农药水解半衰期的pH值敏感性评价

doi:10.3969/j.issn.1004-1524.20221205

浙江农业学报 ›› 2023, Vol. 35 ›› Issue (9): 2130-2148.DOI: 10.3969/j.issn.1004-1524.20221205

农药水解半衰期的pH值敏感性评价

李辉¹(), 胡文兰², 张志恒¹^,^*()

1.浙江省农业科学院农产品质量安全与营养研究所,浙江杭州 310021
2.浙江省杭州市拱墅区疾病预防控制中心,浙江杭州310022

收稿日期:2022-08-18 出版日期:2023-09-25 发布日期:2023-10-09
作者简介:*张志恒, E-mail: zhihengest@126.com
李辉(1995—),女,山西朔州人,硕士,主要从事农药风险评估与合理使用研究。E-mail: 996325960@qq.com
通讯作者: 张志恒
基金资助:
国家重点研发计划(2018YFF0213404)

pH value sensibility evaluation of pesticides hydrolysis half-life

LI Hui¹(), HU Wenlan², ZHANG Zhiheng¹^,^*()

1. Institute of Agro-Product Safety and Nutrition, Zhejiang Academy of Agricultural Sciences, Hangzhou 310021, China
2. Gongshu District Center for Disease Control and Prevention, Hangzhou 310022, China

Received:2022-08-18 Online:2023-09-25 Published:2023-10-09
Contact: ZHANG Zhiheng

摘要/Abstract

摘要：

为了量化环境pH值变化对农药半衰期的影响程度,基于不同环境pH值下的农药半衰期数据,建立了农药半衰期的pH值敏感性指数评价方法,并根据指数大小将敏感性分为3A、2A、1A、0、1B、2B和3B共7个等级。利用该方法对305种农药水解半衰期进行的评价结果:pH值敏感性指数在-1.67~3.31,指数平均值为0.50,指数绝对值平均值为0.60。多数农药的水解半衰期pH值敏感性指数为正值,在环境pH值提高时会促进水解。其中氨基甲酸酯类、二苯醚类和芳氧苯氧丙酸酯类除草剂,氨基甲酸酯类和拟除虫菊酯类杀虫剂,二甲酰亚胺类和苯并咪唑类杀菌剂尤为显著。而三嗪类和磺酰脲类除草剂则比较独特,总体上有随着pH值的降低水解加快的趋势。农药半衰期的pH值敏感性指数,能直观地反映环境pH值变化对农药半衰期的影响程度。

关键词: 农药, 水解, pH值, 半衰期

Abstract:

In order to quantify the influence of environmental pH value changes on pesticide half-life, a pH value sensibility index evaluation method was established based on pesticides half-life data under different environmental pH values. The sensibility was divided into seven grades including 3A, 2A, 1A, 0, 1B, 2B and 3B according to the index. The results of the evaluation of the hydrolysis half-life of 305 pesticides showed that the pH value sensibility index ranged from -1.67 to 3.31, the average was 0.50, and the average of absolute value for index was 0.60. The pH value sensibility index of the hydrolysis half-life of most pesticides was positive, which will promote hydrolysis when the pH value increased in the environment. Carbamate, diphenyl ethers and aryloxyphenoxypropionate herbicides, carbamate and pyrethroid insecticides, dicarboximidies and benzimidazole fungicides were particularly significant. However, triazine and sulfonylurea herbicides were unique and had a tendency to accelerate hydrolysis when the pH value decreased. The pH value sensibility index of pesticide half-life can directly reflect the influence degree of environmental pH value change on pesticide half-life.

Key words: pesticide, hydrolysis, pH value, half-life

中图分类号:

李辉, 胡文兰, 张志恒. 农药水解半衰期的pH值敏感性评价[J]. 浙江农业学报, 2023, 35(9): 2130-2148.

LI Hui, HU Wenlan, ZHANG Zhiheng. pH value sensibility evaluation of pesticides hydrolysis half-life[J]. Acta Agriculturae Zhejiangensis, 2023, 35(9): 2130-2148.

