浙江农业学报

• 生物系统工程 • 上一篇    下一篇

生物质原料及炭化温度对生物炭产率与性质的影响

  

  1. (1.浙江师范大学 化学与生命科学学院,浙江 金华 321004; 2.浙江省农业科学院 环境资源与土壤肥料研究所,浙江 杭州 310021; 3.浙江省生物炭工程技术研究中心,浙江 杭州 310021)
  • 出版日期:2016-07-25 发布日期:2016-07-08

Effects of biomass and carbonization temperature on biochar yield and characteristics

  1. (1. College of Chemistry and Life Sciences, Zhejiang Normal University, Jinhua 321004, China; 2. Institute of Environment, Resource, Soil & Fertilizer, Zhejiang Academy of Agricultural Sciences, Hangzhou 310021, China; 3. Zhejiang Biochar Engineering and Technology Research Center, Hangzhou 310021, China)
  • Online:2016-07-25 Published:2016-07-08

摘要: 本研究以竹片、山核桃壳、水稻及油菜秸秆等4种生物质为原料,通过热重分析研究各生物质材料性质与热解特性及生物炭产率之间的关系;并在300~700 ℃下热解6 h制备生物炭,分析生物炭的元素组成及官能团结构。结果表明,在低温段(300~400 ℃),生物质材料中的纤维素、木质素等组分对生物炭产率影响较明显,木质素含量高的材料产率较高;而400 ℃以上则是灰分含量对生物炭产率影响较大,水稻及油菜秸秆由于灰分含量高,其400 ℃以上的生物炭产率高于竹片及山核桃壳。随着炭化温度的升高,生物炭灰分含量增加,无灰基的碳含量增大,稳定性增强;仅水稻秸秆炭由于灰分含量较高,在高温(500~700 ℃)条件下仍有部分含氧官能团存在。综上,生物炭在一定温度下的产率取决于生物质材料来源,而生物炭的稳定性则主要由炭化温度决定,且温度越高,性质越稳定。

关键词: 生物炭, 生物质, 炭化温度, 产率, 稳定性

Abstract: In the present study, biochars were fabricated from biomass bamboo, pecan shell, rice and rape straw through slow pyrolysis in a vacuum environment at 300-700 ℃ for 6 h, respectively, and the relationship of material properties, pyrolysis characteristics and biochar yield were investigated by thermal gravimetric analysis. The obtained biochars were characterized in terms of its elemental composition and oxygencontaining functional group composition. It was shown that biomass material compositions had obvious influence on the yield of biochar at the pyrolytic temperature of 300-400 ℃. The biochar yield increased with the increasing of lignin content. Nevertheless, at high temperature (>400 ℃), the ash content of biochar dominated the biochar yield. Due to the high ash content in the rice and rape straw, the yield of biochar derived from rice and rape straw was higher than that derived from bamboo and pecan shell. With the increasing of carbonization temperature, the ash, ash less carbon content and the stability of biochars increased, except that rice straw still had some oxygencontaining functional groups at high temperature (500-700 ℃). In conclusion, yield of biochar was dependent on the biomass material at certain temperature, and the stability of biochar was determined by the carbonization temperature in the present study.

Key words: biochar, biomass, carbonization temperature, yield, stability