌县农业局植保站,浙江 遂昌 323300;3浙江省植物保护检疫局,浙江 杭州 310020;4浙江省植物有害生物防控重点实验室——省部共建国家重点实验室培育基地,浙江省农业科学院 农产品质量标准研究所,浙江 杭州 310021
  • 收稿日期:1900-01-01 修回日期:1900-01-01 出版日期:2011-03-25 发布日期:2011-03-25

Residue decline and pre-harvest interval of chlorpyrifos mixed with organosilicon surfactants in kidney bean

ZHU Jin-xing;ZHENG Yong-li;WU Chang-xing;CHEN Li-ping;WU Sheng-gan;ZHAO Xue-ping;*   

  1. 1 College of Agriculture and Biotechnology, Zhejiang University, Hangzhou 310029, China; 2 Plant Protection Station, Bureau of Agriculture of Suichang, Suichang 323300, China; 3Zhejiang Bureau of Plant Protection and Quarantine, Hangzhou 310020,China;4State Key Laboratory Breeding Base for Zhejiang Sustainable Pest and Disease Control, Institute of Quality and Standards for Agricultural Products, Zhejiang Academy of Agricultural Sciences, Hangzhou 310021,China
  • Received:1900-01-01 Revised:1900-01-01 Online:2011-03-25 Published:2011-03-25

摘要: 研究了不同有机硅表面活性剂与毒死蜱混用对四季豆的残留降解和安全间隔期的影响。结果表明:毒死蜱在四季豆中的降解动态符合一级动力学方程,且毒死蜱在四季豆中单独使用时的原始残留量较低,而不同有机硅剂型与毒死蜱混用处理对四季豆中的残留量有不同的影响;毒死蜱与有机硅混合处理的残留量高于单独处理,但对四季豆中毒死蜱的降解速率与半衰期影响不大。根据毒死蜱在四季豆中的残留降解动态方程,计算出不同间隔期的理论残留量,并参照国外标准计算安全间隔期在5 d左右。结论认为,尽管毒死蜱及其与有机硅混用时在四季豆中的残留量可符合CAC的标准要求,但较难达到欧盟、美国和日本的标准要求。

关键词: 有机硅表面活性剂, 毒死蜱, 四季豆, 安全间隔期, 农药残留

Abstract: The residue decline and pre\|harvest interval of chlorpyrifos mixed with organosilicon surfactants in kidney beans have been studied. The results showed that the dynamic decline of chlorpyrifos was consistent with a first\|order kinetic equation, and the original residue of chlorpyrifos applied singly was relatively lower in kidney bean, while it was quite different in the residue in kidney bean when treated with chlorpyrifos mixed with different organosilicon surfactants and the residue was higher than single treatment with chlorpyrifos or organosilicon surfactants; however, there were less influence on its degradation rate and half\|life. According to the dynamic degradation equation of chlorpyrifos in kidney beans, the theoretical residues were estimated in different intervals, and the pre-intervals were about 5 days calculated with the reference of foreign standards. Therefore, the conclusion was that the residue of chlorpyrifos in kidney bean when mixed with organosilicon surfactants readily met the requirement of CAC standards, but not EU, U.S.A and Japan.

Key words: organosilicon surfactant, cloripyfos, kidney bean, pre-harvest interval, pesticide residue