图/表 5

参考文献 69

[1]	MAGGI F, TANG F H M, BLACK A J, et al. The pesticide health risk index-An application to the world’s countries[J]. Science of the Total Environment, 2021, 801: 149731.
[2]	束放, 李永平, 魏启文. 2018年种植业农药使用情况及2019年需求分析[J]. 中国植保导刊, 2019, 39(4): 73-76.
	SHU F, LI Y P, WEI Q W. Pesticide use in planting industry in 2018 and demand analysis in 2019[J]. China Plant Protection, 2019, 39(4): 73-76. (in Chinese with English abstract)
[3]	KUMAR S, KAUSHIK G, DAR M A, et al. Microbial degradation of organophosphate pesticides: a review[J]. Pedosphere, 2018, 28(2): 190-208.
[4]	DELCOUR I, SPANOGHE P, UYTTENDAELE M. Literature review: impact of climate change on pesticide use[J]. Food Research International, 2015, 68: 7-15.
[5]	环境保护部南京环境科学研究所. 农药毒性手册-杀虫剂分册[M]. 北京: 科学出版社, 2016.
[6]	生态环境部南京环境科学研究所. 农药毒性手册-杀菌剂分册[M]. 北京: 科学出版社, 2018.
[7]	环境保护部南京环境科学研究所. 农药毒性手册-除草剂分册[M]. 北京: 科学出版社, 2017.
[8]	谢恩平, 林亲铁, 杨仁斌. 克百威丙硫克百威和丁硫克百威的残留与降解研究进展[J]. 农药科学与管理, 2002, 23(3):18-20, 28.
	XIE E P, LIN Q T, YANG R B. The research development of residue and degredation for carbofuran, benfuracarb and carbosulfan[J]. Pesticide Science and Administration, 2002, 23(3):18-20, 28. (in Chinese with English abstract)
[9]	PA G, SL W. Endosulfan in the Rhine River[J]. Journal of Water Pollution Control Federation, 1971, 43: 2338.
[10]	SARKAR M A, BISWAS P K, ROY S, et al. Effect of pH and type of formulation on the persistence of imidacloprid in water[J]. Bulletin of Environmental Contamination and Toxicology, 1999, 63(5): 604-609.
[11]	The Agriculture & Environment Research Unit (AERU) at the University of Hertfordshire, Pesticides Properties[DB/OL]. http://sitem.herts.ac.uk/aeru/iupac/atoz.htm, (2022-06-23)[2022-06-28].
[12]	USEPA. Revised FED environmental risk assessment for profenofos[DB/OL]. (2002-01-07) [2020-10-13] http:www.epa.gov/pesticides/op/profenofos/prof_efed.pdf.
[13]	TOMLIN C D S. The pesticide manual: A world compendium[M]. 11th ed. Surrey: British Crop Protection Council, 1997.
[14]	KATAGI T. Abiotic hydrolysis of pesticides in the aquatic environment[J]. Reviews of Environmental Contamination and Toxicology, 2002, 175: 79-261.
[15]	CHAPMAN R A, COLE C M. Observations on the influence of water and soil pH on the persistence of insecticides[J]. Journal of Environmental Science and Health, Part B, 1982, 17(5): 487-504.
[16]	RUZICKA J H, THOMSON J, WHEALS B B. The gas chromatographic determination of organo-phosphorus pesticides[J]. Journal of Chromatography A, 1967, 31: 37-47.
[17]	MEIKLE R W, YOUNGSON C R. The hydrolysis rate of chlorpyrifos, O-O-diethylO-(3, 5, 6-trichloro-2-pyridyl) phosphorothioate, and its dimethyl analog, chlorpyrifos-methyl, in dilute aqueous solution[J]. Archives of Environmental Contamination and Toxicology, 1978, 7(1): 13-22.
[18]	邹品田, 邵书念, 陈珊, 等. pH和温度对丁硫克百威水解速率的影响[C]// 中国毒理学会第六届全国毒理学大会论文摘要.中国毒理学会, 2013: 2.
[19]	HARTLEY D, KIDD H. The Agrochemicals Handbook[J]. Lechworth: The Royal Society of Chemistry, 1987.
[20]	BOBÉ A, MEALLIER P, COOPER J F, et al. Kinetics and mechanisms of abiotic degradation of fipronil (hydrolysis and photolysis)[J]. Journal of Agricultural and Food Chemistry, 1998, 46(7): 2834-2839.
[21]	孔德洋, 石利利, 单正军, 等. 甲氨基阿维菌素苯甲酸盐的降解性研究[J]. 生态与农村环境学报, 2009, 25(4):88-91.
	KONG D Y, SHI L L, SHAN Z J, et al. Photolysis and hydrolysis of emamectin benzoate and its degradation in soils[J]. Journal of Ecology and Rural Environment, 2009, 25(4):88-91. (in Chinese with English abstract)
[22]	WOLFE N L, ZEPP R G, PARIS D F. Carbaryl, propham and chlorpropham: a comparison of the rates of hydrolysis and photolysis with the rate of biolysis[J]. Water Research, 1978, 12(8): 565-571.
[23]	ALY O M, EL-DIB M A. Organic compounds in aquatic environment[M]. New York: Marcel Dekker, 1971.
[24]	GEISSBÜHLER H, VOSS G, ANLIKER R. The metabolism of phosphamidon in plants and animals[J]. Residue Reviews, 1971, 37: 39-60.
[25]	温娟, 周硕, 于静洁, 等. 不同水环境条件下马拉硫磷的降解规律[J]. 农药, 2013, 52(3): 210-212.
	WEN J, ZHOU S, YU J J, et al. Malathion degradation law in different aquatic environment[J]. Agrochemicals, 2013, 52(3): 210-212. (in Chinese with English abstract)
[26]	张冲, 葛峰, 单正军, 等. 噻虫啉环境行为研究[J]. 农药, 2010, 49(11):830-833.
	ZHANG C, GE F, SHAN Z J, et al. Study on environmental behavior of thiacloprid[J]. Agrochemicals, 2010, 49(11):830-833. (in Chinese with English abstract)
[27]	CHAPMAN R A, TU C M, HARRIS C R, et al. Biochemical and chemical transformations of phorate, phorate sulfoxide, and phorate sulfone in natural and sterile mineral and organic soil[J]. Journal of Economic Entomology, 1982, 75(1): 112-117.
[28]	石利利, 单正军, 金怡. S-生物烯丙菊酯水解特性与机制研究[C]// 中国化学会色谱专业委员会、中国色谱学会、中国科学院大连化学物理研究所.第十五次全国色谱学术报告会文集(上册). 中国化学会, 2005: 2.
[29]	WORTHING C R, WALKER S B. The pesticide manual[M]. 8th ed. Suffolk: Lavenham Press, 1987.
[30]	LEE C M, ANDERSON B, ELZERMAN A W. Photochemical oxidation of terbufos[J]. Environmental Toxicology and Chemistry, 1999, 18(7): 1349-1353.
[31]	赵淑英, 谭卫红, 宋湛谦. 印楝素的稳定性研究[J]. 福建林学院学报, 2005, 25(3):247-250.
	ZHAO S Y, TAN W H, SONG Z Q. Study on stability of azadirachtin[J]. Journal of Fujian College of Forestry, 2005, 25(3):247-250. (in Chinese with English abstract)
[32]	TOMLIN C, COUNCIL B C P. The pesticide manual: a world compendium.[M]. Array Alton: British Crop Protection Council, 2003.
[33]	李学德, 花日茂, 岳永德, 等. 百菌清(chlorothalonil)在水中的光化学降解[J]. 应用生态学报, 2006, 17(6): 1091-1094.
	LI X D, HUA R M, YUE Y D, et al. Photochemical degradation of chlorothalonil in aqueous solution[J]. Chinese Journal of Applied Ecology, 2006, 17(6): 1091-1094. (in Chinese with English abstract)
[34]	周楷博, 刘胜辉, 罗正刚, 等. 苯醚甲环唑的水解研究[J]. 现代农药, 2010, 9(2):28-32.
	ZHOU K B, LIU S H, LUO Z G, et al. Hydrolysis of difenoconazole[J]. Modern Agrochemicals, 2010, 9(2):28-32. (in Chinese with English abstract)
[35]	远铁疆. 丙烷脒在土壤中吸附、迁移及水解动力学研究[D]. 杨凌: 西北农林科技大学, 2007.
	YUAN T J. Study on adsorption, migration and hydrolysis kinetics of propamidine in soil[D]. Yangling: Northwest A & F University, 2007. (in Chinese with English abstract)
[36]	杨昱. 苯噻菌酯的环境行为研究[D]. 南京: 南京农业大学, 2016.
	YANG Y. Study on environmental behavior of thiophanate-methyl[D]. Nanjing: Nanjing Agricultural University, 2016. (in Chinese with English abstract)
[37]	马腾达. 吡唑醚菌酯的光解与水解特性研究[D]. 长春: 吉林农业大学, 2012.
	MA T D. Study on photolysis and hydrolysis characteristics of pyraclostrobin[D]. Changchun: Jilin Agricultural University, 2012. (in Chinese with English abstract)
[38]	MACBEAN C. E-pesticide manual[M]. 15th ed. Alton: British Crop Protection Council, 2008.
[39]	孔祥吉, 马山山, 吴文铸, 等. 水中代森联的分析方法及其水解特性研究[C]// 中国环境科学学会.2014中国环境科学学会学术年会.中国环境科学学会, 2014: 878-884.
[40]	JERNBERG K M, LEE P W. Fate of famoxadone in the environment[J]. Pesticide Science, 1999, 55(5): 587-589.
[41]	许秀莹, 刘晓凤, 王鸣华. 氟啶胺的水解与土壤降解特性研究[J]. 安全与环境学报, 2014, 14(5):252-256.
	XU X Y, LIU X F, WANG M H. On fluazinam hydrolysis and degradation features in the soil[J]. Journal of Safety and Environment, 2014, 14(5):252-256.(in Chinese with English abstract)
[42]	张春艳, 郑张瑜, 施海燕, 等. 环氟菌胺的水解动力学研究[J]. 生态毒理学报, 2017, 12(4):348-353.
	ZHANG C Y, ZHENG Z Y, SHI H Y, et al. The hydrolysis of cyflufenamid in liquid media[J]. Asian Journal of Ecotoxicology, 2017, 12(4):348-353. (in Chinese with English abstract)
[43]	TOMLIN C D S. The e-pesticide manual (13th ed.Ver.3.0.)[M]. Surrey: British Crop Protection Council, 2003.
[44]	谭红. 稻瘟酰胺和咪鲜胺在稻田中的残留消解及水解研究[D]. 长沙: 湖南农业大学, 2015.
	TAN H. Study on residue digestion and hydrolysis of Magnaporthe grisea and prochloraz in paddy field[D]. Changsha: Hunan Agricultural University, 2015. (in Chinese with English abstract)
[45]	刘晓旭, 侯志广, 吴敬慧, 等. 嘧菌酯水解动力学研究[J]. 农业环境科学学报, 2012, 31(8): 1603-1607.
	LIU X X, HOU Z G, WU J H, et al. Hydrolyze kinetics and mechanism of azoxystrobin[J]. Journal of Agro-Environment Science, 2012, 31(8): 1603-1607. (in Chinese with English abstract)
[46]	亓育杰, 杨昱, 郑张瑜, 等. 噻呋酰胺的光解和水解特性研究[J]. 农药学学报, 2016, 18(4):540-544.
	QI Y J, YANG Y, ZHENG Z Y, et al. Study on the photolysis and hydrolysis properties of thifluzamide[J]. Chinese Journal of Pesticide Science, 2016, 18(4):540-544. (in Chinese with English abstract)
[47]	刘毅华, 郭正元, 杨仁斌, 等. 三唑酮的酸性、中性和碱性水解动力学研究[J]. 农村生态环境, 2005, 21(1): 67-68, 71.
	LIU Y H, GUO Z Y, YANG R B, et al. Hydrolysis dynamics of triadimefon in aquatic environment different in pH value[J]. Rural Eco-Environment, 2005, 21(1): 67-68, 71. (in Chinese with English abstract)
[48]	刘祥云, 崔滢, 杨艳. 影响霜脲氰在土壤中降解的因素研究[J]. 广州化工, 2014, 42(8): 101-103, 120.
	LIU X Y, CUI Y, YANG Y. Factors of affecting the degradation of cymoxanil in soils[J]. Guangzhou Chemical Industry, 2014, 42(8): 101-103, 120. (in Chinese with English abstract)
[49]	高扬帆, 薛凤珍, 李广领, 等. 叶青双在水中的降解特性研究[J]. 西北农业学报, 2006, 15(6):233-235.
	GAO Y F, XUE F Z, LI G L, et al. The research on degradation of MBAMT in water[J]. Acta Agriculturae Boreali-Occidentalis Sinica, 2006, 15(6):233-235. (in Chinese with English abstract)
[50]	CHAMBERLAIN E, SHI H L, WANG T W, et al. Comprehensive screening study of pesticide degradation via oxidation and hydrolysis[J]. Journal of Agricultural and Food Chemistry, 2012, 60(1): 354-363.
[51]	黄巍. 胺苯磺隆降解菌的筛选及其降解特性研究[D]. 长沙: 湖南农业大学, 2007.
	HUANG W. Screening of aminobesulfuron-methyl degrading bacteria and its degradation characteristics[D]. Changsha: Hunan Agricultural University, 2007. (in Chinese with English abstract)
[52]	李广领. 精吡氟禾草灵在人参种植体系中环境行为及残留特性研究[D]. 长春: 吉林农业大学, 2020.
	LI G L. Study on environmental behavior and residue characteristics of fenpropathrin in ginseng planting system[D]. Changchun: Jilin Agricultural University, 2020. (in Chinese with English abstract)
[53]	赵玉文. 吡喃草酮光降解及水解特性研究[D]. 长春: 吉林农业大学, 2006.
	ZHAO Y W. Study on photodegradation and hydrolysis characteristics of pyranone[D]. Changchun: Jilin Agricultural University, 2006. (in Chinese with English abstract)
[54]	谭智勇. 苄嘧磺隆和丁草胺颗粒剂在稻田环境中的残留消解及苄嘧磺隆水解研究[D]. 长沙: 湖南农业大学, 2011.
	TAN Z Y. Residue digestion and hydrolysis of bensulfuron-methyl and butachlor granules in paddy field environment[D]. Changsha: Hunan Agricultural University, 2011. (in Chinese with English abstract)
[55]	程功, 田宏哲, 刘娜, 等. 丙炔氟草胺的水解及光解特性研究[J]. 农药学学报, 2017, 19(5):583-588.
	CHENG G, TIAN H Z, LIU N, et al. Study on the photolytic and hydrolytic properties of flumioxazin[J]. Chinese Journal of Pesticide Science, 2017, 19(5):583-588. (in Chinese with English abstract)
[56]	郑和辉, 叶常明. 乙草胺和丁草胺的水解及其动力学[J]. 环境化学, 2001, 20(2):168-171.
	ZHENG H H, YE C M. Hydrolysis of chloroacetanilide herbicidesacetochlor and butachlor[J]. Environmental Chemistry, 2001, 20(2):168-171. (in Chinese with English abstract)
[57]	孔德洋, 吴文铸, 许静, 等. 毒草胺在环境中的降解特性研究[J]. 生态环境学报, 2012, 21(7):1325-1328.
	KONG D Y, WU W Z, XU J, et al. Study on degradation characteristics of toxaphene in environment[J]. Ecology and Environment Sciences, 2012, 21(7):1325-1328. (in Chinese with English abstract)
[58]	WORTHING C R. The pesticide manual[M]. 8th ed. Suffolk: The Lavenham Press Lth, 1987: 412.
[59]	朱聪, 开美玲, 丁先锋, 等. pH对氟磺胺草醚水解的影响[J]. 农业环境科学学报, 2007, 26(S1):204-206.
	ZHU C, KAI M L, DING X F, et al. Hydrolysis of herbicide fomesafen in buffer solution at various pH values[J]. Journal of Agro-Environment Science, 2007, 26(S1):204-206. (in Chinese with English abstract)
[60]	SARMAH A K, KOOKANA R S, DUFFY M J, et al. Hydrolysis of triasulfuron, metsulfuron-methyl and chlorsulfuron in alkaline soil and aqueous solutions[J]. Pest Management Science, 2000, 56(5): 463-471.
[61]	MILL T, HAAG W, PENWELL P, et al. Environmental fate and exposure studies. Development of a PC-SAR for hydrolysis: Ester, alkyl halides and epoxides[M]. EPA Contract No. 68-02-4254. Menlo Park, CA: SRI International, 1987.
[62]	吴文铸, 孔德洋, 何健, 等. 甲酰氨基嘧磺隆在模拟环境中的降解特性[J]. 环境化学, 2016, 35(3): 439-444.
	WU W Z, KONG D Y, HE J, et al. Degradation of foramsulfuron in the simulated environment[J]. Environmental Chemistry, 2016, 35(3): 439-444. (in Chinese with English abstract)
[63]	AZZOUZI M, MOUNTACER H, MANSOUR M. Kinetics of photochemical degradation of imazapyr in aqueous solution[J]. Fresenius Environmental Bulletin, 1999, 8: 709-717.
[64]	DINELLI G, VICARI A, BONETTI A, et al. Hydrolytic dissipation of four sulfonylurea herbicides[J]. Journal of Agricultural and Food Chemistry, 1997, 45(5): 1940-1945.
[65]	FLURY M. Experimental evidence of transport of pesticides through field soils-a review[J]. Journal of Environmental Quality, 1996, 25(1): 25-45.
[66]	万丽, 侯志广, 李丽春, 等. pH值和初始浓度对烟嘧磺隆水解的影响[J]. 安徽农业科学, 2011, 39(25): 15580-15581, 15649.
	WAN L, HOU Z G, LI L C, et al. Effects of pH and initial concentration on hydrolysis of nicosulfron[J]. Journal of Anhui Agricultural Sciences, 2011, 39(25): 15580-15581, 15649. (in Chinese with English abstract)
[67]	于建垒, 宋国春, 窦传峰, 等. 乙草胺、苯磺隆在土壤中的环境行为研究[C]// 中国农业技术推广协会. 全国安全用药技术研讨会论文集.中国农业技术推广协会, 2001: 4.
[68]	吴凌云, 陶传江, 宗伏霖, 等. 乙羧氟草醚水解动态[J]. 农药学学报, 2007, 9(1): 96-99.
	WU L Y, TAO C J, ZONG F L, et al. Degradation dynamics of fluoroglycofen-ethyl in water[J]. Chinese Journal of Pesticide Science, 2007, 9(1): 96-99. (in Chinese with English abstract)
[69]	欧晓明, 步海燕. 磺酰脲类除草剂水化学降解机理研究进展[J]. 农业环境科学学报, 2007, 26(5): 1607-1614.
	OU X M, BU H Y. Advances on hydrolysis mechanisms of sulfonylurea herbicides in aquatic environments[J]. Journal of Agro-Environment Science, 2007, 26(5): 1607-1614. (in Chinese with English abstract)

