浙江农业学报

• 环境科学 • 上一篇    下一篇

新安江库区消落带土壤向水体释放磷的潜在风险研究

  

  1. (1 浙江省建德市农技推广中心,浙江 建德 311600;2 杭州市植保土肥总站,浙江 杭州 310020;3 浙江大学 环境与资源学院,浙江 杭州 310058)
  • 出版日期:2015-11-25 发布日期:2015-12-05

Potential risk of phosphorus release to water from soils of riparian zone of Xinanjiang reservoir region

  1. (1 Agricultural Technology Extension Center of Jiande City, Jiande 311600, China; 2 Hangzhou Plant Protection and Soil\|fertilizer Station, Hangzhou 310020, China; 3 College of Environmental and Resource Sciences, Zhejiang University, Hangzhou 310058, China)
  • Online:2015-11-25 Published:2015-12-05

摘要: 大型水库周边因季节性水位变化可形成一定宽度的消落带,其中的土壤对磷的吸持或释放可对周围水环境产生影响。本文以新安江库区消落带为研究对象,采用室内模拟方法研究了库区消落带土壤磷的吸附容量及其对磷的吸附与释放行为。结果表明,库区内消落带土壤最大磷吸附容量在197.6~659.6 mg·kg-1之间,平均为438.5 mg·kg-1,属于中等磷吸附水平。土壤对磷零吸附时的磷平衡浓度(EPC0)可作为评价土壤磷素向水体释放磷的阈值。当EPC0值大于水体磷浓度时,土壤以释放磷为主导;小于水体磷浓度时,土壤则以固定磷为主。研究土壤的EPC0值在0.009 8~0.55 mg·L-1之间,平均为0.086 mg·L-1,与土壤有效磷呈显著正相关。在研究设定的溶液磷初始浓度范围(0~0.12 mg·L-1)内,大多数消落带土壤与磷溶液的作用过程为释放-持留交互型,只有个别磷积累较高的土壤属于释放型。消落带被临时农用后,其向水体释放磷的风险明显增加。在目前库区水质状况下,当土壤有效磷超过11 mg·kg-1时,消落带土壤以磷释放型为主。

关键词: 新安江水库, 消落带, 磷, 土壤, 水体

Abstract: Riparian zone with a certain width is commonly formed around many large reservoirs due to the seasonal change of water level. Adsorption and release behavior of phosphorus in soils of the zone would affect the surrounding water environment. In the present paper, Xinanjiang reservoir region was selected as the research area, the adsorption capacity and adsorption\|release behavior of phosphorus in soils of the riparian zone were studied using indoor simulation methods. The results showed that soils in the riparian zone had a medium phosphorus adsorption capacity. The maximum P sorption capacities ranged from 197.6 to 659.6 mg·kg-1 with a mean of 438.5 mg·kg-1. The equilibrium phosphorus concentration at zero phosphorus sorption of soil (EPC0) could be used as a threshold to evaluate release potential of soil phosphorus. Phosphorus was released from soils when EPC0 of the soils was greater than phosphorus concentration in the water. In contrast, soil could fix P from the water when EPC0 of the soils was less than phosphorus concentration in the water. EPC0 values of the tested soils ranged from 0.009 8 to 0.55 mg·L-1, with an average of 0.086 mg·L-1, which were linearly correlated with soil available P contents. When the initial phosphorus concentration in solution was set below 0.12 mg·L-1, the performance of most riparian soils belonged to the release\|retention alternation in interaction between soil and solution, except the individual soil with high P accumulation belonged to release pattern. Phosphorus release risk of soils would increase if riparian zone was temporarily used for agricultural production. In the present water quality situation of the reservoir region, when soil available P content exceeded 11 mg·kg-1, it would present phosphorus release behavior.

Key words: Xinanjiang reservoir, riparian zone, phosphorus, soil, water