级别 Grade	pH值敏感性指数 pH value sensibility index	说明 Explanation
3A	I<-2	pH值降低能极显著促进分解The reduction of pH value promotes decomposition greatly
2A	-2≤I<-1	pH值降低能显著促进分解The decrease in pH value can promote decomposition significantly
1A	-1≤I<-0.2	pH值降低能促进分解Lower pH value promotes decomposition
0	-0.2≤I≤0.2	pH值对分解无明显影响The pH value has no obvious effect on decomposition
1B	0.2<I≤1	pH值提高能促进分解Higher pH value promotes decomposition
2B	1<I≤2	pH值提高能显著促进分解Increasing pH value can promote decomposition significantly
3B	I>2	pH值提高能极显著促进分解The decomposition is enhanced by increasing pH value greatly

级别 Grade	pH值敏感性指数 pH value sensibility index	说明 Explanation
3A	I<-2	pH值降低能极显著促进分解The reduction of pH value promotes decomposition greatly
2A	-2≤I<-1	pH值降低能显著促进分解The decrease in pH value can promote decomposition significantly
1A	-1≤I<-0.2	pH值降低能促进分解Lower pH value promotes decomposition
0	-0.2≤I≤0.2	pH值对分解无明显影响The pH value has no obvious effect on decomposition
1B	0.2<I≤1	pH值提高能促进分解Higher pH value promotes decomposition
2B	1<I≤2	pH值提高能显著促进分解Increasing pH value can promote decomposition significantly
3B	I>2	pH值提高能极显著促进分解The decomposition is enhanced by increasing pH value greatly

药剂名称 Name of pesticide			农药类型 Pesticide type			温度 Temperature/ ℃			不同pH值条件下的半衰期 Half-life at different pH value/d														pH敏感性指数 pH value sensibility index		级别 Grade
药剂名称 Name of pesticide			农药类型 Pesticide type			温度 Temperature/ ℃			pH 4			pH 5			pH 7			pH 9			pH 10		pH敏感性指数 pH value sensibility index		级别 Grade
百菌清Chlorothalonil^[33]			取代苯类Substituted benzenes			25			210			—			84.5			—			6.8		0.83±0.37		1B
						40			123.8			—			14			—			0.17
苯啶菌酮Pyriofenone^[11]			苯甲酰吡啶类Benzoylpyridines			20			稳定Stable			稳定Stable			稳定Stable			稳定Stable			—		—		0
苯醚甲环唑Difenoconazole^[34]			三唑类Triazoles			25			—			315.07			11.53			1.33			—		1.37±0.23		2B
苯霜灵Benalaxyl^[6]			酰基氨基酸类Acyl amino acids			20			—			—			365			157			—		0.42		1B
苯绣啶Fenpropidin^[6]			哌啶类Piperidines			50			稳定Stable			稳定Stable			稳定Stable			稳定Stable			—		—		0
苯噻菌胺Benthiavalicarb-isopropyl^[11]			缬胺酰胺氨基甲酸酯类Valamide carbamates			—			6.8			—			—			178			—		-0.652 972 188		1A
丙烷脒Propamidine^[35]			烷基脒类Alkylamidines			25			—			180			166.8			187.9			—		-0.01±0.04		0
苯噻菌酯			甲氧基丙烯酸酯类Methoxyacrylates			15			365			—			266.5			256.7			—		0.15±0.13		0
Benzene thiamethoxam bacteria ester^[36]						25			330			—			256.7			1.4			—
						35			277			—			216.6			81.6			—
丙森锌Propineb^[11]			二硫代氨基甲酸酯类Dithiocarbamates			22			1			—			—			2.21			—		-0.16		0
吡唑氨酯Fenpyrazamine^[11]			吡唑酮类Pyrazolones			20			—			—			32.6			11			—		0.54		1B
吡噻菌胺Penthiopyrad^[11]			吡唑酰胺类Pyrazolamides			20			稳定Stable			稳定Stable			稳定Stable			稳定Stable			—		—		0
吡唑醚菌酯Pyraclostrobin^[37]			甲氧基丙烯酸酯类Methoxyacrylates			—			—			7.7			8.7			10.4			—		-0.08±0.01		0
多果定Dodine^[11]			胍类Guanidine			25			—			576			—			1 198			—		-0.18		0
多菌灵Carbendazim^[38]			苯并咪唑类Benzimidazoles			22			—			—			>350			124			—		0.52		1B
代森联Metiram^[39]			二硫代氨基甲酸酯类Dithiocarbamates			25			31.5			—			3			6.74			—		0.25±0.35		1B
						50			0.86			—			0.41			0.23			—
敌螨普Dinocap^[11]			二硝基苯基巴豆酸酯类Dinitrophenyl crotonate esters			20			280			—			23			6.5			—		0.74±0.08		1B
						30			73			—			—			1.7			—		0.75±0.28		1B
敌百虫Trichlorfon^[11]			有机磷酸酯类Organophosphate			25			—			117			—			0.022			—		2.14		3B
啶酰菌胺Boscalid^[11]			吡啶甲酰胺类Pyridine formamides			20			稳定Stable			稳定Stable			稳定Stable			稳定Stable			—		—		0
丁苯吗啉Fenpropimorph^[11]			吗啉类Morpholines			25			稳定Stable			稳定Stable			稳定Stable			稳定Stable			—		—		0
噁唑菌酮Famoxadone^[40]			噁唑类Oxazole			—			—			36			2.35			1.7			—		0.76±0.49		1B
						20			—			稳定Stable			稳定Stable			稳定Stable			—		—		0
噁霉灵Hymexazol^[11]			噁唑类Oxazole			20			—			稳定Stable			稳定Stable			稳定Stable			—		—		0
二苯胺Diphenylamine^[11]			其他Other			25			—			316			352			359			—		-0.03±0.02		0
二噻农Dithianon^[11]			蒽醌类Anthraquinones			20			—			10.7			0.6			0.006 8			—		1.84±0.33		2B
二甲基二硫醚Dimethyl disulfide^[11]			其他Other			20			稳定Stable			稳定Stable			稳定Stable			稳定Stable			—		—		0
氟啶胺Fluazinam^[41]			苯基吡啶胺类Phenylpyridinium amines			15			—			364.8			73.74			23.5			—		0.85±0.31		1B
						25			—			141.5			43.87			5.63			—
						35			—			92.42			29.25			1.29			—
氟菌唑Triflumizole^[6]			咪唑类Imidazole			20			0.77(pH 3)			—			68.2			4.6			—		-0.02±1.03		0
氟喹唑Fluquinconazole^[11]			三唑类Triazoles			25			194			2024			—			0.4			—		0.34±1.93		1B
氟环唑Epoxiconazole^[11]		三唑类Triazoles		25			—				稳定Stable		稳定Stable			稳定Stable			—					—	0
氟嘧菌胺Diflumetorim^[11]		嘧啶胺类Pyrimidine amines		20			稳定Stable				稳定Stable		稳定Stable			稳定Stable			—					—	0
氟嘧菌酯Fluoxastrobin^[11]		甲氧基丙烯酸酯类Methoxyacrylates		20			稳定Stable				稳定Stable		稳定Stable			稳定Stable			—					—	0
氟噻唑菌腈Flutianil^[11]		噻唑烷类Thiazolidines		20			稳定Stable				稳定Stable		稳定Stable			稳定Stable			—					—	0
氟酰胺Flutolanil^[11]		N-苯基氨基甲酸酯类N-phenyl carbamates		20			—				稳定Stable		稳定Stable			稳定Stable			—					—	0
福美双Thiram^[6]		二硫代氨基甲酸酯类Dithiocarbamates		25			—				68.5		3.5			0.29			—					1.37±0.10	2B
福美锌Ziram^[6]		二硫代氨基甲酸酯类Dithiocarbamates		25			0.007				—		—			6.3			—					-1.36	2A
腐霉利Procymidone^[6]		二甲酰亚胺类Dicarboximide		25			93				—		17			0.06			—					1.62±0.92	2B
				20			135				—		24.7			0.09			—
硅噻菌胺Silthiofam^[11]		噻吩酰胺类Thiophenylamides		20			3.042				—		—			28 105			—					-1.67±0.96	2A
				25			1.875				61		448			—			—
				50			0.22				—		118			99			—
环氟菌胺Cyflufenamid^[42]		酰胺类Amides		15			27.6				—		26.1			21.7			—					0.07±0.04	0
				25			24.5				—		22.1			17.2			—
				35			21.8				—		18.7			14.2			—
环唑醇Cyproconazole^[11]		三唑类Triazoles		50			稳定Stable				稳定Stable		稳定Stable			稳定Stable			—					—	0
甲霜灵Metalaxyl		酰基丙氨酸类Acylalanines		20			200(pH 1)				—		106			115			12					0.65±1.03	1B
甲苯氟磺胺Tolylfuanid^[43]		磺酰胺类Sulfonamides		20			12				—		1.21			<0.007			—					1.61±0.74	2B
甲基立枯磷Tolclofos-methyl^[6]		氯苯基类Chlorobenzenes		20			126				—		97			102			—					0.03±0.05	0
甲基硫菌灵Thiophanate-methyl^[6]		苯并咪唑类Benzimidazoles		25			—				867		—			0.7			—					1.78	2B
精甲霜灵Metalaxyl-M^[11]		酰基丙氨酸类Acylalanines		20			稳定Stable				稳定Stable		稳定Stable			稳定Stable			—					—	0
邻苯基苯酚2-phenylphenol^[6]		酚类Phenols		20			—				稳定Stable		稳定Stable			稳定Stable			—					—	0
氯硝胺Dicloran^[11]		硝基苯胺类Nitroanilines		20			稳定Stable				稳定Stable		稳定Stable			稳定Stable			—					—	0
联苯三唑醇Bitertanol^[11]		三唑类Triazoles		20			稳定Stable				稳定Stable		稳定Stable			稳定Stable			—					—	0
咯菌腈Fludioxonil^[11]		芳基吡咯类Aryl pyrroles		20			—				稳定Stable		稳定Stable			稳定Stable			—					—	0
咪鲜胺Prochloraz^[44]		咪唑类Imidazole		25			20.4(pH3)				21		17.3			13.3			3.7(pH11)					0.21±0.25	1B
嘧菌酯Azoxystrobin^[45]		甲氧基丙烯酸酯类Methoxyacrylates		—			—				47.9		29.6			17.2			—					0.26±0.01	1B
醚菌酯Kresoxim-methyl^[11]		甲氧基丙烯酸酯类Methoxyacrylates		20			—				102		35			0.38			—					1.92±0.28	2B
嘧霉胺Pyrimethanil^[6]		苯胺嘧啶类Aniline pyrimidines		22			—				稳定Stable		稳定Stable			稳定Stable			—					—	0
嘧菌环胺Cyprodinil^[11]		苯氨基嘧啶类Phenylaminopyrimidines		20			稳定Stable				稳定Stable		稳定Stable			稳定Stable			—					—	0
咪唑菌酮Fenamidone^[11]		咪唑啉酮类Imidazolinones		20			—				221		411			27.6			—					0.52±0.68	1B
棉隆Dazomet^[11]		其他Other		25			—				0.4		—			0.1			—					0.35	1B
灭菌丹Folpet^[6]		二甲酰亚胺类Dicarboximide		25			—				0.11		0.046			0.000 8			—					1.23±0.65	2B
灭锈胺Mepronil^[11]		苯基苯甲酰类Phenylbenzoyl derivatives		25			261						276			253								0.01±0.03	0
麦穗宁Fuberidazole^[11]		苯并咪唑类Benzimidazoles		20			稳定Stable				稳定Stable		稳定Stable			稳定Stable			—					—	0
萘吡菌胺Isopyrazam^[11]		吡唑甲酰胺类Pyrazolecarboxamide		—			稳定Stable				稳定Stable		稳定Stable			稳定Stable			—					—	0
氰菌胺Fenoxanil^[11]	丙酰胺类Propionamides				20			—		稳定Stable				稳定Stable			稳定Stable			—		—			0
噻呋酰胺Thifluzamide^[46]	噻唑酰胺类Thiazolamides				15			385		—				102			288			—		-0.07±0.29			0
					25			144		—				91			187			—
					35			80		—				55			123			—
三唑醇Triadimenol^[6]	三唑类Triazoles				20			稳定Stable		稳定Stable				稳定Stable			稳定Stable			—		—			0
三唑酮Triadimefon^[47]	三唑类Triazoles				—			—		13.81(pH 6)				—			1.36			—		0.77			1B
霜脲氰Cymoxanil^[48]	氰乙酰胺肟类Cyanoacetamide oximes				—			—		4.8(pH 4.6)				3.5(pH 6.7)			2.7(pH 8.1)			—		0.17±0.01			0
三环唑Tricyclazole^[11]	三唑苯并噻唑类Triazole benzothiazoles				20			稳定Stable		稳定Stable				稳定Stable			稳定Stable			—		—			0
双炔酰菌胺Mandipropamid^[11]	扁桃酰胺类Amylamides				20			稳定Stable		稳定Stable				稳定Stable			稳定Stable			—		—			0
土菌灵Etridiazole^[6]	噻唑类Thiazole				25			—		92				—			88			—		0.01			0
戊菌隆Pencycuron^[11]	苯脲类Phenylureas				50			—		4.7				14.2			15			—		-0.29±0.21			1A
戊菌唑Penconazole^[11]	三唑类Triazoles				25			稳定Stable		稳定Stable				稳定Stable			稳定Stable			—		—			0
					50			稳定Stable		稳定Stable				稳定Stable			稳定Stable			—					0
威百亩Metam-sodium^[11]	其他Other				25			—		1.9				2.2			4.5			—		-0.22±0.12			1A
萎锈灵Carboxin^[11]	氧硫杂芑甲酰苯胺类Oxythiocarbarylanilides				20			稳定Stable		稳定Stable				稳定Stable			稳定Stable			—		—			0
肟菌酯Trifloxystrobin^[11]	肟基乙酸酯类Oxime acetate esters				25			—		480				40			1.2			—		1.50±0.21			2B
硝苯菌酯Meptyldinocap^[6]	二硝基苯酚类Dinitrophenols				20			447		229				43			5			—		0.84±0.15			1B
叶青双Amt^[49]	噻唑类Thiazole				15			1.10		—				2.45			—			5.49		-0.14±0.03			0
					25			1.42		—				1.77			—			2.71
					35			0.98		—				1.44			—			2
叶菌唑Metconazole^[11]	三唑类Triazoles				20			稳定Stable		稳定Stable				稳定Stable			稳定Stable			—		—			0
吲哚磺菌胺Amisulbrom^[11]	其他Other				20			106.1		—				87.1			7			—		0.62±0.49			1B
氧化萎锈灵Oxycarboxin^[11]	氧硫杂芑甲酰胺类Oxythiocyanamide				20			—		—				9.8			0.142			—		2.12			3B
异噻菌胺Isotianil^[11]	噻唑甲酰胺类Thiazole formamides				20			—		—				60.8			71.4			—		-0.08			0
异菌脲Iprodione^[6]	二甲酰亚胺类Dicarboximide				20			—		140				4.5			0.2(pH 8)			—		2.33±0.58			3B
异丙菌胺Iprovalicarb^[11]	缬氨酰胺氨基甲酸酯类Valamide carbamates				25			—		稳定Stable				稳定Stable			稳定Stable			—		—			0
乙霉威Diethofencarb^[11]	N-苯基氨基甲酸酯类N-Phenyl carbamates				25			稳定Stable		稳定Stable				稳定Stable			稳定Stable			—		—			0
唑嘧菌胺Ametoctradin^[11]	三唑嘧啶类Triazole pyrimidines				25			稳定Stable		稳定Stable				稳定Stable			稳定Stable			—		—			0

药剂名称 Name of pesticide			农药类型 Pesticide type			温度 Temperature/ ℃			不同pH值条件下的半衰期 Half-life at different pH value/d														pH敏感性指数 pH value sensibility index		级别 Grade
药剂名称 Name of pesticide			农药类型 Pesticide type			温度 Temperature/ ℃			pH 4			pH 5			pH 7			pH 9			pH 10		pH敏感性指数 pH value sensibility index		级别 Grade
百菌清Chlorothalonil^[33]			取代苯类Substituted benzenes			25			210			—			84.5			—			6.8		0.83±0.37		1B
						40			123.8			—			14			—			0.17
苯啶菌酮Pyriofenone^[11]			苯甲酰吡啶类Benzoylpyridines			20			稳定Stable			稳定Stable			稳定Stable			稳定Stable			—		—		0
苯醚甲环唑Difenoconazole^[34]			三唑类Triazoles			25			—			315.07			11.53			1.33			—		1.37±0.23		2B
苯霜灵Benalaxyl^[6]			酰基氨基酸类Acyl amino acids			20			—			—			365			157			—		0.42		1B
苯绣啶Fenpropidin^[6]			哌啶类Piperidines			50			稳定Stable			稳定Stable			稳定Stable			稳定Stable			—		—		0
苯噻菌胺Benthiavalicarb-isopropyl^[11]			缬胺酰胺氨基甲酸酯类Valamide carbamates			—			6.8			—			—			178			—		-0.652 972 188		1A
丙烷脒Propamidine^[35]			烷基脒类Alkylamidines			25			—			180			166.8			187.9			—		-0.01±0.04		0
苯噻菌酯			甲氧基丙烯酸酯类Methoxyacrylates			15			365			—			266.5			256.7			—		0.15±0.13		0
Benzene thiamethoxam bacteria ester^[36]						25			330			—			256.7			1.4			—
						35			277			—			216.6			81.6			—
丙森锌Propineb^[11]			二硫代氨基甲酸酯类Dithiocarbamates			22			1			—			—			2.21			—		-0.16		0
吡唑氨酯Fenpyrazamine^[11]			吡唑酮类Pyrazolones			20			—			—			32.6			11			—		0.54		1B
吡噻菌胺Penthiopyrad^[11]			吡唑酰胺类Pyrazolamides			20			稳定Stable			稳定Stable			稳定Stable			稳定Stable			—		—		0
吡唑醚菌酯Pyraclostrobin^[37]			甲氧基丙烯酸酯类Methoxyacrylates			—			—			7.7			8.7			10.4			—		-0.08±0.01		0
多果定Dodine^[11]			胍类Guanidine			25			—			576			—			1 198			—		-0.18		0
多菌灵Carbendazim^[38]			苯并咪唑类Benzimidazoles			22			—			—			>350			124			—		0.52		1B
代森联Metiram^[39]			二硫代氨基甲酸酯类Dithiocarbamates			25			31.5			—			3			6.74			—		0.25±0.35		1B
						50			0.86			—			0.41			0.23			—
敌螨普Dinocap^[11]			二硝基苯基巴豆酸酯类Dinitrophenyl crotonate esters			20			280			—			23			6.5			—		0.74±0.08		1B
						30			73			—			—			1.7			—		0.75±0.28		1B
敌百虫Trichlorfon^[11]			有机磷酸酯类Organophosphate			25			—			117			—			0.022			—		2.14		3B
啶酰菌胺Boscalid^[11]			吡啶甲酰胺类Pyridine formamides			20			稳定Stable			稳定Stable			稳定Stable			稳定Stable			—		—		0
丁苯吗啉Fenpropimorph^[11]			吗啉类Morpholines			25			稳定Stable			稳定Stable			稳定Stable			稳定Stable			—		—		0
噁唑菌酮Famoxadone^[40]			噁唑类Oxazole			—			—			36			2.35			1.7			—		0.76±0.49		1B
						20			—			稳定Stable			稳定Stable			稳定Stable			—		—		0
噁霉灵Hymexazol^[11]			噁唑类Oxazole			20			—			稳定Stable			稳定Stable			稳定Stable			—		—		0
二苯胺Diphenylamine^[11]			其他Other			25			—			316			352			359			—		-0.03±0.02		0
二噻农Dithianon^[11]			蒽醌类Anthraquinones			20			—			10.7			0.6			0.006 8			—		1.84±0.33		2B
二甲基二硫醚Dimethyl disulfide^[11]			其他Other			20			稳定Stable			稳定Stable			稳定Stable			稳定Stable			—		—		0
氟啶胺Fluazinam^[41]			苯基吡啶胺类Phenylpyridinium amines			15			—			364.8			73.74			23.5			—		0.85±0.31		1B
						25			—			141.5			43.87			5.63			—
						35			—			92.42			29.25			1.29			—
氟菌唑Triflumizole^[6]			咪唑类Imidazole			20			0.77(pH 3)			—			68.2			4.6			—		-0.02±1.03		0
氟喹唑Fluquinconazole^[11]			三唑类Triazoles			25			194			2024			—			0.4			—		0.34±1.93		1B
氟环唑Epoxiconazole^[11]		三唑类Triazoles		25			—				稳定Stable		稳定Stable			稳定Stable			—					—	0
氟嘧菌胺Diflumetorim^[11]		嘧啶胺类Pyrimidine amines		20			稳定Stable				稳定Stable		稳定Stable			稳定Stable			—					—	0
氟嘧菌酯Fluoxastrobin^[11]		甲氧基丙烯酸酯类Methoxyacrylates		20			稳定Stable				稳定Stable		稳定Stable			稳定Stable			—					—	0
氟噻唑菌腈Flutianil^[11]		噻唑烷类Thiazolidines		20			稳定Stable				稳定Stable		稳定Stable			稳定Stable			—					—	0
氟酰胺Flutolanil^[11]		N-苯基氨基甲酸酯类N-phenyl carbamates		20			—				稳定Stable		稳定Stable			稳定Stable			—					—	0
福美双Thiram^[6]		二硫代氨基甲酸酯类Dithiocarbamates		25			—				68.5		3.5			0.29			—					1.37±0.10	2B
福美锌Ziram^[6]		二硫代氨基甲酸酯类Dithiocarbamates		25			0.007				—		—			6.3			—					-1.36	2A
腐霉利Procymidone^[6]		二甲酰亚胺类Dicarboximide		25			93				—		17			0.06			—					1.62±0.92	2B
				20			135				—		24.7			0.09			—
硅噻菌胺Silthiofam^[11]		噻吩酰胺类Thiophenylamides		20			3.042				—		—			28 105			—					-1.67±0.96	2A
				25			1.875				61		448			—			—
				50			0.22				—		118			99			—
环氟菌胺Cyflufenamid^[42]		酰胺类Amides		15			27.6				—		26.1			21.7			—					0.07±0.04	0
				25			24.5				—		22.1			17.2			—
				35			21.8				—		18.7			14.2			—
环唑醇Cyproconazole^[11]		三唑类Triazoles		50			稳定Stable				稳定Stable		稳定Stable			稳定Stable			—					—	0
甲霜灵Metalaxyl		酰基丙氨酸类Acylalanines		20			200(pH 1)				—		106			115			12					0.65±1.03	1B
甲苯氟磺胺Tolylfuanid^[43]		磺酰胺类Sulfonamides		20			12				—		1.21			<0.007			—					1.61±0.74	2B
甲基立枯磷Tolclofos-methyl^[6]		氯苯基类Chlorobenzenes		20			126				—		97			102			—					0.03±0.05	0
甲基硫菌灵Thiophanate-methyl^[6]		苯并咪唑类Benzimidazoles		25			—				867		—			0.7			—					1.78	2B
精甲霜灵Metalaxyl-M^[11]		酰基丙氨酸类Acylalanines		20			稳定Stable				稳定Stable		稳定Stable			稳定Stable			—					—	0
邻苯基苯酚2-phenylphenol^[6]		酚类Phenols		20			—				稳定Stable		稳定Stable			稳定Stable			—					—	0
氯硝胺Dicloran^[11]		硝基苯胺类Nitroanilines		20			稳定Stable				稳定Stable		稳定Stable			稳定Stable			—					—	0
联苯三唑醇Bitertanol^[11]		三唑类Triazoles		20			稳定Stable				稳定Stable		稳定Stable			稳定Stable			—					—	0
咯菌腈Fludioxonil^[11]		芳基吡咯类Aryl pyrroles		20			—				稳定Stable		稳定Stable			稳定Stable			—					—	0
咪鲜胺Prochloraz^[44]		咪唑类Imidazole		25			20.4(pH3)				21		17.3			13.3			3.7(pH11)					0.21±0.25	1B
嘧菌酯Azoxystrobin^[45]		甲氧基丙烯酸酯类Methoxyacrylates		—			—				47.9		29.6			17.2			—					0.26±0.01	1B
醚菌酯Kresoxim-methyl^[11]		甲氧基丙烯酸酯类Methoxyacrylates		20			—				102		35			0.38			—					1.92±0.28	2B
嘧霉胺Pyrimethanil^[6]		苯胺嘧啶类Aniline pyrimidines		22			—				稳定Stable		稳定Stable			稳定Stable			—					—	0
嘧菌环胺Cyprodinil^[11]		苯氨基嘧啶类Phenylaminopyrimidines		20			稳定Stable				稳定Stable		稳定Stable			稳定Stable			—					—	0
咪唑菌酮Fenamidone^[11]		咪唑啉酮类Imidazolinones		20			—				221		411			27.6			—					0.52±0.68	1B
棉隆Dazomet^[11]		其他Other		25			—				0.4		—			0.1			—					0.35	1B
灭菌丹Folpet^[6]		二甲酰亚胺类Dicarboximide		25			—				0.11		0.046			0.000 8			—					1.23±0.65	2B
灭锈胺Mepronil^[11]		苯基苯甲酰类Phenylbenzoyl derivatives		25			261						276			253								0.01±0.03	0
麦穗宁Fuberidazole^[11]		苯并咪唑类Benzimidazoles		20			稳定Stable				稳定Stable		稳定Stable			稳定Stable			—					—	0
萘吡菌胺Isopyrazam^[11]		吡唑甲酰胺类Pyrazolecarboxamide		—			稳定Stable				稳定Stable		稳定Stable			稳定Stable			—					—	0
氰菌胺Fenoxanil^[11]	丙酰胺类Propionamides				20			—		稳定Stable				稳定Stable			稳定Stable			—		—			0
噻呋酰胺Thifluzamide^[46]	噻唑酰胺类Thiazolamides				15			385		—				102			288			—		-0.07±0.29			0
					25			144		—				91			187			—
					35			80		—				55			123			—
三唑醇Triadimenol^[6]	三唑类Triazoles				20			稳定Stable		稳定Stable				稳定Stable			稳定Stable			—		—			0
三唑酮Triadimefon^[47]	三唑类Triazoles				—			—		13.81(pH 6)				—			1.36			—		0.77			1B
霜脲氰Cymoxanil^[48]	氰乙酰胺肟类Cyanoacetamide oximes				—			—		4.8(pH 4.6)				3.5(pH 6.7)			2.7(pH 8.1)			—		0.17±0.01			0
三环唑Tricyclazole^[11]	三唑苯并噻唑类Triazole benzothiazoles				20			稳定Stable		稳定Stable				稳定Stable			稳定Stable			—		—			0
双炔酰菌胺Mandipropamid^[11]	扁桃酰胺类Amylamides				20			稳定Stable		稳定Stable				稳定Stable			稳定Stable			—		—			0
土菌灵Etridiazole^[6]	噻唑类Thiazole				25			—		92				—			88			—		0.01			0
戊菌隆Pencycuron^[11]	苯脲类Phenylureas				50			—		4.7				14.2			15			—		-0.29±0.21			1A
戊菌唑Penconazole^[11]	三唑类Triazoles				25			稳定Stable		稳定Stable				稳定Stable			稳定Stable			—		—			0
					50			稳定Stable		稳定Stable				稳定Stable			稳定Stable			—					0
威百亩Metam-sodium^[11]	其他Other				25			—		1.9				2.2			4.5			—		-0.22±0.12			1A
萎锈灵Carboxin^[11]	氧硫杂芑甲酰苯胺类Oxythiocarbarylanilides				20			稳定Stable		稳定Stable				稳定Stable			稳定Stable			—		—			0
肟菌酯Trifloxystrobin^[11]	肟基乙酸酯类Oxime acetate esters				25			—		480				40			1.2			—		1.50±0.21			2B
硝苯菌酯Meptyldinocap^[6]	二硝基苯酚类Dinitrophenols				20			447		229				43			5			—		0.84±0.15			1B
叶青双Amt^[49]	噻唑类Thiazole				15			1.10		—				2.45			—			5.49		-0.14±0.03			0
					25			1.42		—				1.77			—			2.71
					35			0.98		—				1.44			—			2
叶菌唑Metconazole^[11]	三唑类Triazoles				20			稳定Stable		稳定Stable				稳定Stable			稳定Stable			—		—			0
吲哚磺菌胺Amisulbrom^[11]	其他Other				20			106.1		—				87.1			7			—		0.62±0.49			1B
氧化萎锈灵Oxycarboxin^[11]	氧硫杂芑甲酰胺类Oxythiocyanamide				20			—		—				9.8			0.142			—		2.12			3B
异噻菌胺Isotianil^[11]	噻唑甲酰胺类Thiazole formamides				20			—		—				60.8			71.4			—		-0.08			0
异菌脲Iprodione^[6]	二甲酰亚胺类Dicarboximide				20			—		140				4.5			0.2(pH 8)			—		2.33±0.58			3B
异丙菌胺Iprovalicarb^[11]	缬氨酰胺氨基甲酸酯类Valamide carbamates				25			—		稳定Stable				稳定Stable			稳定Stable			—		—			0
乙霉威Diethofencarb^[11]	N-苯基氨基甲酸酯类N-Phenyl carbamates				25			稳定Stable		稳定Stable				稳定Stable			稳定Stable			—		—			0
唑嘧菌胺Ametoctradin^[11]	三唑嘧啶类Triazole pyrimidines				25			稳定Stable		稳定Stable				稳定Stable			稳定Stable			—		—			0

药剂名称 Name of pesticide	农药类型 Pesticide type	温度 Temperature/ ℃	不同pH值条件下的半衰期 Half-life at different pH value/d						pH敏感性指数 pH value sensibility index	级别 Grade
药剂名称 Name of pesticide	农药类型 Pesticide type	温度 Temperature/ ℃	pH 4	pH 5	pH 6	pH 7	pH 8	pH 9	pH敏感性指数 pH value sensibility index	级别 Grade
2,4-滴2,4-D^[50]	苯氧羧酸类Phenoxyalkanoic acids	—	—	—	—	稳定Stable	—	稳定Stable(pH 10)	—	0
2-甲-4-氯MCPA^[7]	苯氧羧酸类Phenoxyalkanoic acids	25	—	稳定Stable	稳定Stable	稳定Stable	稳定Stable	稳定Stable	—	0
阿特拉津Atrazine^[7]	三嗪类Triazines	25	174(pH 4.5)	—	398	742	—	—	-0.06±1.00	0
氨氯吡啶酸Picloram^[7]	吡啶类Pyridines	25	—	稳定Stable	稳定Stable	稳定Stable	稳定Stable	稳定Stable	—	0
氨磺乐灵Oryzalin^[11]	二硝基苯胺类Dinitroanilines	25	稳定Stable	稳定Stable	稳定Stable	稳定Stable	稳定Stable	稳定Stable	—	0
胺苯磺隆Ethametsulfuron-methyl^[51]	磺酰脲类Sulfonylureas	—	37.5(pH 4.1)	—	50(pH 5.7)	—	—	—	-0.30±0.08	1A
百草枯Paraquat^[7]	联吡啶类Bipyridines	40	—	稳定Stable		稳定Stable		稳定Stable	—	0
	其他Other	20	—	3.5	—	—	—	0.9(pH 10)	0.57	1B
苯磺隆Tribenuron-methyl^[7]	磺酰脲类Sulfonylureas	20	—	1	—	16	—		-1.39	2A
苯嗪草酮Metamitron^[7]	三唑酮类Triazolones	20	—	480	—	353.2	—	8.5	0.93±0.89	1B
吡氟禾草灵Fluazifop-P-butyl^[52]	芳氧苯氧羧酸酯类	25	288.8	—	—	72.2	—	1.2	1.14±0.63	2B
	Aromatic oxyphenoxy carboxylates
		50	96.27	—	—	28.9	—	0.69
吡喃草酮Tepraloxydim^[53]	环己烯酮类Cyclohexanediones	—	1.8	—	—	60.3(pH 6.9)	—	—	-1.23	2A
吡唑草胺Metazachlor^[11]	酰胺类Amides	20	稳定Stable	稳定Stable	稳定Stable	稳定Stable	稳定Stable	稳定Stable	—	0
苄嘧磺隆Bensulfuron-methyl^[54]	磺酰脲类Sulfonylureas	25	14.56	—	—	141.43	—	346.5(pH 10)	-0.53±0.19	1A
丙炔氟草胺Flumioxazin^[55]	N-苯基肽酰亚胺类	15	—	2.6	—	1.4	—	1.6	0.12±0.15	0
	N-phenyl peptide imides
草除灵Benazolin^[11]	其他Other	20	稳定Stable	稳定Stable	稳定Stable	稳定Stable	稳定Stable	稳定Stable	—	0
草铵膦Glufosinate-ammonium^[11]	次膦酸类Phosphonic acids	25	—	稳定Stable	稳定Stable	稳定Stable	稳定Stable	稳定Stable	—	0
草甘膦Glyphosate^[11]	甘氨酸衍生物类Glycine derivatives	25	—	稳定Stable	稳定Stable	稳定Stable	稳定Stable	—	—	0
除草定Bromacil^[7]	尿嘧啶类Uracil	20	—	稳定Stable	—	稳定Stable	—	稳定Stable	—	0
哒草特Pyridate^[11]	苯基哒嗪类Phenylpyridazines	25	4.9	—	—	—	—	0.28	0.33±0.25	1B
		50	0.44	—	—	—	—	0.3
丁草胺Butachlor^[56]	酰胺类Amides	25	630	—	—	115	—	1 155(pH 10)	0.10±0.55	0
丁酰溴苯腈Bromoxynil butanoate^[11]	羟基苯腈类Hydroxybenzonitrile	20	44	—	—	33	—	1.1	0.84±0.66	1B
毒草胺Propachlor^[57]	氯乙酰苯胺类Chloroacetanilides	25	—	148	—	173	—	239	-0.19±0.07	0
		50	—	15.2	—	27	—	42.3
敌草胺Napropamide^[11]	酰胺类Amides	25	—	稳定Stable	稳定Stable	稳定Stable	—	—	—	0
		40	—	稳定Stable	稳定Stable	稳定Stable	—	—	—
敌草快Diquat dibromide^[11]	联吡啶类Bipyridines	20	—	稳定Stable	稳定Stable	稳定Stable	稳定Stable	稳定Stable	—	0
敌草隆Diuron^[11]	脲类Ureas	20	稳定Stable	稳定Stable	稳定Stable	稳定Stable	稳定Stable	稳定Stable	—	0
噁唑禾草灵Fenoxaprop-P-ethyl^[7]	杂环氧基苯氧基脂肪类	25	2.8	19.2	—	—	—	0.7	-0.27±1.19	1A
	Heterocyclic phenoxy ester
噁草酮Oxadiazon^[11]	噁二唑类Oxadiazoles	20	—	—	—	31	—	11.7	0.49	1B
二氯吡啶酸Clopyralid^[11]	烟酸类Nicotinic acids	50	稳定Stable	稳定Stable	稳定Stable	稳定Stable	稳定Stable	稳定Stable	—	0
二甲戊灵Pendimethalin^[11]	二硝基苯胺类Dinitroanilines	20	稳定Stable	稳定Stable	稳定Stable	稳定Stable	稳定Stable	稳定Stable	—	0
高效氟吡甲禾灵	杂环氧基苯氧基脂肪酸类	20	—	—	—	43	—	0.63	2.11	3B
Haloxyfop-R-methyl^[7]	Heterocyclic phenoxy ester
呋草酮Flurtamone^[11]	其他Other	25	—	稳定Stable	稳定Stable	稳定Stable	稳定Stable	稳定Stable	—	0
氟草定Fluroxipir^[7]	有机氯类Organochlorines	20	—	—	—	223	—	3.2	2.12	3B
氟草隆Fluometuron^[58]	苯脲类Phenylureas	—	—	876	—	—	—	1 022	-0.04	0
氟磺胺草醚Fomesafen^[59]	有机氯类Organochlorines	—	—	106	157.4	183	215.2	247.4	-0.21±0.11	1A
氟烯草酸Flumiclorac-pentyl^[7]	甲酰亚胺类Formimide derivatives	20	—	4.2	—	0.8	—	0.004 2	1.73±0.73	2B
氟磺隆Prosulfuron^[11]	磺酰脲类Sulfonylureas	25	—	5~12	—	424~651	—	610~1 690	-1.23±0.68	2A
氟胺草酯Flumiclorac-pentyl^[11]	环己烯-1,2-二酰亚胺类	20	—	4.2	—	0.8	—	0.004	1.74±0.74	2B
	Cyclohexene-1,2-diimide derivatives
氟胺磺隆	磺酰脲类Sulfonylureas	20	—	3.7	—	32	—	36	-0.57±0.42	1A
Triflusulfuron-methyl^[11]
氟啶嘧磺隆	磺酰脲类Sulfonylureas	20	—	44	—	12	—	0.4	1.18±0.43	2B
Flupyrsulfuron-methyl-sodium^[11]
氟吡草腙Diflufenzopyr^[11]	缩氨基脲类Semicarbazone	20	—	13	—	24	—	26	-0.17±0.11	0
氟吡草酮Bicyclopyrone^[11]	其他Other	20	稳定Stable	稳定Stable	稳定Stable	稳定Stable	稳定Stable	稳定Stable	—	0
氟噻草胺Flufenacet^[11]	酰胺类Amides	20	—	稳定Stable	稳定Stable	稳定Stable	稳定Stable	稳定Stable	—	0
氟咯草酮Flurochloridone^[11]	其他Other	25	—	稳定Stable	稳定Stable	稳定Stable	稳定Stable	稳定Stable	—	0
砜嘧磺隆Rimsulfuron^[11]	磺酰脲类Sulfonylureas	25	—	4.7	—	—	—	0.175	0.82	1B
庚酰溴苯腈	羟基苯腈类Hydroxybenzonitrile	20	—	11.7	—	7.3	—	4.1	0.26±0.02	1B
Bromoxynil heptanoate^[11]
高效氟吡甲禾灵	芳氧苯氧丙酸酯类	20	—	—	—	43	—	0.63	2.11	3B
Haloxyfop-P-methyl^[11]	Aryloxyphenoxypropionate esters
禾草灵Diclofop-methyl^[7]	苯氧羧酸类phenoxyalkanoic acids	25	—	363	—	31.7	—	0.52	1.64±0.34	2B
禾草丹Thiobencarb^[11]	氨基甲酸酯类Carbamates	20	—	稳定Stable	稳定Stable	稳定Stable	稳定Stable	稳定Stable	—	0
磺酰磺隆Sulfosulfuron^[7]	磺酰脲类Sulfonylureas	25	7	48	—	168	—	156	-0.77±0.68	1A
磺苯呋草酮Tembotrione^[11]	其他Other	20	稳定Stable	稳定Stable	稳定Stable	稳定Stable	稳定Stable	稳定Stable	—	0
环氧嘧磺隆Oxasulfuron^[11]	磺酰脲类Sulfonylureas	25	—	6.5	—	8.5	—	—	-0.13	0
环庚草醚Cinmethylin^[11]	其他Other	25	稳定Stable	稳定Stable	稳定Stable	稳定Stable	稳定Stable	稳定Stable	—	0
甲磺隆Metsulfuron-methyl^[60]	磺酰脲类Sulfonylureas	25	9.6(pH 5.2)	63(pH 6.2)	116(pH 7.1)	139(pH 8.2)	99(pH 9.4)	87(pH 10.2)	-0.58±0.73	1A
甲基二磺隆Mesosulfuron-methyl^[7]	磺酰脲类Sulfonylureas	25	319	—	—	253	—	3.5	1.04±0.85	2B
甲羧除草醚Bifenox^[61]	二苯醚类Diphenylethers	—	—	—	—	584	60	—	2.28	3B
甲酰胺基嘧磺隆Foramsulfuron^[62]	磺酰脲类Sulfonylureas	25	4.17	—	—	91.2	—	97.6	-0.56±0.41	1A
甲氧咪草烟Imazamox^[11]	咪唑啉酮类Imidazolinones	20	稳定Stable	稳定Stable	稳定Stable	稳定Stable	稳定Stable	稳定Stable	—	0
甲酰胺磺隆Foramsulfuron^[11]	磺酰脲类Sulfonylureas	25	3.7	10	—	—	—	132	-0.78±0.15	1A
解草唑Fenchlorazole-ethyl^[11]	三唑类Triazoles	20	—	115	—	5.5	—	0.08	1.82±0.24	2B
精噁唑禾草灵	芳氧苯氧羧酸酯类	25	2.8	19.2	—	—	—	0.7	-0.27±1.19	1A
Fenoxaprop-P-ethyl^[11]	Aromatic oxyphenoxy carboxylates
精异丙甲草胺S-metolachlor^[11]	酰胺类Amides	25	—	稳定Stable	稳定Stable	稳定Stable	稳定Stable	稳定Stable	—	0
绿麦隆Chlortoluron^[7]	苯脲类Phenylureas	50	—	22	—	—	—	69	-0.29	1A
氯磺隆Chlorsulfuron^[58]	磺酰脲类Sulfonylureas	20	—	—	28(pH 5.7)	—	56	—	-0.3	1A
氯嘧磺隆Chlorimuron-ethyl^[7]	磺酰脲类Sulfonylureas	—	—	17	—	<3.5	—	—	0.79	1B
氯氟吡氧乙酸Fluroxypyr^[11]	吡啶氧乙酸类Pyridoxyacetic acids	20	—	—	—	223	—	3.2	2.12	3B
氯酯磺草胺Cloransulam-methyl^[11]	三唑并嘧啶类Triazole pyrimidines	20	—	>365	—	175	—	3	1.20±0.68	2B
氯吡嘧磺隆Halosulfuron-methyl^[11]	磺酰脲类Sulfonylureas	25	—	26.9	—	—	—	0.775	0.89	1B
利谷隆Linuron^[11]	脲类Ureas	22	—	稳定Stable	稳定Stable	稳定Stable	稳定Stable	稳定Stable	—	0
嘧苯胺磺隆Orthosulfamuron^[11]	磺酰脲类Sulfonylureas	25	—	0.33	—	—	—	228	-1.63	2A
		50	0.017	—	—	1.5	—	8	-1.19±0.27
咪唑烟酸Imazapyr^[63]	咪唑啉酮类Imidazolinones	—	1.03	—	—	0.79	—	—	0.09	0
灭藻醌Quinoclamine^[11]	其他Other	20	—	稳定Stable	稳定Stable	稳定Stable	稳定Stable	稳定Stable	—	0
扑灭津Propazine^[7,11]	三嗪类Triazines	25	—	61	—	>200	—	—	-0.59	1A
炔草酯Clodinafop-propargyl^[7]	芳氧苯氧丙酸酯类	—	—	184	—	2.7	—	0.092	1.90±0.17	2B
	Aryloxyphenoxypropionate esters
坪草丹Orbencarb^[11]	氨基甲酸酯类Carbamates	25	稳定Stable	稳定Stable	稳定Stable	稳定Stable	稳定Stable	稳定Stable	—	0
氰草津Cyanazine^[11]	三唑类Triazoles	—	—	稳定Stable	稳定Stable	稳定Stable	稳定Stable	稳定Stable	—	0
乳氟禾草灵Lactofen^[61]	二苯醚类Diphenylethers	—	—	—	—	365	37	—	2.29	3B
噻吩磺隆Thifensulfuron-methyl^[64]	磺酰脲类Sulfonylureas	29	—	346	1950	—	739	130	0.20±1.25	0
		25	0.42	1.05	7.07(pH 6.5)	4.90(pH 7.5)	3.26(pH 8.5)
噻草啶Thiazopyr^[11]	吡啶类Pyridines	20	稳定Stable	稳定Stable	稳定Stable	稳定Stable	稳定Stable	稳定Stable	—	0
三氯吡氧乙酸Triclopyr^[7]	吡啶类Pyridines	25	—	84	—	8.7	—	0.3	1.46±0.24	2B
		35	—	26	—	2.3	—	0.06
三氟甲磺隆Tritosulfuron^[11]	磺酰脲类Sulfonylureas	20	56	—	—	62	—	20	0.25±0.25	1B
单氰胺Cyanamide^[6]	其他Other	22	—	1 200	—	—	—	810	0.31±0.22	1B
		80	—	2.5	—	—	—	0.3
四唑嘧磺隆Azimsulfuron^[7]	磺酰脲类Sulfonylureas	20	—	89	—	124	—	132	-0.10±0.05	0
四唑酰草胺Fentrazamide^[11]	四唑啉酮类Tetrazolinone	20	—	稳定Stable	稳定Stable	稳定Stable	稳定Stable	稳定Stable	—	0
莎稗磷Anilofos^[11]	硫代磷酸酯类Thiophosphates	20	—	稳定Stable	稳定Stable	稳定Stable	稳定Stable	稳定Stable	—	0
特丁津Terbuthylazine^[7]	三嗪类Triazines	25	—	73	—	205	—	194	-0.24±0.22	1A
特丁净Terbutryn^[11]	1,3,5-三嗪类1,3,5-triazines	20	—	稳定Stable	稳定Stable	稳定Stable	稳定Stable	稳定Stable	—	0
甜菜安Desmedipham^[7]	氨基甲酸酯类Carbamates	22	—	70	—	—	—	0.008	2.25±0.01	3B
		25	—	39	—	—	—	0.005
甜菜宁Phenmedipham^[7]	氨基甲酸酯类Carbamates	25	259	47	—	0.004 9	—	—	3.31±1.19	3B
烯禾啶Sethoxydim^[65]	环己二酮类Cyclohexanediketones	25	1.6(pH 3)	—	45	—	—	438	-0.94±0.14	1A
烯草胺Pethoxamid^[11]	酰胺类Amides	20	稳定Stable	稳定Stable	稳定Stable	稳定Stable	稳定Stable	稳定Stable	—	0
喔草酸Propaquizafop^[11]	芳氧苯氧丙酸酯类	20	—	10.5	—	32	—	0.537 5	0.74±1.06	1B
	Aryloxyphenoxypropionate esters
肟草酮Tralkoxydim^[11]	环己酮肟类Cyclohexanone oximes	25	—	9	—	140	—	—	-1.37	2A
辛酰碘苯腈Ioxynil-octanoate^[7]	羟基苯腈类Hydroxybenzonitrile	22	—	—	—	6	—	16	0.33±0.82	1B
		25	—	—	—	52	—	5.3
辛酰溴苯腈Bromoxynil octanoate^[11]	羟基苯腈类Hydroxybenzonitrile	20	—	34.1	—	15	—	1.7	0.75±0.28	1B
溴苯腈庚酸酯	羟基苯腈类Hydroxybenzonitrile	20	—	11.7	—	—	—	4.1	0.26	1B
Bromoxynil heptanate^[7]
溴苯腈辛酸酯	羟基苯腈类Hydroxybenzonitrile	20	—	34.1	—	11.3	—	1.8	0.74±0.14	1B
Bromoxynil octanoate^[7]
硝磺草酮Mesotrione^[11]	三酮类Triketone	25	—	稳定Stable	稳定Stable	稳定Stable	稳定Stable	稳定Stable	—	0
烟嘧磺隆Nicosulfuron^[7,66]	磺酰脲类Sulfonylureas	25	—	7.7	—	5.2	—	22.5	-0.27±0.46	1A
燕麦灵Barban^[11]	氨基甲酸酯类Carbamates	20	—	—	—	0.046	0.005	—	2.22	3B
乙草胺Acetochlor^[67]	酰胺类Amides	—	—	21.2	—	18.4	—	16.5	0.06±0.01	0
乙氧呋草黄Ethofumesate^[11]	苯并呋喃类Benzofurans	20	—	稳定Stable	稳定Stable	稳定Stable	稳定Stable	稳定Stable	—	0
乙羧氟草醚Fluoroglycofen^[68]	二苯醚类Diphenylethers	25		12.2		6.02		0.06	1.45±0.58	2B
		50		11.7		0.56		0.02
异丙隆Isoproturon^[7]	苯脲类Phenylureas	25	—	1 210	—	—	—	540	0.2	0
异噁草胺Isoxaben^[11]	酰胺类Amides	20		稳定Stable	稳定Stable	稳定Stable	稳定Stable	稳定Stable		0
异噁草酮Clomazone^[11]	异噁唑酮类Isooxazolones	25	—	稳定Stable	稳定Stable	稳定Stable	稳定Stable	稳定Stable	—	0
吲哚酮草酯Cinidon-ethyl^[11]	苯基苯邻二甲酰亚胺类	20	—	5	—	1.5	—	0.037 5	1.22±0.51	2B
	Phenylphthalimide derivatives
唑啉草酯Pinoxaden^[11]	苯基吡唑啉类	20	24	25	—	15	—	0.3	0.69±0.88	1B
	Phenylpyrazoline derivatives
仲丁灵Butralin^[11]	二硝基苯胺类Dinitroanilines	20	稳定Stable	稳定Stable	稳定Stable	稳定Stable	稳定Stable	稳定Stable	—	0

农药水解半衰期的pH值敏感性评价

pH value sensibility evaluation of pesticides hydrolysis half-life

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农药类型 Pesticide type	评估的农药种数 Number of pesticides evaluated	pH值敏感性指数均值 Mean of pH value sensibility index	pH值敏感性指数绝对值平均 Mean of absolute value for pH value sensibility index	不同等级pH值敏感性的农药品种数 Pesticides number for different grades of pH value sensibility
农药类型 Pesticide type	评估的农药种数 Number of pesticides evaluated	pH值敏感性指数均值 Mean of pH value sensibility index		3A	2A	1A	0	1B	2B	3B
杀虫剂Insecticide	114	0.60	0.69	0	3	8	32	42	20	9
有机磷类Organophosphorus	47	0.28	0.53	0	1	4	11	23	7	1
氨基甲酸酯类Carbamates	13	0.96	1.38	0	2	0	0	3	6	2
拟除虫菊酯类pyrethroid	10	1.29	1.29	0	0	0	1	5	0	4
有机氯类Organochlorine	4	0.98	0.98	0	0	0	0	3	1	0
烟碱类Neonicotinoid	4	-0.01	0.01	0	0	0	4	0	0	0
吡唑类Pyrazole	2	0.96	1.01	0	0	0	1	0	1	0
苯甲酰脲类N-benzoylurea	2	0.21	0.21	0	0	0	1	1	0	0
季酮酸类Quaternary ursolic acid	3	0.82	0.82	0	0	0	0	3	0	0
双酰肼类Diacylhydrazide	2	0.04	0.04	0	0	0	2	0	0	0
其他Other	27	0.42	0.61	0	0	4	12	4	5	2
杀菌剂Fungicide	82	0.41	0.50	0	2	3	48	17	9	3
酰胺类Amides	12	0.17	0.47	0	1	0	9	0	1	1
三唑类Triazole	9	0.28	0.28	0	0	0	6	2	1	0
二甲酰亚胺Dicarboximidies	3	1.73	1.73	0	0	0	0	0	2	1
甲氧基丙烯酸酯类Strobilurin	5	0.45	0.48	0	0	0	3	1	1	0
氨基甲酸酯类Carbamates	8	0.07	0.47	0	1	1	4	1	1	0
咪唑类Imidazole	2	0.1	0.12	0	0	0	1	1	0	0
苯并咪唑类Benzimidazole	3	0.77	0.77	0	0	0	1	1	1	0
噻唑类Thiazole	2	-0.07	0.08	0	0	0	2	0	0	0
噁唑类Oxazole	2	0.38	0.38	0	0	0	1	1	0	0
酰基丙氨酸类Acylalanine	2	0.33	0.33	0	0	0	1	1	0	0
其他Other	34	0.34	0.38	0	0	2	20	9	2	1
除草剂Herbicide	109	0.49	0.62	0	5	16	50	17	12	9
磺酰脲类Sulfonylurea	21	-0.23	0.70	0	3	9	3	4	2	0
芳氧苯氧丙酸酯类Aryloxyphenoxypropionate	3	1.58	1.58	0	0	0	0	1	1	1
羟基苯腈Hydroxybenzonitrile	6	0.53	0.53	0	0	0	0	6	0	0
苯氧羧酸Phenoxycarboxylic acids	3	0.55	0.55	0	0	0	2	0	1	0
三嗪类Triazines	3	-0.30	0.30	0	0	2	1	0	0	0
三唑类Triazole	2	0.91	0.91	0	0	0	1	0	1	0
苯脲类Phenylurea	3	-0.04	0.18	0	0	1	2	0	0		0
氨基甲酸酯类Carbamates	5	1.56	1.56	0	0	0	2	0	0		3
吡啶类Pyridines	3	0.49	0.49	0	0	0	2	0	1		0
二苯醚类Diphenyl ethers	3	2.01	2.01	0	0	0	0	0	1		2
二硝基苯胺类Dinitroaniline	3	0.00	0.00	0	0	0	3	0	0		0
酰胺类Amides	8	0.02	0.02	0	0	0	8	0	0		0
有机氯类Organochlorine	2	0.96	1.17	0	0	1	0	0	0		1
联吡啶类Bipyridine	2	0.00	0.00	0	0	0	2	0	0		0
脲类Urea	2	0.00	0.00	0	0	0	2	0	0		0
咪唑啉酮类Imidazolinone	2	0.05	0.05	0	0	0	2	0	0		0
其他Other	38	0.27	0.50	0	2	3	20	6	5		2
合计Total	305	0.50	0.60	0	10	27	130	76	41		21

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